4.7 Article

Single-step extraction of functionalized cellulose nanocrystal and polyvinyl chloride from industrial wallpaper wastes

Journal

INDUSTRIAL CROPS AND PRODUCTS
Volume 89, Issue -, Pages 66-77

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.indcrop.2016.04.040

Keywords

Wallpaper wastes; Cellulose nanocrystals; Formate groups; Recyclable polyvinyl chloride; Reinforcing capability

Funding

  1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University [LK1428]
  2. National Natural Science Foundation of China [51403187, 51372226]
  3. public technology research plan of Zhejiang Province, China [2015C33111]
  4. 521 Talent Project of Zhejiang Sci-Tech University [2013YBZX01, 2015YXQN11]
  5. Top Priority Discipline of Zhejiang Province in Zhejiang Sci-Tech University [2013YBZX01, 2015YXQN11]
  6. Fresh Talent Program for Science and Technology Department of Zhejiang Province [2014R406020]
  7. Zhejiang Provincial Natural Science Foundation of China [LQ14E030007]

Ask authors/readers for more resources

An efficient route for extracting cellulose nanocrystals (CNCs) and recycling polyvinyl chloride (PVC) is presented through formic/hydrochloric acid hydrolysis of industrial wallpaper wastes (WS). The preparation parameters were optimized by using Box-Behnken design and Multiple-response surface methodology with desirability function. An optimum yield (54.0%) and aspect ratio (12.4) were achieved at reaction time of 10 h, liquid-solid ratio of 60 mL/g, and temperature of 80 degrees C. With the increasing reaction time, a gradual reduction in the size of the CNCs with rod-like and spherical shapes was found, which was explained by proposed mechanism-progressively peeling reaction. Moreover, compared to WS, the crystallinity and maximum degradation temperature of the CNC-10H increased to 89.8% and 371.4 degrees C, respectively. Furthermore, the CNC-10H showed stronger nucleating effect and reinforcing capability on polylactic acid than CNC-nanosphere and CNC-nanorod. In addition, PVC layers can be completely recycled, and further used to produce new wallpapers. (C) 2016 Elsevier B.V. All rights reserved.

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