Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 272, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2021.125049
Keywords
Electrocatalysis; Hydrogen evolution reaction; Carbon-based catalyst; Nickel
Categories
Funding
- Open Project of State Key Laboratory of Industrial Vent Gas Reuse [SKLIVGR-SWPU-2020-01]
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This study demonstrated that loading nickel particles on the surface of graphene and Cabot conductive carbon black Vxc-72 can enhance the hydrogen evolution performance. Particularly, Ni/Graphene exhibited excellent catalytic activity and stability in 1.0 M KOH media.
High-performance hydrogen evolution catalysts are compelling for the conversion of energy. In this work, nickel particles were loaded on the surface of two kinds of carbon-based materials (graphene and Cabot conductive carbon black Vxc-72) by using a mild chemical method. The prepared Ni/Graphene and Ni/Vxc-72 show excellent hydrogen evolution reaction performance in 1.0 M KOH media. In particular, the overpotential of Ni/ Graphene is only 29 mV (at 10 mA/cm2), and the Tafel slope is 87 mV/dec. It is also proved that Ni/Graphene has good stability by chronoamperometry and cyclic voltammetry. These findings suggest the loading nickel on the carbon-base catalysts can improve the hydrogen evolution performance.
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