4.7 Article

Multiscale super-amphiphobic ceramic membrane for oil aerosol removal

Journal

JOURNAL OF MEMBRANE SCIENCE
Volume 642, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.memsci.2021.119996

Keywords

SiC membrane; Super-amphiphobic; TiO2 nanocones; Oil aerosol removal

Funding

  1. National Key Research and Development Project of China [2018YFE0203500]
  2. National Natural Science Foundation of China [21921006, 21878148]
  3. Jiangsu Province Scientific Supporting Project [BK20170046, BZ2018004, BE2019117]

Ask authors/readers for more resources

A superamphiphobic ceramic membrane with TiO2/SiC composite was prepared, exhibiting excellent water and oil repelling properties. The membrane showed low static oil adsorption capacity and high rejection rate, making it suitable for long-term oil filtration.
1H, 1H, 2H, 2H-perfluorooctyltrichlorosilane (FOTS)-grafted TiO2/SiC membrane with multiscale superamphiphobic property was prepared by solvothermal growth followed by dipping treatment. TiO2 nanocones grown on silicon carbide (SiC) help to ameliorate the surface structure and chemical properties for grafting FOTS. The resulted membrane exhibits super-amphiphobicity with water and oil (n-hexadecane) contact angles of 171.9. and 151.2., respectively. The static oil adsorption capacity of the membrane is lower than 5%, indicating excellent oil repelling performance. Such an amphiphobic ceramic membrane can be used in long-term oil filtration with comparative low and stable pressure drop (11 kPa) and high rejection rate (98.24%). This work represents a new approach to achieve a super-amphiphobic surface on a solid ceramic membrane, opening a new avenue for the application of oil aerosol removal.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Chemical

Determining stability of organic solvent nanofiltration membranes by cross-flow aging

Ze-Xian Low, Junjie Shen

Summary: Through static aging experiments and cross-flow aging protocols, the stability of four commercial OSN membranes in different organic solvents was studied. The results showed that acetonitrile had the most significant effect on the membranes, and polyimide-based membranes exhibited signs of aging with increasing temperature. The new cross-flow aging protocol can facilitate rapid screening of OSN membranes for industrial use.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Engineering, Chemical

Machine Learning for Advanced Design of Nanocomposite Ultrafiltration Membranes

Masoud Fetanat, Mohammadali Keshtiara, Ze-Xian Low, Ramazan Keyikoglu, Alireza Khataee, Yasin Orooji, Vicki Chen, Gregory Leslie, Amir Razmjou

Summary: This study developed a graphical user interface platform using a neural network model to predict the performance of ultrafiltration nanocomposite membranes, saving time and resources in membrane design. Experimental data from the literature were used, and sensitivity analysis identified the most effective input variables for each nanocomposite membrane performance.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

Article Chemistry, Multidisciplinary

Two-dimensional N-doped Pd/carbon for highly efficient heterogeneous catalysis

Jiuxuan Zhang, Ze-Xian Low, Yanhua Shao, Hong Jiang, Rizhi Chen

Summary: The novel two-dimensional ZIF-derived Pd@CN material prepared via one-step calcination exhibits outstanding catalytic activity in heterogeneous hydrogenation. Its well-developed porous structure, low dimensions, and low density make active sites more accessible. This facile and effective strategy can guide the synthesis of highly active and durable Pd@CN catalysts with specific morphologies.

CHEMICAL COMMUNICATIONS (2022)

Review Engineering, Environmental

Porous metal-organic framework-based filters: Synthesis methods and applications for environmental remediation

Huan Xiao, Ze-Xian Low, Damian B. Gore, Ravinder Kumar, Mohsen Asadnia, Zhaoxiang Zhong

Summary: MOFilters, based on porous metal-organic frameworks, are hybrid materials used for environmental treatment. They can remove various pollutants and enhance the performance of current environmental treatment technologies through customizing their architectures and functionalities.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Universal water disinfection by piezoelectret aluminium oxide-based electroporation and generation of reactive oxygen species

Yang Zhao, Ze-Xian Low, Yifan Pan, Zhaoxiang Zhong, Guandao Gao

Summary: The piezo-catalytic disinfection system utilizing PEAO was shown to effectively kill various water microbes and improve oxidant utilization, leading to decreased formation of disinfection by-products. This technology has potential applications in various water treatment fields.

