One‐Step Sequence‐Selective Synthesis of Block Copolyester from Mixed Phthalic Anhydride, Cyclohexene Oxide, and δ ‐Valerolactone

A Lewis Pair as Organocatalyst for One-Pot Synthesis of Block Copolymers from a Mixture of Epoxide, Anhydride, and CO2

(2021) Jinbo Zhang et al.   MACROMOLECULES

Triethylborane-Assisted Synthesis of Random and Block Poly(ester-carbonate)s through One-Pot Terpolymerization of Epoxides, CO2, and Cyclic Anhydrides

(2021) Vamshi K. Chidara et al.   MACROMOLECULES

Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity

(2021) Alex J. Plajer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Semi‐Aromatic Di‐Block Polyesters by Terpolymerization of Macrolactones, Epoxides, and Anhydrides.

(2021) Mina Mazzeo et al.   ChemCatChem

Smart Access to Sequentially and Architecturally Controlled Block Polymers via a Simple Catalytic Polymerization System

(2021) Xiaochao Xia et al.   ACS Catalysis

Recent Developments in Ring-Opening Copolymerization of Epoxides With CO2 and Cyclic Anhydrides for Biomedical Applications

(2021) Xue Liang et al.   Frontiers in Chemistry

Sequence Control from Mixtures: Switchable Polymerization Catalysis and Future Materials Applications

(2021) Arron C. Deacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Constructing ABA- and ABCBA-Type Multiblock Copolyesters with Structural Diversity by Organocatalytic Self-Switchable Copolymerization

(2021) Chen Li et al.   MACROMOLECULES

Performance tailorable terpolymers synthesized from carbon dioxide, phthalic anhydride and propylene oxide using Lewis acid-base dual catalysts

(2021) Jiaxin Liang et al.   Journal of CO2 Utilization

Bimetallic Aluminum Complexes Bearing Binaphthyl-Based Iminophenolate Ligands as Catalysts for the Synthesis of Polyesters

(2020) Federica Santulli et al.   ORGANOMETALLICS

Lewis Pair Polymerization: Perspective on a Ten-Year Journey

(2020) Michael L. McGraw et al.   MACROMOLECULES

Metal-Free Approach for a One-Pot Construction of Biodegradable Block Copolymers from Epoxides, Phthalic Anhydride, and CO2

(2020) Shuxian Ye et al.   ACS Sustainable Chemistry & Engineering

One-Pot Synthesis of Diblock Polyesters by Catalytic Terpolymerization of Lactide, Epoxides, and Anhydrides

(2019) Yanchuan Zhou et al.   MACROMOLECULES

Easy access to oxygenated block polymers via switchable catalysis

(2019) Tim Stößer et al.   Nature Communications

One-Step Approach to Polyester–Polyether Block Copolymers Using Highly Tunable Bicomponent Catalyst

(2019) Heng Li et al.   ACS Macro Letters

Recent advances in thermoplastic elastomers from living polymerizations: Macromolecular architectures and supramolecular chemistry

(2019) Weiyu Wang et al.   PROGRESS IN POLYMER SCIENCE

Biased Lewis Pairs: A General Catalytic Approach to Ether-Ester Block Copolymers with Unlimited Ordering of Sequences

(2019) Shan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr-Salen Catalyst To Access ABA Block Polyesters

(2018) Tim Stößer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Making Various Degradable Polymers from Epoxides Using a Versatile Dinuclear Chromium Catalyst

(2018) Ye Liu et al.   MACROMOLECULES

One-Step Block Copolymer Synthesis versus Sequential Monomer Addition: A Fundamental Study Reveals That One Methyl Group Makes a Difference

(2018) Eduard Grune et al.   MACROMOLECULES

Multiblock Polyesters Demonstrating High Elasticity and Shape Memory Effects

(2018) Yunqing Zhu et al.   MACROMOLECULES

Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst

(2018) Thomas T. D. Chen et al.   MACROMOLECULES

Old meets new: Combination of PLA and RDRP to obtain sophisticated macromolecular architectures

(2018) Ilknur Yildirim et al.   PROGRESS IN POLYMER SCIENCE

Copolymerization of cyclic esters, epoxides and anhydrides: evidence of the dual role of the monomers in the reaction mixture

