4.6 Article

Lightweight, Low-Cost Co2SiO4@diatomite Core-Shell Composite Material for High-Efficiency Microwave Absorption

Journal

MOLECULES
Volume 27, Issue 3, Pages -

Publisher

MDPI
DOI: 10.3390/molecules27031055

Keywords

diatomite; Co2SiO4; electromagnetic wave absorption; nanomaterial

Funding

  1. National Natural Science Foundation of China [51908092]
  2. Fundamental Research Funds for the Central Universities [2020CDJXZ001, 2021CDJJMRH-005, SKLMT-ZZKT-2021M04]
  3. National Natural Science Foundation of China-Guangdong [U1801254]
  4. Chongqing Special Postdoctoral Science Foundation [XmT2018043]
  5. Chongqing Research Program of Basic Research and Frontier Technology [cstc2017jcyjBX0080]
  6. Natural Science Foundation Project of Chongqing [cstc2019jcyjbsh0079, cstc2019jcyjbshX0085]
  7. Chongqing Municipal Education Commission [KJZDK201800801]
  8. Innovative Research Team of Chongqing [CXTDG201602014]
  9. Innovative Technology of New Materials and Metallurgy [2019CDXYCL0031]
  10. Technology Innovation and Application Development Special Project of Chongqing [Z20211350, Z20211351]

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In this study, a porous and biomimetic cobalt silicate@diatomite material was successfully synthesized, and its electromagnetic wave absorption property was improved by controlling the composition and structure of the material. The experimental results showed that the Co2SiO4@diatomite composites exhibited low reflection loss and a wide absorption bandwidth, indicating promising high-efficiency microwave absorption capability.
The porous and biomimetic cobalt silicate@diatomite (Co2SiO4@diatomite) was successfully synthesized by a two-step method, including the hydrothermal method and calcination to improve the electromagnetic wave absorption property. Different hydrothermal times were well-tuned for Co2SiO4@diatomite composites with different loadings of Co2SiO4. Interestingly, the Co2SiO4@diatomite composites (6 h, 25 wt%) had a smaller minimum reflection loss. Moreover, the minimum reflection loss (RLmin) could reach -12.03 dB at 16.64 GHz and the matched absorber thickness was 10 mm, while the effective absorption bandwidth (EAB, RL <= -10 dB) could be 1.92 GHz. In principle, such findings indicate that Co2SiO4@diatomite nanocomposites could be a promising candidate for high-efficiency microwave absorption capability.

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