4.8 Article

One-step fabrication of eco-friendly superhydrophobic fabrics for high-efficiency oil/water separation and oil spill cleanup

Journal

NANOSCALE
Volume 14, Issue 4, Pages 1296-1309

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nr07111d

Keywords

-

Funding

  1. National Natural Science Foundation of China [21774098]
  2. Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) [sklpme2019-4-26]

Ask authors/readers for more resources

This study successfully developed a superhydrophobic fabric with PEI/TMSPA/SiO2/DTMS, showing excellent oil/water separation and oil spill cleanup efficiency. The modified fabric has promising characteristics of simple preparation, environmental friendliness, and scalability.
The oily wastewater and oil spill caused by oil leakage accidents are extremely harmful to human health and the environment. Thus, it is very important to exploit superhydrophobic separation materials and technologies for oil/water separation and oil spill cleanup. In this study, using the 1,4-conjugate addition reaction between polyethyleneimine (PEI) and 3-(trimethoxysilyl)propyl acrylate (TMSPA), hydrolysis condensation reaction of TMSPA and dodecyltrimethoxysilane (DTMS) jointly connecting to the surface of hydrophilic silica nanoparticles, and hydrogen bond interaction of the residual amino group on the surface of PEI, covalently-crosslinked rough network structures were constructed on fabric surfaces, which endow PEI/TMSPA/SiO2/DTMS fabrics with excellent superhydrophobic properties. The obtained superhydrophobic fabric not only showed excellent heat resistance and excellent stability to acid, alkali, salt and organic solvents, but also showed good mechanical stability to tape stripping and washing tests. The superhydrophobic, superoleophilic properties and porous structure of the modified fabric make it have excellent oil/water separation efficiency (98.49% after 18 cycles) and oil spill cleanup efficiency (95.35% after 9 cycles). This superhydrophobic PEI/TMSPA/SiO2/DTMS fabric has characteristics of simple preparation, environmental friendliness and scale-up, which makes it a very promising separation material for actual oil/water separation and oil spill cleanup.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Review Chemistry, Multidisciplinary

Source of Nanocellulose and Its Application in Nanocomposite Packaging Material: A Review

Jingwen Wang, Xiaoshuai Han, Chunmei Zhang, Kunming Liu, Gaigai Duan

Summary: Food packaging is not just about preserving food, but also about keeping up with technological advances. New degradable packaging materials are becoming popular. Cellulose, a biodegradable material, has better degradability compared to traditional materials and is being introduced into the packaging industry.

NANOMATERIALS (2022)

Article Polymer Science

A Tissue Paper/Hydrogel Composite Light-Responsive Biomimetic Actuator Fabricated by In Situ Polymerization

Qijun Wu, Chao Ma, Lian Chen, Ye Sun, Xianshuo Wei, Chunxin Ma, Hongliang Zhao, Xiuling Yang, Xiaofan Ma, Chunmei Zhang, Gaigai Duan

Summary: In this study, a light-responsive composite actuator was developed by combining inkjet-printed tissue paper with PNIPAM hydrogel. The mechanical property of the composite actuator was highly enhanced due to the high strength of tissue paper and the strong interaction within the interface of the bilayer structure. Furthermore, remote manipulation of light-responsive actuation was achieved using a stamping graphite electrode with high efficiency of photothermal conversion. Biomimetic actuating devices based on the near-infrared (NIR) light response of the composite actuator were also remotely controlled. This work provides a simple strategy for the construction of biomimetic anisotropic actuators and inspires the exploration of new intelligent materials.

POLYMERS (2022)

Review Polymer Science

Nanocellulose-Based Adsorbents for Heavy Metal Ion

Rongrong Si, Junwen Pu, Honggang Luo, Chaojun Wu, Gaigai Duan

Summary: Nanocellulose-based adsorbents, with their unique properties including high specific surface area, excellent mechanical properties, and biocompatibility, are emerging as an environmentally friendly material platform for heavy metal ion removal. By introducing functional groups, nanocellulose-based adsorbents can remove single heavy metal ions and selectively adsorb multiple heavy ions.

POLYMERS (2022)

Article Chemistry, Multidisciplinary

A melanin-inspired robust aerogel for multifunctional water remediation

Peng Yang, Wanjie Bai, Yuan Zou, Xueqian Zhang, Yiyan Yang, Gaigai Duan, Jinrong Wu, Yuanting Xu, Yiwen Li

Summary: Inspired by melanin, researchers have created a multifunctional aerogel for water remediation. The aerogel effectively removes organic dyes and heavy metal ions contaminants in wastewater, while also exhibiting excellent underwater oil resistance and oil-water separation ability. It has an impressive evaporation rate and efficiency under sunlight, making it ideal for long-term water evaporation. This melanin-inspired aerogel offers new strategies for developing robust photothermal devices for solar-driven water remediation.

MATERIALS HORIZONS (2023)

Article Chemistry, Multidisciplinary

A bioinspired antibacterial and photothermal membrane for stable and durable clean water remediation

Yiyan Yang, Lei Yang, Fengying Yang, Wanjie Bai, Xueqian Zhang, Haotian Li, Gaigai Duan, Yuanting Xu, Yiwen Li

Summary: In this study, a solar-driven method for obtaining clean fresh water was developed. A cellulose membrane device coated with antibacterial and photothermal polydopamine nanoparticles was constructed, resulting in a high water evaporation rate and efficiency. Moreover, the membrane exhibited excellent durability for stable reuse in microbe-rich environments.

MATERIALS HORIZONS (2023)

Article Chemistry, Multidisciplinary

Preparation, Application and Enhancement Dyeing Properties of ZnO Nanoparticles in Silk Fabrics Dyed with Natural Dyes

Haijuan Du, Mengyuan Yue, Xin Huang, Gaigai Duan, Zhihui Yang, Weihan Huang, Wenjie Shen, Xiangfeng Yin

Summary: In this study, ZnO nanoparticles were synthesized with varying structures and morphologies using a hydrothermal method. These nanoparticles were then used as mordant for dyeing silk fabrics, and it was found that they could improve the dyeing properties and fastness.

NANOMATERIALS (2022)

Article Chemistry, Multidisciplinary

High mass-loading α-Fe2 O3 nanoparticles anchored on nitrogen-doped wood carbon for high-energy-density supercapacitor

Gaigai Duan, Hua Zhang, Chunmei Zhang, Shaohua Jiang, Haoqing Hou

Summary: In this study, alpha-Fe₂O₃ nanoparticles uniformly anchored on nitrogen-doped wood carbons were synthesized using a facile electrodeposition method followed by post-heating treatment. The resulting composite showed high specific capacitance and superior cycling stability, attributed to the synergistic effects of alpha-Fe₂O₃ nanoparticles, conductive matrix, and interfacial Fe-O-C bonding.

CHINESE CHEMICAL LETTERS (2023)

Article Biochemistry & Molecular Biology

Effect of Carbonization Temperature on Microstructures and Properties of Electrospun Tantalum Carbide/Carbon Fibers

Hongtao Guo, Xiaofan Ma, Qiqi Lv, Chunmei Zhang, Gaigai Duan

Summary: Compared with traditional metal materials, carbon-based materials have the benefits of low density, high conductivity, and good chemical stability, making them reliable alternative materials in various fields. Among them, the carbon fiber conductive network created by electrospinning technology possesses high porosity, high specific surface area, and abundant heterogeneous interfaces. By using tantalum carbide (TaC) nanoparticles as conductive fillers, the crystallization degree, electrical and mechanical properties of electrospun TaC/C nanofibers were investigated at different temperatures. The best mechanical properties of 12.39 MPa were achieved at a carbonization temperature of 1200 degrees C. Through comprehensive analysis and comparison, it can be concluded that a carbonization temperature of 1200 degrees C is the optimum.

MOLECULES (2023)

Review Biochemistry & Molecular Biology

Research Progress of the Ion Activity Coefficient of Polyelectrolytes: A Review

Aokai Zhang, Xiuling Yang, Feng Yang, Chunmei Zhang, Qixiong Zhang, Gaigai Duan, Shaohua Jiang

Summary: Polyelectrolyte, a complex physical system, has wide applications in biomedicine, agriculture, and soft robotics. This review presents a comprehensive description of experimental and theoretical studies on the activity coefficient, a crucial thermodynamic property of polyelectrolyte. Experimental methods including direct potentiometric measurement and indirect methods such as isopiestic measurement and solubility measurement were introduced. Various theoretical approaches, including analytical, empirical, and simulation methods, were discussed. Future development challenges were also proposed.

MOLECULES (2023)

Article Multidisciplinary Sciences

Single-cell RNA sequencing highlights intratumor heterogeneity and intercellular network featured in adamantinomatous craniopharyngioma

Yu Jiang, Jinlong Yang, Ruichao Liang, Xin Zan, Rangrang Fan, Baoyin Shan, Hao Liu, Li Li, Yue Wang, Min Wu, Xin Qi, Hongxu Chen, Qingqing Ren, Zhiyong Liu, Yuelong Wang, Jing Zhang, Peizhi Zhou, Qiang Li, Meng Tian, Jinhao Yang, Chaoyang Wang, Xueying Li, Shu Jiang, Liangxue Zhou, Gao Zhang, Yaohui Chen, Jianguo Xu

Summary: Through integrative analysis of 44,038 single-cell transcriptome profiles, the cellular atlas and biological features of adamantinomatous craniopharyngioma (ACP) were characterized, revealing intratumoral heterogeneity and the tumor microenvironment (TME). Pseudotime analyses suggested potential evolutionary trajectories between specific neoplastic cell states. Additionally, a tumor-centric regulatory network based on intercellular communication in TME was described. These findings provide valuable insights into the tumor heterogeneity of ACP and can improve clinical diagnosis and treatment strategies.

SCIENCE ADVANCES (2023)

Article Chemistry, Medicinal

Chiral Gd-DOTA as a Versatile Platform for Hepatobiliary and Tumor Targeting MRI Contrast Agents

Weiyuan Xu, Xinjian Ye, Min Wu, Xin Jiang, Lik Hang Hugo Tse, Yanjuan Gu, Kun Shu, Liuhui Xu, Yong Jian, Gengshen Mo, Jiao Xu, Yinghui Ding, Ruonan Gao, Jianliang Shen, Fangfu Ye, Zhihan Yan, Lixiong Dai

Summary: The leakage of gadolinium ions from commercial GBCAs is a safety concern in clinical MRI scans, and the lack of task-specific GBCAs limits their use in disease detection and imaging of specific biological regions. Ultrastable GBCAs were constructed by decorating chiral Gd-DOTA with a phenylic analogue, exhibiting high stability and outstanding inert nature. A hepatic-specific chiral Gd-DOTA was identified as a potential alternative to commercial Gd-EOB-DTPA, and combination with functional molecules favored its use as tumor targeting probes.

JOURNAL OF MEDICINAL CHEMISTRY (2023)

Review Polymer Science

Cellulose-Based Intelligent Responsive Materials: A Review

Sisi Chang, Zhangzhao Weng, Chunmei Zhang, Shaohua Jiang, Gaigai Duan

Summary: This review summarizes the research on cellulose-based intelligent responsive materials in recent years, including the characteristics and applications of different stimuli responses, as well as the future trends and research directions.

