Lowering Electrocatalytic CO2 Reduction Overpotential Using N-Annulated Perylene Diimide Rhenium Bipyridine Dyads with Variable Tether Length

Molecular enhancement of heterogeneous CO2 reduction

(2020) Dae-Hyun Nam et al.   NATURE MATERIALS

Breaking Scaling Relationships in CO2 Electroreduction with Isoelectronic Analogs [Fe4N(CO)12]− and [Fe3MnO(CO)12]−

(2020) Cody R. Carr et al.   ORGANOMETALLICS

Homogeneous Electrochemical Reduction of CO2 to CO by a Cobalt Pyridine Thiolate Complex

(2020) Md Estak Ahmed et al.   INORGANIC CHEMISTRY

Tuning Second Coordination Sphere Interactions in Polypyridyl–Iron Complexes to Achieve Selective Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide

(2020) David Z. Zee et al.   INORGANIC CHEMISTRY

The electrochemical response of core-functionalized naphthalene Diimides (NDI) – a combined computational and experimental investigation

(2020) Cedrik Wiberg et al.   ELECTROCHIMICA ACTA

Sensitized photochemical CO2 reduction by hetero-Pacman compounds linking a Re(I) tricarbonyl with a porphyrin unit

(2019) Philipp Lang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Isolation of a Stable Perylenediimide Radical Anion and Its Exceptionally Electron-Deficient Precursor

(2019) Yogendra Kumar et al.   ORGANIC LETTERS

Effect of Electronic Coupling on Electron Transfer Rates from Photoexcited Naphthalenediimide Radical Anion to Re(bpy)(CO)3X

(2019) Jose F. Martinez et al.   Journal of Physical Chemistry C

Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

(2019) Md Golam Kibria et al.   ADVANCED MATERIALS

What would it take for renewably powered electrosynthesis to displace petrochemical processes?

(2019) Phil De Luna et al.   SCIENCE

Heterogeneous Aqueous CO2 Reduction Using a Pyrene-Modified Rhenium(I) Diimine Complex

(2019) Soumalya Sinha et al.   INORGANIC CHEMISTRY

Spectroscopic, electrochemical and electrocolorimetric properties of novel 2-(2′-pyridyl)-1H-benzimidazole appended bay-substituted perylene diimide triads

(2019) Fatih Pekdemir et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

Molecular electrocatalysts can mediate fast, selective CO2 reduction in a flow cell

(2019) Shaoxuan Ren et al.   SCIENCE

Kinetics and Mechanism of Intramolecular Electron Transfer in Ru(II)–Re(I) Supramolecular CO2–Reduction Photocatalysts: Effects of Bridging Ligands

(2019) Yasuomi Yamazaki et al.   INORGANIC CHEMISTRY

Bridge-Mediated Charge Separation in Isomeric N-Annulated Perylene Diimide Dimers

(2019) Yuanyuan Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Immobilized Molecular Wires on Carbon-Cloth Electrodes Facilitate CO2 Electrolysis

(2019) Nicholas M. Orchanian et al.   ACS Catalysis

Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices

(2019) Chuan Xia et al.   Nature Energy

Fulvalene Embedded Perylene Diimide and Its Stable Radical Anion

(2019) Andong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine

(2019) Min Wang et al.   Nature Communications

A Unified Electro- and Photocatalytic CO2 to CO Reduction Mechanism with Aminopyridine Cobalt Complexes

(2019) Sergio Fernández et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic CO2 Reduction Mediated by Electron Transfer via the Excited Triplet State of Zn(II) Porphyrin

(2019) Yusuke Kuramochi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Voltage Matters When Reducing CO2 in an Electrochemical Flow Cell

(2019) Danielle Salvatore et al.   ACS Energy Letters

Photoelectrochemical CO2 Reduction Using a Ru(II)–Re(I) Supramolecular Photocatalyst Connected to a Vinyl Polymer on a NiO Electrode

(2018) Ryutaro Kamata et al.   ACS Applied Materials & Interfaces

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts

(2018) Robert Francke et al.   CHEMICAL REVIEWS

Synthesis of a Perylene Diimide Dimer with Pyrrolic N-H Bonds and N-Functionalized Derivatives for Organic Field-Effect Transistors and Organic Solar cells

(2018) Gregory Charles Welch et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Activation of Co(I) State in a Cobalt-Dithiolato Catalyst for Selective and Efficient CO2 Reduction to CO

