Sterically Stabilized End-On Superoxocopper(II) Complexes and Mechanistic Insights into Their Reactivity with O–H, N–H, and C–H Substrates

A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity

(2021) Mayukh Bhadra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure, Spectroscopy, and Reactivity of a Mononuclear Copper Hydroxide Complex in Three Molecular Oxidation States

(2020) Tong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formylglycine-generating enzyme binds substrate directly at a mononuclear Cu(I) center to initiate O2activation

(2019) Mason J. Appel et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Mechanistic Dichotomy in Proton-Coupled Electron-Transfer Reactions of Phenols with a Copper Superoxide Complex

(2019) Wilson D. Bailey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Revisiting the Synthesis and Nucleophilic Reactivity of an Anionic Copper Superoxide Complex

(2019) Wilson D. Bailey et al.   INORGANIC CHEMISTRY

Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O−H and C−H Substrates

(2019) Daniel E. Diaz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes

(2018) E. W. Dahl et al.   CHEMICAL COMMUNICATIONS

Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes

(2018) Mayukh Bhadra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding Biological Hydrogen Transfer Through the Lens of Temperature Dependent Kinetic Isotope Effects

(2018) Judith P. Klinman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen Atom Abstraction Thermodynamics of a μ-1,2-Superoxo Dicopper(II) Complex

(2017) Nicole Kindermann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of dioxygen by copper metalloproteins and insights from model complexes

(2016) David A. Quist et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps

(2016) Laura Falivene et al.   ORGANOMETALLICS

Mechanism of O2activation and substrate hydroxylation in noncoupled binuclear copper monooxygenases

(2016) Ryan E. Cowley et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Developing Mononuclear Copper–Active-Oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions

(2015) Shinobu Itoh   ACCOUNTS OF CHEMICAL RESEARCH

Perturbing the Copper(III)–Hydroxide Unit through Ligand Structural Variation

(2015) Debanjan Dhar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Reactivity of a Copper(II)-Superoxide Complex

(2014) Paolo Pirovano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Active Sites in Biology

(2014) Edward I. Solomon et al.   CHEMICAL REVIEWS

Mechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric–Superoxo Complex

(2014) Jung Yoon Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox Properties of a Mononuclear Copper(II)-Superoxide Complex

(2013) Tetsuro Tano et al.   INORGANIC CHEMISTRY

Correlation of the Electronic and Geometric Structures in Mononuclear Copper(II) Superoxide Complexes

(2013) Jake W. Ginsbach et al.   INORGANIC CHEMISTRY

Stepwise Protonation and Electron-Transfer Reduction of a Primary Copper–Dioxygen Adduct

(2013) Ryan L. Peterson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Dioxygen Reactivity in a Sterically Demanding Tripodal Tetradentate tren Ligand: Formation and Reactivity of a Mononuclear Copper(II) End-On Superoxo Complex

(2012) Yuki Kobayashi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Active Site Models for the CuA Site of Peptidylglycine α-Hydroxylating Monooxygenase and Dopamine β-Monooxygenase

(2012) Atsushi Kunishita et al.   INORGANIC CHEMISTRY

Coordination Chemistry and Reactivity of a Cupric Hydroperoxide Species Featuring a Proximal H-Bonding Substituent

(2012) Sunghee Kim et al.   INORGANIC CHEMISTRY

Spectroscopic and computational characterization of CuII–OOR (R = H or cumyl) complexes bearing a Me6-tren ligand

(2011) Yu Jin Choi et al.   DALTON TRANSACTIONS

Rapid C–H Bond Activation by a Monocopper(III)–Hydroxide Complex

(2011) Patrick J. Donoghue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cupric Superoxo-Mediated Intermolecular C−H Activation Chemistry

(2011) Ryan L. Peterson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory

(2010) James M. Mayer   ACCOUNTS OF CHEMICAL RESEARCH

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Comparing the Enantioselective Power of Steric and Electrostatic Effects in Transition-Metal-Catalyzed Asymmetric Synthesis

(2010) Albert Poater et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spectroscopic and Computational Studies of an End-on Bound Superoxo-Cu(II) Complex: Geometric and Electronic Factors That Determine the Ground State

(2010) Julia S. Woertink et al.   INORGANIC CHEMISTRY

An Anionic, Tetragonal Copper(II) Superoxide Complex

(2010) Patrick J. Donoghue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An “End-On” Chromium(III)-Superoxo Complex: Crystallographic and Spectroscopic Characterization and Reactivity in C−H Bond Activation of Hydrocarbons

(2010) Jaeheung Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Predicting organic hydrogen atom transfer rate constants using the Marcus cross relation

(2010) J. J. Warren et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Mononuclear Copper(II)−Superoxo Complexes that Mimic the Structure and Reactivity of the Active Centers of PHM and DβM

(2009) Atsushi Kunishita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of Copper(II)-H2O2Adducts Supported by Tridentate Bis(2-pyridylmethyl)amine Ligands: Sensitivity to Solvent and Variations in Ligand Substitution

(2008) Atsushi Kunishita et al.   INORGANIC CHEMISTRY

H2O2-Reactivity of Copper(II) Complexes Supported by Tris[(pyridin-2-yl)methyl]amine Ligands with 6-Phenyl Substituents

(2008) Atsushi Kunishita et al.   INORGANIC CHEMISTRY

Hydride, Hydrogen Atom, Proton, and Electron Transfer Driving Forces of Various Five-Membered Heterocyclic Organic Hydrides and Their Reaction Intermediates in Acetonitrile

(2008) Xiao-Qing Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of a Copper(II) Superoxo Complex Lead to CH and OH Substrate Oxygenation: Modeling Copper-Monooxygenase CH Hydroxylation

(2007) Debabrata Maiti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION