Article
Materials Science, Composites
Wen Zhou, Jianyong Yu, Shichao Zhang, Bin Ding
Summary: In this study, fluorine-free polyamide/poly-dimethylsiloxane (PA/PDMS) composite nanofibrous waterproof and breathable membranes (WBMs) were successfully synthesized by direct electrospinning using alcohol-based green solvents. The resulting membranes exhibited excellent breathability, moisture permeability, and hydrostatic pressure performance, making them promising for applications in outdoor clothing, medical gowns, and wound dressings.
COMPOSITES COMMUNICATIONS
(2022)
Article
Materials Science, Multidisciplinary
Lulu Tian, Gaihuan Ren, Pan Zhang, Bo Li, Shuzhen Chang, Hongqin Yu, Rongwu Wang, Jianxin He
Summary: This study combines the electrospinning technique and the UV-initiated thiol-ene click reaction to produce fluorine-free waterproof and breathable nanofibrous membranes with excellent properties, suitable for use in protective garments and oil-water separation.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2022)
Review
Chemistry, Multidisciplinary
Xiaobao Gong, Xia Yin, Fei Wang, Xiaoyan Liu, Jianyong Yu, Shichao Zhang, Bin Ding
Summary: This article provides a systematic overview of the recent progress in the design, fabrication, and application of waterproof and breathable nanofibrous membranes. It comprehensively analyzes the different design concepts and structural characteristics of each type of membrane, highlights representative applications, and presents the challenges and future perspectives associated with these membranes.
Article
Polymer Science
Ling Zhang, Junlu Sheng, Yongbo Yao, Zhiyong Yan, Yunyun Zhai, Zhongfeng Tang, Haidong Li
Summary: Waterproof breathable functional membranes have broad application prospects in outdoor textiles. Modifying the membranes with fluorine-free environmental nanofibrous membranes can improve the waterproof properties. In addition, the formation of bonding points and the in situ preparation of polyuria can effectively improve the mechanical properties.
Article
Materials Science, Multidisciplinary
Yang Li, Xuan Zhang, Yang Si, Jianyong Yu, Bin Ding
Summary: This study presents a simple yet effective strategy to design waterproof and breathable membranes (WBMs) using a polyurethane-based spinnable material through electrospinning technique. The resulting membranes exhibit super-elastic mechanical properties and multifunctional performance, making them suitable for extreme situations in the protection field.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Chemistry, Physical
Wen Zhou, Xiaobao Gong, Yang Li, Yang Si, Shichao Zhang, Jianyong Yu, Bin Ding
Summary: The environmentally friendly fluorine-free polyurethane nanofibrous membranes prepared via waterborne electrospinning demonstrate robust waterproof and breathable performances, along with high water contact angle, desirable water vapor transmission rate, good tensile elongation, and remarkable elasticity, showing strong potential for various applications without leaving toxic solvent residues.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Huijia Wang, Liang Chen, Yuqing Yi, Yongjing Fu, Jie Xiong, Ni Li
Summary: An efficient chemical modification method was suggested in this study to prepare polyurethane/SiO2 nanofibrous membranes with superhydrophobicity and durability, providing a new perspective for waterproofing and moisture permeability.
ACS APPLIED NANO MATERIALS
(2022)
Article
Engineering, Environmental
Wen Zhou, Xiaobao Gong, Yang Li, Yang Si, Shichao Zhang, Jianyong Yu, Bin Ding
Summary: The study presents a method for preparing environmentally friendly waterborne polyurethane nanofibrous membranes with high waterproofness and breathability. These membranes exhibit excellent performance in terms of hydrostatic pressure, air permeability, water vapor transmission rate, and elasticity, providing high-level personal protection and comfortable microclimate in harsh environments. The successful construction of these intriguing nanofibrous membranes could inspire the green synthesis of fibrous materials for various applications.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Gaihuan Ren, Zhanzhao Li, Lulu Tian, Dongxu Lu, Yurui Jin, Yunhe Zhang, Bo Li, Hongqin Yu, Jianxin He, Dejun Sun
Summary: Environmentally friendly and high-performing fluorine-free silicon-based polyurethane/polymethyl methacrylate/polyvinyl butyral (Si-PU/PMMA/PVB) WBMs were prepared through easy electrospinning technology and post-heat treatment. The heat treatment decreased the maximum pore size of the fiber membrane, enhancing the waterproof ability, and also improved the mechanical properties. The resulting nanofiber membrane exhibited good water resistance, breathability, and tensile strength, making it suitable for special protective clothing and outdoor equipment.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Physical
Rong Liu, Chuan Zhou, Yiming Wang, Huijia Wang, Ni Li
Summary: Waterproof and breathable SiO2@PAN nanofibrous membranes with light-shielding properties were successfully fabricated. The membranes displayed durable water repellency, high breathability, and showed lower surface temperature when exposed to sunlight. This work provides a promising candidate for protective clothing.
APPLIED SURFACE SCIENCE
(2024)
Article
Materials Science, Composites
Xiaolu You, Hongbo Wang, Jianxin He, Kun Qi
Summary: In this study, excellent waterproof polyethylene terephthalate (PET) fibrous membranes were constructed using simple strategies. Fluorine-free hydrophobic polydimethylsiloxane (PDMS) was embedded into PET membranes via one-step electrospinning and heat treatment techniques. The resulting PET/PDMS membranes exhibited vigorous hydrophobic channels, small apertures, high porosity, and excellent water resistance (86.9 kPa), moisture permeability (5100 g m(-2) d(-1)), air permeability (6.97 mm s(-1)), and mechanical strength (6.27 MPa). These nanofiber membranes can serve as exceptional additional products for various applications.
COMPOSITES COMMUNICATIONS
(2023)
Article
Polymer Science
Liqiang Yi, Shuoshuo Wang, Lina Wang, Juming Yao, Jaromir Marek, Ming Zhang
Summary: A waterproof and breathable nanofibrous membrane with thermal-regulated performance and excellent mechanical property was fabricated using coaxial electrospinning. By optimizing morphology and pore structure, well-performed membranes were obtained. Loading octadecane into the fibers for thermal regulation sacrificed overall properties, but adding carbon nanotubes improved comprehensive performance. The best membrane achieved a hydrostatic pressure of 59.2 kPa, WVTR of 7.846 kg m(-2) d(-1), latent heat of 50.1 J g(-1), and tensile strength of 20.2 MPa, showing reference significance for multifunctional membrane synthesis.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Xiaobao Gong, Mingle Ding, Ping Gao, Yu Ji, Xianfeng Wang, Xiao-Yan Liu, Jianyong Yu, Shichao Zhang, Bin Ding
Summary: A novel strategy based on humidity induced electrospinning and electromeshing is developed to synthesize a dual-network structured nanofiber/mesh material for personal comfort management. The smart membranes exhibit high liquid repellency, improved breathability, and remarkable cooling performance, providing a new pathway for the design of advanced smart textiles for personal protection.
Article
Materials Science, Multidisciplinary
Lingling Cai, Li Xu, Yang Si, Jianyong Yu, Bin Ding
Summary: The study introduces a new method to create autoclavable ternary electrospun nanofibrous membranes (TENMs) for potential reuse of medical protective clothing. These membranes exhibit excellent waterproof-breathable function, high thermostable performance, and outstanding properties such as high moisture transmission rate, high hydrostatic pressure, high bacteria retention rate, high aerosol retention rate, and autoclave sterilization durability, paving the way for sustainable use of medical protective clothing in the future.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Polymer Science
Xiaowei Xing, Xiaoyu Zhang, Jian Fang, Hua Zhou, Haitao Niu
Summary: This study presents a facile and scalable method to fabricate waterproof breathable membranes using electrospinning and electrospraying. The composite nanofiber membranes exhibit excellent durability, breathability, and elasticity. This research is of great significance for the preparation of waterproof and breathable membranes with balanced properties.
Article
Polymer Science
Ying Wu, Qingquan Tang, Minghui Zhang, Zi Li, Wen Zhu, Zhengping Liu
Article
Polymer Science
Xiangwei Zhu, Congying Wei, Fang Zhang, Qingquan Tang, Qiang Zhao
MACROMOLECULAR RAPID COMMUNICATIONS
(2019)
Article
Chemistry, Applied
Qingquan Tang, Weiyi Zhang, Jiayin Yuan, Qiang Zhao
REACTIVE & FUNCTIONAL POLYMERS
(2019)
Article
Chemistry, Applied
Qingquan Tang, Ziyang Zhang, Jiang Gong, Qiang Zhao
REACTIVE & FUNCTIONAL POLYMERS
(2019)
Article
Engineering, Chemical
Huawen Peng, Qingquan Tang, Sihan Tang, Jiang Gong, Qiang Zhao
JOURNAL OF MEMBRANE SCIENCE
(2019)
Article
Materials Science, Multidisciplinary
Changyuan Song, Liang Hao, Boyi Zhang, Zhiyue Dong, Qingquan Tang, Jiakang Min, Qiang Zhao, Ran Niu, Jiang Gong, Tao Tang
SCIENCE CHINA-MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Qingquan Tang, Ke Zhang
Summary: This review discusses a polymer synthesis method based on a self-accelerating double-strain-promoted 1,3-dipole-alkyne cycloaddition (DSPDAC) click reaction, which can produce polymers with ultrahigh molecular weight. The method also demonstrates a stoichiometric imbalance-promoted step-growth polymerization approach and a unique bimolecular ring-closure method.
CHINESE JOURNAL OF CHEMISTRY
(2021)
Article
Polymer Science
Qingquan Tang, Hao Ren, Zdravko Kochovski, Lisheng Cheng, Ke Zhang, Jiayin Yuan, Weiyi Zhang
Summary: The topological geometry of poly(ionic liquid)s has a strong influence on their self-assembly behaviors. This study investigates the effects of cyclic topology on poly(ionic liquid)s by preparing linear and cyclic copolymers and studying their self-assembly phenomena. The results show that the average size of cyclic copolymers nanospheres is 46.2% smaller than linear copolymers nano-assemblies. The authors speculate that the spherical aggregates are formed through a transition from micelles with gradient block-like structures.
MACROMOLECULAR CHEMISTRY AND PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Mingchen Lu, Xuyi Wang, Hao Ren, Luoxin Wang, Qingquan Tang, Hua Wang
Summary: A facile electrospray technique combining breath figure or nonsolvent induced phase separation was developed to prepare microparticles with hierarchical pores and tunable morphologies. The as-prepared microparticles possess predominant micropores and abundant macropores with high surface areas, and exhibit enhanced selective adsorption abilities towards malachite green.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Applied
Haojie Chen, Xuyi Wang, Hao Ren, Mingchen Lu, Xin Cui, Luoxin Wang, Hua Wang, Qingquan Tang
Summary: A novel fluorene-based polymer, PFLTB, was synthesized for the first time through a Tro center dot ger's base reaction. It shows a high selectivity, sensitivity, and rapid fluorescent response to Fe3+. A PFLTB-based indicator film was fabricated and exhibited a fast response time of only 10 s to Fe3+. This work provides a novel and feasible approach to fabricating efficient polymer-based sensors for metal ions, which is of great importance for diverse industrial and engineering processes.
REACTIVE & FUNCTIONAL POLYMERS
(2022)
Article
Materials Science, Multidisciplinary
Hao Ren, Haojie Chen, Mingchen Lu, Xin Cui, Hua Wang, Luoxin Wang, Qingquan Tang
Summary: Polymer-based solar thermal fuels (PSTFs) with improved energy density and processability were successfully prepared by using 4-bromomethyl-azobenzene (Azo-Br) to quaternize polymers of intrinsic microporosity. The as-prepared Azo-PDAT showed higher energy density and storage capacity compared to the parent Azo-Br. In contrast, Azo-MTLE exhibited lower energy density due to the hindrance of photoisomerization and decreased micropores. The improved energy density of Azo-PDAT was attributed to the synergistic effect of cation-pi interactions, intrinsic microporosity, and template-enforced steric strain.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Engineering, Multidisciplinary
Shiqi Huang, Panlong Lin, Hao Huang, Liang Zhao, Changqing Zhu, Yan Yu, Zongmin Zhu, Kun Nie, Qingquan Tang, Luoxin Wang, Hua Wang
COMPOSITES PART B-ENGINEERING
(2020)
Article
Chemistry, Multidisciplinary
Qingquan Tang, Ran Niu, Jiang Gong
NEW JOURNAL OF CHEMISTRY
(2020)
Article
Chemistry, Physical
Qingquan Tang, Jiang Gong, Qiang Zhao
CATALYSIS SCIENCE & TECHNOLOGY
(2019)