POLYMERS (2023)

Review Chemistry, Inorganic & Nuclear

Advances in the application of manganese dioxide and its composites for theranostics

Jiaqi Hao, Yu Zhao, Yiqi Ma, Beibei Liu, Yonglan Luo, Sulaiman Alfaifi, Xuping Sun, Min Wu

Summary: Manganese dioxide (MnO2) is a versatile transition-metal dioxide widely used in various fields such as catalysts, oxidants, ferrites, achromats, and battery materials. It is also increasingly utilized in disease diagnosis and treatment in the biomedical field. However, there is a lack of comprehensive review articles on the use of MnO2 in disease diagnosis and treatment. This review provides an overview of the latest developments in MnO2 nanomaterials, focusing on their applications as magnetic resonance, photoacoustic, and fluorescent contrast agents. The review also discusses the potential therapeutic applications of MnO2 nanomaterials and the challenges and prospects for their clinical use.

INORGANIC CHEMISTRY FRONTIERS (2023)

Article Chemistry, Multidisciplinary

Efficient removal of high- or low-concentration copper ions using diethylenetriamine-grafted electrospun polyacrylonitrile fibers

Yuyin Zhang, Keyu Wang, Gaigai Duan, Yiming Chen, Kunming Liu, Haoqing Hou

Summary: The heavy metal copper is a hazard to human health and the environment. A highly efficient and low-cost adsorbent, the aminated electrospun polyacrylonitrile (PAN) staple fiber, was prepared by grafting diethylenetriamine (DETA) onto the PAN fiber. The fiber showed high adsorption activity for copper ions and could reduce the concentration below 1 mg/L with a small amount of adsorbent at low copper ion concentrations.

NEW JOURNAL OF CHEMISTRY (2023)

Review Materials Science, Biomaterials

Shield-activated two-way imaging nanomaterials for enhanced cancer theranostics

Yang Xu, Zhaokun Nie, Nengyi Ni, Xinyu Zhang, Jia Yuan, Yuan Gao, Yufang Gong, Shuangqing Liu, Min Wu, Xiao Sun

Summary: This review discusses the design and mechanism of engineered nanomaterials with two-way imaging tuning, and their latest applications in cancer theranostics. By activating the separation of two components in the tumor microenvironment, the dual-mode imaging ability is enhanced. The challenges and future directions for improving these nanomaterials are also addressed.

BIOMATERIALS SCIENCE (2022)

Article Chemistry, Multidisciplinary

Exploring the degradation of silver nanowire networks under thermal stress by coupling in situ X-ray diffraction and electrical resistance measurements

Laetitia Bardet, Herve Roussel, Stefano Saroglia, Masoud Akbari, David Munoz-Rojas, Carmen Jimenez, Aurore Denneulin, Daniel Bellet

Summary: The thermal instability of silver nanowires leads to increased electrical resistance in AgNW networks. Understanding the relationship between structural and electrical properties of AgNW networks is crucial for their integration as transparent electrodes in flexible optoelectronics. In situ X-ray diffraction measurements were used to study the crystallographic evolution of Ag-specific Bragg peaks during thermal ramping, revealing differences in thermal and structural transitions between bare and SnO2-coated AgNW networks.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Recording physiological and pathological cortical activity and exogenous electric fields using graphene microtransistor arrays in vitro

Nathalia Cancino-Fuentes, Arnau Manasanch, Joana Covelo, Alex Suarez-Perez, Enrique Fernandez, Stratis Matsoukis, Christoph Guger, Xavi Illa, Anton Guimera-Brunet, Maria V. Sanchez-Vives

Summary: This study provides a comprehensive characterization of graphene-based solution-gated field-effect transistors (gSGFETs) for brain recordings, highlighting their potential clinical applications.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Metal oxide-embedded carbon-based materials for polymer solar cells and X-ray detectors

Sikandar Aftab, Hailiang Liu, Dhanasekaran Vikraman, Sajjad Hussain, Jungwon Kang, Abdullah A. Al-Kahtani

Summary: This study examines the effects of hybrid nanoparticles made of NiO@rGO and NiO@CNT on the active layers of polymer solar cells and X-ray photodetectors. The findings show that these hybrid nanoparticles can enhance the charge carrier capacities and exciton dissociation properties of the active layers. Among the tested configurations, the NiO@CNT device demonstrates superior performance in converting sunlight into electricity, and achieves the best sensitivity for X-ray detection.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Peptide-mediated targeted delivery of SOX9 nanoparticles into astrocytes ameliorates ischemic brain injury

