Article
Chemistry, Multidisciplinary
Kanghyeon Kim, Taehun Kim, Gawon Song, Seonghyun Lee, Min Soo Jung, Seongmin Ha, A. Reum Ha, Kyu Tae Lee
Summary: Argyrodite-type Li6PS5Cl (LPSCl) has attracted attention as a solid electrolyte for all-solid-state batteries due to its high ionic conductivity and mechanical flexibility. However, the interface between LPSCl and cathode materials faces challenges such as electrochemical degradation. In this study, trimethylsilyl compounds were introduced as solid electrolyte additives to improve the interfacial stability between sulfide-based solid electrolytes and cathode materials, resulting in excellent electrochemical performance and enhanced cycle life.
Article
Chemistry, Physical
Madison Olson, Jacob Wheaton, Mary Okkema, Nicholas Oldham, Steve W. Martin
Summary: Na4P2S7-6xO4.62xN0.92x (NaPSON) glassy solid electrolytes (GSEs) were studied for their electrochemical properties and processability into thin films. The x = 0.2 composition (NaPSON-2) showed high conductivity, non-crystallizability, stability against Na-metal, and support for symmetric cell cycling. Thin films of NaPSON-2 exhibited unchanged conductivity and slow growth in resistance, while NaPSON-2 disc displayed stability and reaction products in the bulk. The surface stability was attributed to the segregation of trigonally coordinated nitrogen.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Bo-Sheng Zhao, Lu Wang, Peng Chen, Sheng Liu, Guo-Ran Li, Ning Xu, Meng-Tao Wu, Xue-Ping Gao
Summary: Glass-ceramic sulfide solid electrolytes like Li7P3S11 are practical propellants for all-solid-state lithium-sulfur batteries, but stability and conductivity issues persist. Through a congener substitution strategy, Li7P3S1 was optimized to Li7P2.9Sb0.1S10.75 with improved chemical stability and high ionic conductivity. The electrolyte exhibited high discharge capacities, remarkable rate performance, and high Coulombic efficiency in the ASSLSB.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Su-Yeon Jung, Rajesh Rajagopal, Kwang-Sun Ryu
Summary: The study involved the preparation of (100-x)Li7P3S11-x Li3SI solid electrolyte composites by mechanical ball milling process, which effectively influenced the ionic conductivity and electrochemical properties of Li7P3S11 solid electrolyte. The addition of Li3SI improved the stability and capacity retention of the Li7P3S11 electrolyte, thus enhancing electrochemical performance.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Chemistry, Physical
Min-ho Park, Rajesh Rajagopal, Kwang-Sun Ryu
Summary: In this study, solid electrolytes with improved performance were synthesized by mixing Li3SI with stable to lithium metal and high ionic conductivity Li6PS5Cl. The mixed electrolyte showed high ionic conductivity and excellent electrochemical performance, providing a promising solid electrolyte material for solid-state lithium batteries.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Physical
Qifa Gao, Dengxu Wu, Xiang Zhu, Pushun Lu, Tenghuan Ma, Ming Yang, Liquan Chen, Hong Li, Fan Wu
Summary: By constructing an artificial solid electrolyte interphase (SEI), the performance of all-solid-state lithium metal batteries can be improved while overcoming the issues of interfacial reactions and dendrite penetration. The passivated artificial SEI shows high current density and cycling performance.
Review
Chemistry, Physical
Alex M. Bates, Yuliya Preger, Loraine Torres-Castro, Katharine L. Harrison, Stephen J. Harris, John Hewson
Summary: This work presents the first thermodynamic models to evaluate the heat release of both solid-state and Li-ion batteries under failure scenarios. It is found that all-solid-state batteries can reach significantly higher temperatures than conventional Li-ion batteries, which could lead to fire accidents.
Review
Chemistry, Physical
Xinyang Wang, Kuang He, Siyuan Li, Jiahui Zhang, Yingying Lu
Summary: Sulfide solid electrolyte (SE) and silicon anodes play important roles in all-solid-state batteries (ASSBs), but the bulk instability of sulfide SE and poor utilization of silicon materials pose significant challenges. Improving strategies for sulfide SEs and factors affecting silicon-sulfide SE compatibility, such as carbon's effect and particle size of silicon, need to be considered.
Article
Materials Science, Multidisciplinary
Lei Xi, Yu Li, Dechao Zhang, Zhengbo Liu, Xijun Xu, Jun Liu
Summary: This study presents a novel method for the development of high-performance all-sulfide-based solid-state batteries by using a dissoluble sulfide electrolyte and a MOF-derived composite cathode.
ENERGY & ENVIRONMENTAL MATERIALS
(2022)
Article
Electrochemistry
Luhan Ye, Eva Gil-Gonzalez, Xin Li
Summary: The study reports on the air stability and ionic conductivity of a new family of sulfide solid state electrolytes, demonstrating their stability in high humidity environments and potential application in lithium metal anode solid-state batteries.
ELECTROCHEMISTRY COMMUNICATIONS
(2021)
Article
Engineering, Environmental
Yang Li, Selim Halacoglu, Varun Shreyas, William Arnold, Xiaolin Guo, Qianqian Dou, Jacek B. Jasinski, Badri Narayanan, Hui Wang
Summary: This study demonstrates the use of an ionic liquid interlayer to address interfacial issues in sulfide-based solid-state sodium batteries (SSSBs). The interlayer stabilizes the Na metal/SSE interface, enabling the formation of a stable solid electrolyte interphase (SEI) and preventing harmful reactions and Na dendrite growth. Experimental and simulation results reveal that the stable SEI is composed of reduced products of TFSI-. Symmetric cells and FeS2||Na quasi-solid-state batteries exhibit stable cycling performance and high specific capacity.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Nanoscience & Nanotechnology
Grayson Deysher, Yu-Ting Chen, Baharak Sayahpour, Sharon Wan-Hsuan Lin, So-Yeon Ham, Phillip Ridley, Ashley Cronk, Erik A. Wu, Darren H. S. Tan, Jean-Marie Doux, Jin An Sam Oh, Jihyun Jang, Long Hoang Bao Nguyen, Ying Shirley Meng
Summary: All-solid-state batteries have gained attention for their potential improvements in safety, energy density, and cycle-life. Sodium all-solid-state batteries eliminate costly materials and are ideal for emerging grid energy storage applications. This study emphasizes the importance of solid electrolyte selection and presents three emerging solid electrolyte materials. The results demonstrate that stable cycling performance can be achieved by selecting appropriate materials for the anode and cathode interfaces.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Jianwei Li, Yuanyuan Li, Jun Cheng, Qing Sun, Linna Dai, Naixuan Ci, Deping Li, Lijie Ci
Summary: Sulfide-based solid electrolytes with high ionic conductivity and wide electrochemical window are a research hotspot for all-solid-state lithium batteries. However, the interface problem between the sulfide electrolyte and lithium metal remains a challenge. In this study, coating the Li2S layer on the surface of the sulfide solid electrolyte successfully improved the stability of lithium metal batteries.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Dongxu Liu, Qingtao Wang, Xuefang Ma, Qian Liu, Xiaozhong Zhou, Ziqiang Lei
Summary: This study investigates the doping of oxygen in Li10SnP2S12 electrolyte using solid-phase sintering method to improve the ionic conductivity and stability to lithium and air. The doped electrolyte shows enhanced conductivity, improved stability, and good cycling performance in all-solid-state batteries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Xinyang Wang, Wei Jiang, Xinxin Zhu, Siyuan Li, Shichao Zhang, Qian Wu, Jiahui Zhang, Wei Zhong, Shu Zhao, Hao Cheng, Yuanzhong Tan, Min Ling, Yingying Lu
Summary: A dynamically stable sulfide electrolyte architecture is reported in this study, which can inhibit dendrite growth and stabilize the polarization by designing multilayer structures. The electrolyte system plays an important role in maintaining long-term polarization stability, achieving high current densities, and steady over-potential. The battery also exhibits a high capacity retention rate in the cycling test.
Article
Chemistry, Multidisciplinary
Jichen Dong, Degong Ding, Chuanhong Jin, Yunqi Liu, Feng Ding
Summary: We present a systematic theoretical study on the CVD growth mechanism of MoS2 and propose a transition of growth from Mo-II edges to S-III edges and Mo-III edges by tuning the growth condition from Mo-rich to S-rich. This study provides a general guideline on theoretical studies of 2D crystals' growth mechanisms and deepens our understanding on the growth mechanism of multielement 2D crystals.
