4.6 Article

Lightweight, Refractory High-Entropy Alloy, CrNbTa0.25TiZr, with High Yield Strength

Journal

METALS AND MATERIALS INTERNATIONAL
Volume 28, Issue 2, Pages 448-455

Publisher

KOREAN INST METALS MATERIALS
DOI: 10.1007/s12540-021-01059-7

Keywords

Refractory high entropy alloys (HEA); Phase structure; Microstructure; Mechanical properties

Funding

  1. National Natural Science Foundation of China [51801124]
  2. Natural Science Foundation of Jiangsu Province of China [BK20181047]

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A lightweight, refractory high entropy alloy CrNbTa0.25TiZr was prepared by arc-melting under vacuum, with as-cast and annealed samples showing improvement in yield strength and lower density compared to a reference alloy. The evolution of the microstructure highlights the promising strength of CrNbTa0.25TiZr.
A new lightweight, refractory high entropy alloy (HEA), CrNbTa0.25TiZr, was prepared by arc-melting under a vacuum condition. The as-cast and annealed CrNbTa0.25TiZr possessed identical dual-phase components: a BCC + a cubic Laves phase. After annealing, the Laves phase matrix in the as-cast alloy was replaced by the BCC phase, possibly due to the diffusion of Cr, which have a much smaller atomic radius than the other principal elements. From a performance perspective, the yield strength significantly increased from 926 MPa of the as-cast HfNbTaTiZr to 1800 MPa and 1500 MPa for as-cast and annealed -CrNbTa0.25TiZr, while its density (7.25 g/cm(3)) is only 73% of HfNbTaTiZr. The microstructure evolution of the stiff cubic Laves phase is highlighted to unveil the promising strength of the CrNbTa0.25TiZr.

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