(2018) Subal Dey et al.   INORGANIC CHEMISTRY

Electron Transfer from Photoexcited Naphthalene Diimide Radical Anion to Electrocatalytically Active Re(bpy)(CO)3Cl in a Molecular Triad

(2018) Jose F. Martinez et al.   Journal of Physical Chemistry C

Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons

(2018) Yansong Zhou et al.   Nature Chemistry

Investigation of excited state, reductive quenching, and intramolecular electron transfer of Ru(ii)–Re(i) supramolecular photocatalysts for CO2 reduction using time-resolved IR measurements

(2018) Kazuhide Koike et al.   Chemical Science

Highly Selective Molecular Catalysts for the CO2-to-CO Electrochemical Conversion at Very Low Overpotential. Contrasting Fe vs Co Quaterpyridine Complexes upon Mechanistic Studies

(2018) Claudio Cometto et al.   ACS Catalysis

Kinetic and Mechanistic Effects of Bipyridine (bpy) Substituent, Labile Ligand, and Brønsted Acid on Electrocatalytic CO2 Reduction by Re(bpy) Complexes

(2018) Melissa L. Clark et al.   ACS Catalysis

Recent Advances in Electrochemical CO2 -to-CO Conversion on Heterogeneous Catalysts

(2018) Tingting Zheng et al.   ADVANCED MATERIALS

Synthesis of Molecular Dyads and Triads based upon N-Annulated Perylene Diimide Monomers and Dimers

(2018) Jonathan R. Cann et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Electrocatalytic CO2 Reduction with Cis and Trans Conformers of a Rigid Dinuclear Rhenium Complex: Comparing the Monometallic and Cooperative Bimetallic Pathways

(2018) Weiwei Yang et al.   INORGANIC CHEMISTRY

Redox “Innocence” of Re(I) in Electrochemical CO2 Reduction Catalyzed by Nanographene–Re Complexes

(2018) Richard N. Schaugaard et al.   INORGANIC CHEMISTRY

A Thiourea Tether in the Second Coordination Sphere as a Binding Site for CO2 and a Proton Donor Promotes the Electrochemical Reduction of CO2 to CO Catalyzed by a Rhenium Bipyridine-Type Complex

(2018) Eynat Haviv et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron transfer from photoexcited naphthalene-1,4:5,8-bis(dicarboximide) radical anion to Mn(bpy)(CO)3X and Re(bpy)(CO)3X CO2 reduction catalysts linked via a saturated methylene bridge

(2018) Jose F. Martinez et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

Decoding Proton-Coupled Electron Transfer with Potential–pKa Diagrams

(2017) Brian D. McCarthy et al.   INORGANIC CHEMISTRY

Well-Defined Nanographene–Rhenium Complex as an Efficient Electrocatalyst and Photocatalyst for Selective CO2 Reduction

(2017) Xiaoxiao Qiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thousandfold Enhancement of Photoreduction Lifetime in Re(bpy)(CO)3 via Spin-Dependent Electron Transfer from a Perylenediimide Radical Anion Donor

(2017) Svante Hedström et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Identifying and Breaking Scaling Relations in Molecular Catalysis of Electrochemical Reactions

(2017) Michael L. Pegis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning Product Selectivity for Aqueous CO2 Reduction with a Mn(bipyridine)-pyrene Catalyst Immobilized on a Carbon Nanotube Electrode

(2017) Bertrand Reuillard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic CO2 Reduction by Imidazolium-Functionalized Molecular Catalysts

(2017) Siyoung Sung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular Materials for Nonaqueous Flow Batteries with a High Coulombic Efficiency and Stable Cycling

(2017) Margarita Milton et al.   NANO LETTERS

Photoinduced electron transfer from rylenediimide radical anions and dianions to Re(bpy)(CO)3 using red and near-infrared light

(2017) Nathan T. La Porte et al.   Chemical Science

Recent progress in non-fullerene small molecule acceptors in organic solar cells (OSCs)

(2017) Wangqiao Chen et al.   Journal of Materials Chemistry C

Towards an intelligent design of molecular electrocatalysts

(2017) Cyrille Costentin et al.   Nature Reviews Chemistry

Synthesis, Self-Assembly, and Solar Cell Performance of N-Annulated Perylene Diimide Non-Fullerene Acceptors