Article
Chemistry, Physical
Ziwei Xu, Feng Ding
Summary: This study reveals that the shape of the catalyst has an impact on the formation process of SWCNTs, and that using catalyst particles with higher curvature and catalytic reactions involving Pt adatom on the catalyst surface can promote the synthesis of SWCNTs.
Article
Chemistry, Physical
Yue Zou, Yukang Xiao, Yonglin Tang, Yong Cheng, Shi-Gang Sun, Ming-Sheng Wang, Yong Yang, Jianming Zheng
Summary: A hybrid coating layer of LaPO4 and Al2O3 is designed and constructed on the surface of LiCoO2 (LCO) cathode to improve its performance and cycle life at high voltage operation. The hybrid coating layer effectively suppresses side reactions and mitigates structural damage of LCO, resulting in significantly enhanced capacity retention after cycling.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Yiou Sun, Yu Su, Yong Cheng, Danhui Zhao, Xiaozhen Zhang, Zhongru Zhang, Yong Yang
Summary: In this study, a novel cyclic siloxane additive, TMDSi, was proposed to improve the capacity retention and suppress the dissolution of transition metal ions of Ni-rich cathode materials during long-term cycling. The working mechanism of TMDSi was revealed through various techniques, and it was found that TMDSi can effectively scavenge HF and form a protective film on the cathode surface to maintain its morphology and reduce parasitic side reactions. This bifunctional working mechanism makes TMDSi a promising electrolyte additive for Ni-rich cathode in Li-ion batteries.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Zaifa Wang, Zhenyu Wang, Dingchuan Xue, Jun Zhao, Xuedong Zhang, Lin Geng, Yanshuai Li, Congcong Du, Jingming Yao, Xinyu Liu, Zhaoyu Rong, Baiyu Guo, Ruyue Fang, Stephen J. Harris, Yong Su, Claude Delmas, Marnix Wagemaker, Liqiang Zhang, Yongfu Tang, Sulin Zhang, Lingyun Zhu, Jianyu Huang
Summary: The rock-salt phase (RSP) formed on the surface of Ni-rich layered cathodes in liquid-electrolyte lithium-ion batteries is considered electrochemically inactive. However, in sulfide based all solid state batteries (ASSBs), massive RSP forms in the interior of LiNixMnyCo(1_x-y)O2 (NMC) crystals and remains electrochemically active even after long cycles. The tensioned layered phase in ASSBs allows lithium to be squeezed out of RSPs by compressive stress, rendering the RSPs electrochemically active. This discovery enables the development of high energy density and durable ASSBs.
Article
Nanoscience & Nanotechnology
Jinxue Peng, Xuefan Zheng, Yuqi Wu, Cheng Li, Zhongwei Lv, Chenxi Zheng, Jun Liu, Haoyue Zhong, Zhengliang Gong, Yong Yang
Summary: In this study, an 85(92Li2S-8P2S5)-15AB composite cathode was developed by generating a Li3PS4 glassy electrolyte on Li2S active materials, resulting in enhanced electrode/electrolyte contact and ion/electron transport. The composite demonstrated superior electrochemical performance with high utilization of Li2S and a high reversible capacity even at high Li2S loading.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Tong Yuan, Jitong Yan, Qingfeng Zhang, Yong Su, Shuhong Xie, Bingan Lu, Jianyu Huang, Xiaoping Ouyang
Summary: The researchers synthesized a composite material consisting of Bi0.48Sb1.52Se3 nanoparticles uniformly dispersed in carbon nanofibers (Bi0.48Sb1.52Se3@C), which exhibited high capacity and cycling stability for potassium-ion batteries. The study reveals the stable potassium storage mechanisms of the Bi0.48Sb1.52Se3@C composite material, providing an effective strategy for high-performance potassium-ion batteries for energy storage applications.