NANO ENERGY (2022)

Article Engineering, Chemical

Prediction and Optimization of Interlayer-Interface Resistance for Expanded Polytetrafluoroethylene-Laminated Polyphenylene Sulfide Composite Membranes

Wentai He, Ze-Xian Low, Shasha Feng, Qun Zhou, Feng Zhang, Zhaoxiang Zhong, Weihong Xing

Summary: This study investigates the interfacial effect on the air resistance of the ePTFE/PPS composite membrane through experimental and numerical simulation. It is found that profiled fibers with a smaller intersection angle and diameter ratio can effectively decrease the interlayer-interface resistance (IIR). Model modification parameters and air permeability effective coefficient are introduced to optimize the composite membrane.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2022)

Article Engineering, Chemical

Efficient removal of high-temperature particulate matters via a heat resistant and flame retardant thermally-oxidized PAN/PVP/SnO2 nanofiber membrane

Yutang Kang, Jiahao Chen, Shasha Feng, Huixian Zhou, Fangqi Zhou, Ze-Xian Low, Zhaoxiang Zhong, Weihong Xing

Summary: This study presents a nanofiber membrane with excellent performance for high-temperature particulate matter filtration. By performing thermally induced cyclization and oxidation reaction at 350 degrees C, a nanofiber membrane with superior PMs filtration performance is obtained. The membrane maintains high PMs removal efficiency at high temperature and exhibits fire-retarding and self-extinguishing properties.

JOURNAL OF MEMBRANE SCIENCE (2022)

Article Engineering, Chemical

Biocompatible curcumin coupled nanofibrous membrane for pathogens sterilization and isolation

Yuanyuan Rao, Shasha Feng, Ze-Xian Low, Junwei Wu, Shengui Ju, Zhaoxiang Zhong, Weihong Xing

Summary: An efficient antiviral personal protective filter was fabricated in this study, which exhibited good antibacterial and antiviral properties, as well as good gas permeability and particle rejection rate.

JOURNAL OF MEMBRANE SCIENCE (2022)

Article Engineering, Chemical

Readily processed multifunctional SiC catalytic filter for industrial emissions control

Jiahao Chen, Yongliang Yin, Ze-Xian Low, Kai Yuan, Wei Wei, Yiqing Zeng, Zhaoxiang Zhong, Weihong Xing

Summary: This study introduces a fast and efficient processing technique for SiC-based catalytic filters, using a one-step reactive thermal processing approach to fabricate SrTi1-xCoxO3-SiC (STC-SiC) catalytic filters. Acid etching enhances the formation of active nanoparticles on the STC catalysts, leading to improved adsorption and activation of oxygen and nitrogen oxides.

AICHE JOURNAL (2023)

Article Engineering, Chemical

Co-sintering of ceramic ultrafiltration membrane with gradient pore structures for separation of dye/salt wastewater

Dong Zou, Shiying Ni, Huandi Yao, Chang Hu, Ze-Xian Nicholas Low, Zhaoxiang Zhong

Summary: This study utilized a co-sintering process to fabricate alumina tight ultrafiltration (UF) membranes with gradient pore structures, showing high separation efficiency for treating dye wastewater with high salinity. The alumina membranes can reject almost 99% of dyes while allowing over 99% of salts to pass through, demonstrating great potential for practical applications.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Engineering, Chemical

Effect of relative humidity and dust moisture content on filtration performance of bag filter

Guangyu Zhou, Ze-Xian Low, Shasha Feng, Feng Zhang, Zhaoxiang Zhong, Weihong Xing

Summary: Bag filters are used to remove fine particulate matter from industrial flue gases. Moisture regulation and dust moisture content play a key role in reducing cake resistance.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Multidisciplinary Sciences

Pyro-layered heterostructured nanosheet membrane for hydrogen separation

Ruoxin Wang, Jianhao Qian, Xiaofang Chen, Ze-Xian Low, Yu Chen, Hongyu Ma, Heng-An Wu, Cara M. Doherty, Durga Acharya, Zongli Xie, Matthew R. Hill, Wei Shen, Fengchao Wang, Huanting Wang

Summary: Engineering heterostructured membranes using different two-dimensional materials is an effective way to design membranes for selective gas molecule transport. In this study, a simple and versatile pyro-layering approach was developed to fabricate heterostructured membranes using boron nitride nanosheets as the scaffold and graphene nanosheets derived from a chitosan precursor as the filler. The rearrangement of graphene nanosheets during the pyro-layering treatment formed precise nanochannels and spacing, enabling selective hydrogen transport.

NATURE COMMUNICATIONS (2023)

Article Chemistry, Physical

Metal oxyhydroxide nanosheet-assisted fabrication of ultrathin carbon molecular sieve membrane for hydrogen separation

Kaiqiang He, Yaoxin Hu, Ze-Xian Low, Ruoxin Wang, Fanmengjing Wang, Hongyu Ma, Xiaofang Chen, Douglas R. MacFarlane, Huanting Wang

Summary: In this study, ultrathin poly(furfuryl alcohol) nanocomposite layer was fabricated on a porous alumina support using FeCoNi oxyhydroxide nanosheets, and a carbon molecular sieve membrane was produced through carbonization. The transformation of FeCoNi oxyhydroxide nanosheets during the pyrolysis process improved the gas permeance of the carbon membrane, resulting in an excellent gas separation performance.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Multidisciplinary

A simple and versatile synthesis strategy of hollow MOFs for CO2 separation and catalysis

Yanhua Shao, Jie Xu, Ze-Xian Low, Chunhong Chen, Hong Jiang, Rizhi Chen

Summary: A novel method for synthesizing hollow MOFs using the self-deliquescence of hydration water in metallic precursors and low water solubility solvents at the two-phase interface is proposed. The resulting hierarchically porous hollow MOFs exhibit significant enhancements in CO2 separation and catalysis.

CHEMICAL COMMUNICATIONS (2022)

Article Engineering, Chemical

r-HGO/MXene composite membrane with enhanced permeability and rejection performance for water treatment

Jiawei Hou, Shixuan Guo, Nigel Graham, Wenzheng Yu, Kening Sun, Ting Liu

Summary: A novel 2D composite membrane based on r-HGO and MXene materials was developed, demonstrating exceptional performance for water treatment in terms of permeability, pollutant rejection, and physical stability. The optimization of preparation conditions and material proportions can result in high water flux and efficient removal of pollutants.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Designing a multifunctional TFC membrane with improved permeability and anti-biofouling performance using zwitterionic, quaternary ammonium, and fluorinated materials

Rui Gao, Caihong Liu, Andreia F. Faria, Qiang He, Chun Yang, Jun Ma

Summary: A novel copolymer architecture has been developed to address biofouling concerns in thin-film composite (TFC) membranes by integrating anti-fouling, bactericidal, and fouling-release functions. The multifunctional membrane demonstrates promising anti-adhesive properties, self-cleaning ability, and high flux recovery rate.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Defect-free asymmetric Matrimid® gas separation membranes using dihydrolevoglucosenone (Cyrene™) as a greener polar aprotic solvent than traditional solvents

Alexander T. Bridge, Noah P. Wamble, Matthew S. Santoso, Joan F. Brennecke, Benny D. Freeman

Summary: This study demonstrates the reproducible preparation of high-flux defect-free asymmetric gas separation membranes using Cyrene(TM) as a majority dope formulation component. By adjusting the volume ratios of Cyrene(TM) and THF, as well as the concentrations of Matrimid(R) and the dry step time, optimal membrane performance is achieved.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Nanofiber composite ultrafiltration membrane functionalized with cross-linked β-cyclodextrin for steroid hormone micropollutant removal

Alessandra Imbrogno, Han Ya Lin, Babak Minofar, Andrea Iris Schaefer

Summary: In this study, a composite nanofiber membrane containing cross-linked beta-cyclodextrin-epichlorohydrin was prepared and evaluated for the removal of steroid hormones. The results showed that the membrane had high adsorption capacity and the ability to form a specific inclusion complex interaction with the hormones, indicating its potential application in hormone removal.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Modeling the flux of volatile fatty acid in a membrane distillation with the effect of pH

Bora Shin, Jaewon Shin, Yanuar Chandra Wirasembada, Ki Young Park, Jinwoo Cho

Summary: This study develops a mathematical model to estimate the initial flux of volatile fatty acids in the direct contact membrane distillation process. It identifies the parameters affecting the flux and their relationship with pH.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Plasma-engineered GQD-inorganic membranes with tunable interactions for ultrahigh-efficiency molecular separations

Yi-Jui Yeh, Jr Rong Liou, Wei Lin, Kuo-Lun Tung, Wei-Hung Chiang

Summary: This study demonstrates an effective plasma engineering method to create nitrogen-doped graphene quantum dot (NGQD)-inorganic nanocomposites for tunable molecular separation. The composite materials show high separation efficiency and controllable nanopore structures, making them potentially valuable for various applications.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Water vapor sorption and transport in carbon molecular sieve membranes

Horacio Lopez-Marques, Kristofer L. Gleason, Manuel Aguilar-Vega, Rita Sulub-Sulub, J. Ehren Eichler, Hyeonji Oh, C. Buddie Mullins, Benny D. Freeman, Manish Kumar

