4.6 Article

The influence of Gd content on the microstructure, mechanical properties, corrosion behavior and corrosion film deposition mechanisms of as-extruded Mg-Zn-Mn-Sr-Gd alloys for biomedical applications

Journal

JOURNAL OF MATERIALS SCIENCE
Volume 57, Issue 3, Pages 2053-2072

Publisher

SPRINGER
DOI: 10.1007/s10853-021-06622-6

Keywords

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Funding

  1. National Natural Science Foundation of China [U1806220]
  2. Science and Technology Major Project of Shanxi Province [20201101011]
  3. Fundamental Research Funds for the Central Universities [FRF-TP18-043A1]

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The microstructure, corrosion behavior and corrosive film formation of Mg-2Zn-0.4Mn-0.1Sr-xGd alloys were studied. The addition of Gd led to the formation of Mg3Zn3Gd2 phase and grain refinement. The alloy with 0.5-1 wt% Gd exhibited better corrosion resistance and uniform corrosion behavior.
The microstructure, corrosion behavior and corrosive film formation of as-extruded Mg-2Zn-0.4Mn-0.1Sr-xGd alloys (x = 0, 0.5, 1 and 2 wt%) in Hank's solution were studied. Microstructure was investigated by scanning electron microscopy (SEM), scanning Kelvin probe force microscopy (SKPFM), X-ray photoelectron spectroscopy (XPS). Corrosion behavior was evaluated by immersion and electrochemical tests. The microstructural observations indicated that the addition of 0.5-2 wt% Gd led to the formation of Mg3Zn3Gd2 phase and grain refinement. SKPFM results showed that the Gd-rich (Mg3Zn3Gd2) phase was nobler than the alpha-Mg matrix in Gd-containing alloys and formed micro-galvanic corrosion. The alloy with 0.5-1 wt% Gd addition had better corrosion resistance and displayed uniform corrosion behavior than that Gd-free alloy. However, excessive Gd addition (2 wt%) decreased the corrosion rate and caused severe localized corrosion due to massive cathode Gd-rich particles. Combined with mechanical properties and corrosion resistance, the alloy with 1 wt% Gd exhibited a potential for degradable implant applications. The obtained superior corrosion resistance was due to the refined microstructure and the compactness of Gd-containing corrosion products film. In addition, a systematic discussion of corrosion behavior and corrosion film formation was provided by means of schematic illustration.

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