Article
Chemistry, Multidisciplinary
Zhouliang Tan, Xiaoxuan Chen, Yunjiao Li, Xiaoming Xi, Shuaipeng Hao, Xiaohui Li, Xingjie Shen, Zhenjiang He, Wengao Zhao, Yong Yang
Summary: In this study, ZrTiO4 was used as an epitaxial layer for the first time to enhance the mechanical stability of ultrahigh-Ni LiNi0.9Co0.05Mn0.05O2 (NCM90). The conformal ZTO layers and Zr doping effectively suppressed the internal strain and the release of lattice oxygen, maintaining good mechanical stability and preventing electrolyte erosion.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Multidisciplinary Sciences
Lu Qiu, Xiuyun Zhang, Xiao Kong, Izaac Mitchell, Tianying Yan, Sung Youb Kim, Boris I. Yakobson, Feng Ding
Summary: In chemistry, the theory of aromaticity or pi bond resonance is crucial for understanding the stability and properties of organic molecules. This study presents an analogue theory for sigma bond resonance in flat boron materials, allowing for the determination of two-center two-electron and three-center two-electron bond distributions without quantum calculations. Based on this theory, three rules are proposed for drawing Kekule-like bonding configurations and exploring properties of flat boron materials. Additionally, the theory is applied to explain the stability of neutral borophene with approximately 1/9 hole occupancy and the effect of charge doping on borophene's optimal hole concentration. This theory enhances our understanding of boron materials and facilitates the rational design of boron-based materials.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Yong Su, Shuangxu Liu, Dingding Zhu, Yang Luo, Xuedong Zhang, Jitong Yan, Jingzhao Chen, Lin Geng, Baiyu Guo, Hui Li, Qiushi Dai, Hongjun Ye, Jingming Yao, Yunna Guo, Gang Wang, Yongfu Tang, Liqiang Zhang, Congcong Du, Jianyu Huang, Qiao Huang
Summary: In this study, FeF2 nanoparticles were embedded in an interconnected cPAN network to passivate the cathode/electrolyte interface. The cPAN acted as a superior binder and effectively inhibited the growth of excessive CEI. DFT calculations showed that cPAN was inert to the electrolyte and suppressed the catastrophic decomposition caused by FeF2.
ENERGY STORAGE MATERIALS
(2023)
Article
Engineering, Environmental
Yong Cheng, Xiaozhen Zhang, Qianyi Leng, Xuerui Yang, Tianpeng Jiao, Zhengliang Gong, Ming-Sheng Wang, Yong Yang
Summary: In this study, a cobalt-free, aluminum-doped Ni-rich cathode material was proposed and optimized through doping with high-valence molybdenum or tungsten. The introduction of Mo/W improved the structural integrity, cyclability, rate capability, and thermal stability of the material, resulting in enhanced electrochemical performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Yu Su, Xiangsi Liu, Hao Yan, Jun Zhao, Yong Cheng, Yu Luo, Jiabao Gu, Haoyue Zhong, Ang Fu, Kangjun Wang, Ming-sheng Wang, Jianyu Huang, Jiawei Yan, Yong Yang
Summary: Recently, all-solid-state lithium-ion batteries (ASSLBs) have gained significant attention, but degradation processes at the composite cathode interface, including side electrochemical reactions and morphological/structural degradation, still hinder their development. In this study, an elastic and sticky interfacial layer was successfully assembled for ASSLBs using molecular layer deposition (MLD) technique. This layer not only suppressed side reactions but also enabled close contact between NCM811 particles and the electrolyte. The results showed improved capacity retention and lower irreversible resistance compared to bare NCM811. This work highlights the importance of elastic and sticky coatings in maintaining the electrochemical-mechanical integrity of composite cathode materials for ASSLBs.
Article
Chemistry, Physical
Xiaohua Shen, Jianghua Zhang, Hao Chen, Hongtao Sun, Liqiang Zhang, Bailing Li, Hongmei Zhang, Xu Li, Shengyang Li, Jian Zhu, Xidong Duan
Summary: In this study, a novel separator-interface-scaffold microenvironment is developed for lithium metal batteries, which effectively prevents dendritic growth and improves the cycling stability. The resulting battery shows exceptional stability with dendrite-free cycling for over 5500 hours and stable cycling under high currents and deep plating/stripping.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Shi Zhou, Yiting Zhu, Haoran Hu, Chenghan Li, Jie Jiang, Jianyu Huang, Biao Zhang
Summary: By synthesizing porous organic polymers (POPs) with flexible modification at the molecular level, the LiF concentration in the solid electrolyte interface (SEI) can be optimized by tuning the fluorine atom substitution positions on the benzene rings of the POPs to boost the performance of solid-state lithium metal batteries (SSLMBs).
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Review
Electrochemistry
Baiyu Guo, Liqiang Zhang, Yongfu Tang, Jianyu Huang
Summary: This article provides a timely review of the operation principles and challenges of all-solid-state Li-Se batteries. It summarizes various strategies for designing and modifying the components of batteries, including Li anodes, solid-state electrolytes, and Se cathodes.