Summary: In this study, water transport properties in Carbon Molecular Sieve (CMS) membranes were investigated. It was found that membranes synthesized at different pyrolysis temperatures exhibited varying water permeabilities. Compared to other polymeric materials, CMS membranes showed high water permeability, indicating potential for dehydration applications.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Vinyl-addition polynorbornenes with glycerol and diethylene glycol moieties: Synthesis and structure-property study

Dmitry A. Alentiev, Roman Yu. Nikiforov, Marina A. Rudakova, Danil P. Zarezin, Maxim A. Topchiy, Andrey F. Asachenko, Nikolay A. Belov, Maxim Bermeshev

Summary: A series of new norbornene-type monomers containing linear and branched substituents were synthesized, and robust thin membranes were prepared by vinyl-addition polymerization. Gas separation performance for the synthesized polymers was evaluated, and the structure of substituent side chains was found to significantly affect gas permeability and CO2 facilitated transport.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Hydrogel electrolyte membrane with regulated pore effect to stabilize zinc anode in aqueous zinc-ion batteries

Lei Yan, Qi Zhang, Ze Zhang, Gui-Jie Li, Yi Jin, Xin-Lin Zhang, Yan-Yun Sun

Summary: In this study, a continuous, stable and fast ion transport channel was established through in-situ guided cross-linking of zinc alginate hydrogels on a porous membrane, overcoming the negative pore effect and effectively inhibiting the dendrite growth of zinc anodes and interfacial side reactions.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Fabrication of an ultra-thin and ordered SPEEK proton exchange membrane by a Langmuir-Blodgett self-assembly process

Yuqing Zhang, Ailing Zhang, Huiyang He, Yuting Fan, Yongjiang Li, Song Wang, Sanxi Li

Summary: The Langmuir-Blodgett self-assembly process is used to create an ordered SPEEK membrane, which enhances the proton conductivity by three times compared to conventional solution casting method.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Estimating Gas Sorption In Polymeric Membranes From The Molecular Structure: A Machine Learning Based Group Contribution Method For The Non-Equilibrium Lattice Fluid Model (ML-GC-NELF)

Hasan Ismaeel, David Gibson, Eleonora Ricci, Maria Grazia De Angelis

Summary: In this study, a machine learning-based group contribution method (ML-GC) was developed to predict pure polymer parameters and successfully applied to predict gas solubility and gas solubility isotherms in glassy polymeric membranes. The model showed satisfactory performance on a small dataset, but has the potential to provide more accurate predictions for a wider range of polymers as more data becomes available.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Angular vibrations for fouling control during ultrafiltration of microalgae in a spiral wound module

Yi Ji, Yu Sun, Huilin Li, Qiang Fu, Yan Zhang

Summary: Previous studies have shown that vibration- or rotation-based techniques can effectively mitigate fouling during membrane filtration. However, it is difficult to incorporate these techniques with spiral wound modules (SWMs) widely used in water and wastewater treatment. This study developed a prototype membrane system to accommodate angular vibrations with a modified SWM, and experimental results showed that applying angular vibrations can effectively control algal fouling in an SWM with lower energy consumption compared to traditional methods.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Polyphenol-coated hollow fiber system for energy-efficient dehumidification in air-conditioning

Lakshmeesha Upadhayaya, Abaynesh Yihdego Gebreyohannes, Muhammad Wakil Shahzad, Usman T. Syed, Sandra L. Aristizabal, Radoslaw Gorecki, Suzana P. Nunes

Summary: Increasing temperatures worldwide pose a significant health risk, exacerbated by high humidity. Conventional air conditioners contribute heavily to carbon dioxide emissions, with dehumidification being a major factor. Membrane-based dehumidification system offers energy efficiency and non-toxic water vapor removal. This study demonstrates a membrane dehumidification system with polymeric hollow fibers coated with a green polyphenol coating, showing remarkable water vapor transport rate and selectivity. Long-term testing reveals minimal decline in vapor transport and a 4-5 times higher coefficient of performance (COP) compared to conventional dehumidifiers, making it a highly competitive, energy-saving device with reduced emissions and a smaller footprint.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

A facile method to fabricate anti-fouling nanofiltration membrane with aminated lignin

Zhengzhong Zhou, Xue Zhu, Yi Yuan, Shaoqiang Wang, Xiaoshan Meng, Taoli Huhe, Qian Wang

Summary: In this study, lignin, a biomass material, was chemically modified and utilized in the interfacial polymerization process to improve the performance of nanofiltration membranes. The modified membranes showed enhanced hydrophilicity and anti-fouling properties, and the optimization of membrane pore size increased permeability. The study also demonstrated the potential application of the membranes in biogas slurry valorization.

JOURNAL OF MEMBRANE SCIENCE (2024)