Hyo Jung Shin, Seung Gyu Choi, Fengrui Qu, Min-Hee Yi, Choong-Hyun Lee, Sang Ryong Kim, Hyeong-Geug Kim, Jaewon Beom, Yoonyoung Yi, Do Kyung Kim, Eun-Hye Joe, Hee-Jung Song, Yonghyun Kim, Dong Woon Kim

Summary: This study investigates the role of SOX9 in reactive astrocytes following ischemic brain damage using a PLGA nanoparticle plasmid delivery system. The results demonstrate that PLGA nanoparticles can reduce ischemia-induced neurological deficits and infarct volume, providing a potential opportunity for stroke treatment.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Spontaneous unbinding transition of nanoparticles adsorbing onto biomembranes: interplay of electrostatics and crowding

Anurag Chaudhury, Koushik Debnath, Nikhil R. Jana, Jaydeep K. Basu

Summary: The study investigates the interaction between nanoparticles and cell membranes, and identifies key parameters, including charge, crowding, and membrane fluidity, that determine the adsorbed concentration and unbinding transition of nanoparticles.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Autonomous nanomanufacturing of lead-free metal halide perovskite nanocrystals using a self-driving fluidic lab

Sina Sadeghi, Fazel Bateni, Taekhoon Kim, Dae Yong Son, Jeffrey A. Bennett, Negin Orouji, Venkat S. Punati, Christine Stark, Teagan D. Cerra, Rami Awad, Fernando Delgado-Licona, Jinge Xu, Nikolai Mukhin, Hannah Dickerson, Kristofer G. Reyes, Milad Abolhasani

Summary: In this study, an autonomous approach for the development of lead-free metal halide perovskite nanocrystals is presented, which integrates a modular microfluidic platform with machine learning-assisted synthesis modeling. This approach enables rapid and optimized synthesis of copper-based lead-free nanocrystals.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

In situ growth of a redox-active metal-organic framework on electrospun carbon nanofibers as a free-standing electrode for flexible energy storage devices

Zahir Abbas, Nissar Hussain, Surender Kumar, Shaikh M. Mobin

Summary: The rational construction of free-standing and flexible electrodes for electrochemical energy storage devices is an emerging research focus. In this study, a redox-active metal-organic framework (MOF) was prepared on carbon nanofibers using an in situ approach, resulting in a flexible electrode with high redox-active behavior and unique properties such as high flexibility and lightweight. The prepared electrode showed excellent cyclic retention and rate capability in supercapacitor applications. Additionally, it could be used as a freestanding electrode in flexible devices at different bending angles.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

A NIR-driven green affording-oxygen microrobot for targeted photodynamic therapy of tumors

Lishan Zhang, Xiaoting Zhang, Hui Ran, Ze Chen, Yicheng Ye, Jiamiao Jiang, Ziwei Hu, Miral Azechi, Fei Peng, Hao Tian, Zhili Xu, Yingfeng Tu

Summary: Photodynamic therapy (PDT) is a promising local treatment modality in cancer therapy, but its therapeutic efficacy is restricted by ineffective delivery of photosensitizers and tumor hypoxia. In this study, a phototactic Chlorella-based near-infrared (NIR) driven green affording-oxygen microrobot system was developed for enhanced PDT. The system exhibited desirable phototaxis and continuous oxygen generation, leading to the inhibition of tumor growth in mice. This study demonstrates the potential of using a light-driven green affording-oxygen microrobot to enhance photodynamic therapy.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Novel hollow MoS2@C@Cu2S heterostructures for high zinc storage performance

Yujin Li, Jing Xu, Xinqi Luo, Futing Wang, Zhong Dong, Ke-Jing Huang, Chengjie Hu, Mengyi Hou, Ren Cai