(2016) Arthur D. Hendsbee et al.   CHEMISTRY OF MATERIALS

Structural and Spectroscopic Characterization of Rhenium Complexes Containing Neutral, Monoanionic, and Dianionic Ligands of 2,2′-Bipyridines and 2,2′:6,2″-Terpyridines: An Experimental and Density Functional Theory (DFT)-Computational Study

(2016) Mei Wang et al.   INORGANIC CHEMISTRY

Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO2-to-CO Conversion Catalyzed by Iron Porphyrins

(2016) Iban Azcarate et al.   Journal of Physical Chemistry C

Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H2-Evolution Catalysts

(2016) Noémie Elgrishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Graphite-Conjugated Rhenium Catalysts for Carbon Dioxide Reduction

(2016) Seokjoon Oh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improving the Efficiency and Activity of Electrocatalysts for the Reduction of CO2 through Supramolecular Assembly with Amino Acid-Modified Ligands

(2016) Charles W. Machan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoelectrochemical Reduction of CO2 Coupled to Water Oxidation Using a Photocathode with a Ru(II)–Re(I) Complex Photocatalyst and a CoOx/TaON Photoanode

(2016) Go Sahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO2 Reduction

(2016) Hiroyuki Takeda et al.   ACS Catalysis

Non-fullerene small molecule acceptors based on perylene diimides

(2016) Zhitian Liu et al.   Journal of Materials Chemistry A

Efficient Photocatalysts for CO2 Reduction

(2015) Go Sahara et al.   INORGANIC CHEMISTRY

An ambient stable core-substituted perylene bisimide dianion: isolation and single crystal structure analysis

(2015) Sabine Seifert et al.   Chemical Science

Comparison of rhenium–porphyrin dyads for CO2 photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy

(2015) Christopher D. Windle et al.   Chemical Science

Near-IR Phosphorescent Ruthenium(II) and Iridium(III) Perylene Bisimide Metal Complexes

(2014) Marcus Schulze et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photo- and Electrocatalytic Reduction of CO2by [Re(CO)3{α,α′-Diimine-(4-piperidinyl-1,8-naphthalimide)}Cl] Complexes

(2014) Federico Franco et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry

(2014) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Synthesis, Characterization, Physical Properties, and OLED Application of Single BN-Fused Perylene Diimide

(2014) Gang Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis

(2014) Matthew D. Sampson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supramolecular Assembly Promotes the Electrocatalytic Reduction of Carbon Dioxide by Re(I) Bipyridine Catalysts at a Lower Overpotential

(2014) Charles W. Machan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Contrasts between Manganese and Rhenium Bipyridine Electrocatalysts for the Reduction of Carbon Dioxide

(2014) Christoph Riplinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction using Infrared Spectroelectrochemistry

(2014) Charles W. Machan et al.   ORGANOMETALLICS

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

The Electronic States of Rhenium Bipyridyl Electrocatalysts for CO2Reduction as Revealed by X-ray Absorption Spectroscopy and Computational Quantum Chemistry

(2013) Eric E. Benson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon monoxide release catalysed by electron transfer: electrochemical and spectroscopic investigations of [Re(bpy-R)(CO)4](OTf) complexes relevant to CO2 reduction

(2013) Kyle A. Grice et al.   DALTON TRANSACTIONS

Catalysis of the electrochemical reduction of carbon dioxide

(2012) Cyrille Costentin et al.   CHEMICAL SOCIETY REVIEWS

Photochemistry offac-[Re(bpy)(CO)3Cl]

(2012) Shunsuke Sato et al.   CHEMISTRY-A EUROPEAN JOURNAL

Advances in molecular photocatalytic and electrocatalytic CO2 reduction

(2012) Christopher D. Windle et al.   COORDINATION CHEMISTRY REVIEWS

Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO

(2012) J. M. Smieja et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Integration of nitrogen into coronene bisimides

(2012) Linxiao Hao et al.   TETRAHEDRON

Re(bipy-tBu)(CO)3Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies

(2010) Jonathan M. Smieja et al.   INORGANIC CHEMISTRY

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

(2008) Jean-Michel Savéant   CHEMICAL REVIEWS

Architecture of supramolecular metal complexes for photocatalytic CO2 reduction

(2008) Kazuhide Koike et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

Stable Aromatic Dianion in Water

(2008) Elijah Shirman et al.   JOURNAL OF PHYSICAL CHEMISTRY B