4.6 Article

Continuous and Simultaneous CO2 Absorption, Calcium Extraction, and Production of Calcium Carbonate Using Ammonium Nitrate

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 55, Issue 45, Pages 11795-11800

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.6b02880

Keywords

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Funding

  1. Human Resources Program in Energy Technology of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) - Ministry of Trade, Industry & Energy, Republic of Korea [20154010200810]
  2. Global Ph.D. Fellowship Program through the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2014H1A2A1021595]
  3. National Research Foundation of Korea [2014H1A2A1021595] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Carbon capture and utilization (CCU) technology is receiving notable attention because carbon capture and storage (CCS) technology has some limitations. Using solid waste or natural minerals, CO, capture can be achieved through the wet absorption-based CCU technology. This research proposes a novel process through which simultaneous and continuous carbon dioxide absorption, calcium component extraction, and production of calcium carbonate salt can be achieved. Also, recycling of the absorbent can be performed without requiring a thermal desorption step. The possibility of absorbent recovery was investigated, and the crystal structure of the produced calcium carbonate salt was proven to be vaterite. Based on the process, 0.566 tons of carbon dioxide was reduced per ton of CaO. The precipitated salt produced by carbonation reaction was determined to be vaterite by X-ray diffraction analysis and scanning electron microscopy images. To summarize, a continuous process using NH4NO3 is thought to have potential for application in industry.

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