Summary: In this study, hollow heterostructured materials were constructed using an innovative template-engaged method as cathodes for zinc-ion batteries. The materials exhibited fast Zn2+ transport channels, improved electrical conductivity, and controlled volume expansion during cycling. The designed structure allowed for an admirable reversible capacity and high coulombic efficiency.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Mechanistic elucidation of the catalytic activity of silver nanoclusters: exploring the predominant role of electrostatic surface

Paritosh Mahato, Shashi Shekhar, Rahul Yadav, Saptarshi Mukherjee

Summary: This study comprehensively elucidates the role of the core and electrostatic surface of metal nanoclusters in catalytic reduction reactions. The electrostatic surface dramatically modulates the reactivity of metal nanoclusters.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Facile green synthesis of wasted hop-based zinc oxide nanozymes as peroxidase-like catalysts for colorimetric analysis

Pei Liu, Mengdi Liang, Zhengwei Liu, Haiyu Long, Han Cheng, Jiahe Su, Zhongbiao Tan, Xuewen He, Min Sun, Xiangqian Li, Shuai He

Summary: This study demonstrates a simple and environmentally-friendly method for the synthesis of zinc oxide nanozymes (ZnO NZs) using wasted hop extract (WHE). The WHE-ZnO NZs exhibit exceptional peroxidase-like activity and serve as effective catalysts for the oxidation of 3,3,5,5-tetramethylbenzidine (TMB) in the presence of hydrogen peroxide (H2O2). In addition, a straightforward colorimetric technique for detecting both H2O2 and glucose was developed using the WHE-ZnO NZs as peroxidase-like catalysts.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Impact of channel nanostructures of porous carbon particles on their catalytic performance

Hyunkyu Oh, Young Jun Lee, Eun Ji Kim, Jinseok Park, Hee-Eun Kim, Hyunsoo Lee, Hyunjoo Lee, Bumjoon J. Kim

Summary: Mesoporous carbon particles have unique structural properties that make them suitable as support materials for catalytic applications. This study investigates the impact of channel nanostructures on the catalytic activity of porous carbon particles (PCPs) by fabricating PCPs with controlled channel exposure on the carbon surface. The results show that PCPs with highly open channel nanostructures exhibit significantly higher catalytic activity compared to those with closed channel nanostructures.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Fabrication of a tough, long-lasting adhesive hydrogel patch via the synergy of interfacial entanglement and adhesion group densification

Yunjie Lu, Zhaohui Li, Zewei Li, Shihao Zhou, Ning Zhang, Jianming Zhang, Lu Zong

Summary: A tough, long-lasting adhesive and highly conductive nanocomposite hydrogel (PACPH) was fabricated via the synergy of interfacial entanglement and adhesion group densification. PACPH possesses excellent mechanical properties, interfacial adhesion strength, and conductivity, making it a promising material for long-term monitoring of human activities and electrocardiogram signals.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Strongly coupled plasmonic metal nanoparticles with reversible pH-responsiveness and highly reproducible SERS in solution

Zichao Wei, Audrey Vandergriff, Chung-Hao Liu, Maham Liaqat, Mu-Ping Nieh, Yu Lei, Jie He

Summary: We have developed a simple method to prepare polymer-grafted plasmonic metal nanoparticles with pH-responsive surface-enhanced Raman scattering. By using pH-responsive polymers as ligands, the aggregation of nanoparticles can be controlled, leading to enhanced SERS. The pH-responsive polymer-grafted nanoparticles show high reproducibility and sensitivity in solution, providing a novel approach for SERS without the need for sample pre-concentration.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Unlocking the full potential of citric acid-synthesized carbon dots as a supercapacitor electrode material via surface functionalization

Melis Ozge Alas Colak, Ahmet Gungor, Merve Buldu Akturk, Emre Erdem, Rukan Genc

Summary: This research investigates the effect of functionalizing carbon dots with hydroxyl polymers on their performance as electrode materials in a supercapacitor. The results show that the functionalized carbon dots exhibit excellent electrochemical performance and improved stability.

NANOSCALE (2024)