(2018) Florence Isnard et al.   Catalysis Science & Technology

Switch Catalysis To Deliver Multi-Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride

(2018) Tim Stößer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Step Access to Sequence-Controlled Block Copolymers by Self-Switchable Organocatalytic Multicomponent Polymerization

(2018) He-Yuan Ji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fast Access to Amphiphilic Multiblock Architectures by the Anionic Copolymerization of Aziridines and Ethylene Oxide

(2018) Tassilo Gleede et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequence-Selective Terpolymerization from Monomer Mixtures Using a Simple Organocatalyst

(2018) Heng Li et al.   ACS Macro Letters

Dual Polymerizations: Untapped Potential for Biomaterials

(2018) Daniel C. Lee et al.   Advanced Healthcare Materials

50th Anniversary Perspective: Polymers with Complex Architectures

(2017) George Polymeropoulos et al.   MACROMOLECULES

‘Switch’ catalysis: from monomer mixtures to sequence-controlled block copolymers

(2017) T. Stößer et al.   PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Macromolecular architectures through organocatalysis

(2017) Shuangyan Hu et al.   PROGRESS IN POLYMER SCIENCE

Self-Buffering Organocatalysis Tailoring Alternating Polyester

(2017) Heng Li et al.   ACS Macro Letters

Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides with Discrete Metal Complexes: Structure–Property Relationships

(2016) Julie M. Longo et al.   CHEMICAL REVIEWS

Chemoselective Polymerizations from Mixtures of Epoxide, Lactone, Anhydride, and Carbon Dioxide

(2016) Charles Romain et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

50th Anniversary Perspective: Block Polymers—Pure Potential

(2016) Christopher M. Bates et al.   MACROMOLECULES

The limits of precision monomer placement in chain growth polymerization

(2016) Guillaume Gody et al.   Nature Communications

Performance Enhancement of Electronic and Energy Devices via Block Copolymer Self-Assembly

(2015) Hyeon Gyun Yoo et al.   ADVANCED MATERIALS

Dinuclear Zinc Salen Catalysts for the Ring Opening Copolymerization of Epoxides and Carbon Dioxide or Anhydrides

(2015) Arnaud Thevenon et al.   INORGANIC CHEMISTRY

Selective Polymerization Catalysis: Controlling the Metal Chain End Group to Prepare Block Copolyesters

(2015) Yunqing Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequence Selective Polymerization Catalysis: A New Route to ABA Block Copoly(ester-b-carbonate-b-ester)

(2015) Shyeni Paul et al.   MACROMOLECULES

Semi-crystalline terpolymers with varying chain sequence structures derived from CO2, cyclohexene oxide and ε-caprolactone: one-step synthesis catalyzed by tri-zinc complexes

(2015) Yonghang Xu et al.   Polymer Chemistry

Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone

(2015) Yang Li et al.   Chemical Science

A “Catalyst Switch” Strategy for the Sequential Metal-Free Polymerization of Epoxides and Cyclic Esters/Carbonate

(2014) Junpeng Zhao et al.   MACROMOLECULES

Highly active bifunctional cobalt-salen complexes for the synthesis of poly(ester-block-carbonate) copolymerviaterpolymerization of carbon dioxide, propylene oxide, and norbornene anhydride isomer: Roles of anhydride conformation consideration

(2013) Zhongyu Duan et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Kinetic Studies of the Alternating Copolymerization of Cyclic Acid Anhydrides and Epoxides, and the Terpolymerization of Cyclic Acid Anhydrides, Epoxides, and CO2 Catalyzed by (salen)CrIIICl

(2012) Donald J. Darensbourg et al.   MACROMOLECULES

Multiblock Polymers: Panacea or Pandora's Box?

(2012) F. S. Bates et al.   SCIENCE

Architecturally Complex Polymers with Controlled Heterogeneity

(2011) K. Matyjaszewski   SCIENCE

Pre-Rate-Determining Selectivity in the Terpolymerization of Epoxides, Cyclic Anhydrides, and CO2: A One-Step Route to Diblock Copolymers

(2008) Ryan C. Jeske et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION