Review
Energy & Fuels
Divyam Jha, Pranjal Maheshwari, Yugank Singh, Mohd Belal Haider, Rakesh Kumar, M. S. Balathanigaimani
Summary: Extractive desulfurization has been found to be one of the most effective methods for desulfurizing liquid fuels. The factors that affect desulfurization include temperature, oil/ionic liquid (IL)/deep eutectic solvent (DES) mass ratio, extraction time, initial sulfur content, mutual solubilities, multiple cycles, and regeneration of used solvents in the extractive desulfurization (EDS) process. The results of this study are significant for solvent selection and setting criteria for the EDS process.
JOURNAL OF THE ENERGY INSTITUTE
(2023)
Article
Energy & Fuels
Naushad Khan, Vimal Chandra Srivastava
Summary: In this study, three deep eutectic solvents (DESs) were synthesized and utilized for extractive desulfurization (EDS), with a maximum sulfur extraction efficiency of 81.2% achieved under optimized conditions. The recyclability of DES affected the extraction efficiency, which was restored after regeneration. EDS kinetics were represented using pseudo first-, second-, and nth-order models.
Article
Energy & Fuels
Filipa Lima, Luis C. Branco, Armando J. D. Silvestre, Isabel M. Marrucho
Summary: This review article presents the use of deep eutectic solvents (DES) in removing sulfur pollutants from transportation fuels, highlighting the urgent need to reduce the impact of fossil fuels impurities on outdoor air pollution. A comparative evaluation with Ionic Liquids (ILs) shows that DES has advantages in extracting sulfur contaminants, but the efficiency gap between simulated matrices and real fuels is still a challenge to be addressed.
Review
Engineering, Environmental
Rashid Abro, Nusrat Kiran, Shoaib Ahmed, Atta Muhammad, Abdul Sattar Jatoi, Shaukat A. Mazari, Umme Salma, Natalia Plechkova
Summary: In the coming decades, the delivery of clean energy and its applications will be of utmost importance. Elimination of toxic emissions, particularly sulfur compounds, is essential for the survival of our planet. The use of extractive desulfurization (EDS) process with deep eutectic solvents (DESs) is a promising alternative to conventional hydrodesulfurization (HDS) technique. This review discusses the advantages and factors of EDS using DESs, as well as potential problems and flaws. DESs are recommended as preferable solvents for cleaner fuel oil production.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Energy & Fuels
Wenkang Ye, Tongmiao Wang
Summary: This study introduces a novel three-body deep eutectic solvent (DES) synthesized from nitromethylpyrrolidone (NMP) as a hydrogen bond acceptor (HBA) and benzoic acid (BEN) and water (H2O) as hydrogen bond donors (HBDs). It is used for extractive desulfurization (EDS) of model oil and analogue FCC gasoline. The results show that the three-body DES has higher activity, lower viscosity, and lower volatility, and the best desulfurization performance is achieved by a DES with a mass ratio of 8NMP/2BEN/0.06H2O containing 6 wt % water.
Article
Chemistry, Physical
Zhiguo Zhu, Hongying Lu, Ming Zhang, Hengquan Yang
Summary: This review focuses on the physicochemical properties of deep eutectic solvents (DESs) and their applications in desulfurization processes, with particular emphasis on recent advances in selective aerobic oxidation desulfurization (AODS) and the biomimetic approach coupling DESs with polyoxometallates (POMs). The strategy of combining DESs as multifunctional agents with POMs as electron transfer mediators offers a novel path for oxidation catalysis, overcoming challenges such as O-2 activation. The potential applications and future opportunities of DESs in catalysis science are also discussed.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Review
Energy & Fuels
Amir Aghaei, Mohammad Amin Sobati
Summary: This study investigates various aspects of the extractive desulfurization process using ILs and DESs, including the physical and chemical properties of solvents, the structure of solvents, the role of oxidants and catalysts in the process, and experimental conditions. Regeneration issues related to ILs and DESs compared to traditional organic solvents are also discussed, along with challenges and associated problems in using ILs and DESs in the EDS process. Research gaps and future research directions are highlighted for further studies.
Article
Chemistry, Physical
Alberto Gutierrez, Lorena Zamora, Cristina Benito, Mert Atilhan, Santiago Aparicio
Summary: This study investigates Type V natural deep eutectic solvents composed of menthol, thymol, and levulinic acids using a combined experimental and theoretical approach. The results provide insights into the intermolecular forces (hydrogen bonding) and their relationship with the macroscopic behavior of these solvents, informing their design and application.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Engineering, Chemical
Shu-Xian Zhu, Zhang-Min Li, Wen-Qiang Gong, Zi-Teng Gao, Hua Guan, Ming-Shuai Sun, Yan Zhou, Duan-Jian Tao
Summary: Due to inefficient pi-complexation of Cu+ sites, current available cuprous-based liquid absorbents have limited CO solubilities, which are far from equimolar CO capture. In this study, a novel cuprous-based quaternary deep eutectic solvent (DES) was prepared and used as a superior absorbent for equimolar CO capture. The cuprous-based quaternary DES [Emim]Cl-CuCl-ZnCl2-EG exhibited a remarkable CO uptake capacity (0.934 mol/mol, almost equimolar CO capture) and good ideal selectivities for CO/N2, CO/CO2, and CO/H2, making it the best liquid absorbent for efficient CO absorption.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Energy & Fuels
Jingyuan Ma, Shaocong Pang, Wei Zhou, Boru Xia, Yuxiu An
Summary: The study demonstrates that the four deep eutectic solvents effectively inhibit the hydration and swelling of shale, with Gly-DES showing the highest inhibition capability and not affecting the basic performance of drilling fluids. The electrostatic interaction and hydrogen bonding between the solvents and sodium bentonite are important factors in inhibiting clay hydration.
Article
Engineering, Chemical
Ge Cui, Dezhong Yang, Hongbin Qi
Summary: In this study, anion-functionalized deep eutectic solvents were synthesized for efficient SO2 capture, showing good reusability and reversibility. The high SO2 absorption capacity was attributed to the chemical reaction between SO2 and the anion, as well as the strong interaction between SO2 and the deep eutectic solvent.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Energy & Fuels
Jiawen Li, Chao Wang, Haoyu Wu, Jiaxuan Zhang, Ming Zhang, Qian Zhu, Yiqun Fan, Hui Liu, Wenshuai Zhu
Summary: Using alkaline ternary deep eutectic solvents (DESs) as absorbents, an effective and reversible strategy for capturing and recycling SO2 was proposed, showing great potential for environmental protection and high-value utilization.
Article
Chemistry, Physical
Lixian Xu, Yaping Luo, Hui Liu, Jie Yin, Hongping Li, Wei Jiang, Wenshuai Zhu, Huaming Li, Hongbing Ji
Summary: A novel amide-based deep eutectic solvent (DES) was synthesized and applied for desulfurization of fuels, showing high efficiency. Experimental and theoretical studies revealed the mechanism of desulfurization by this DES.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Energy & Fuels
Ahmed Reza Mahdavi, Mohammad Amin Sobati, Salman Movahedirad
Summary: The extractive desulfurization from the model fuel was studied in different micro-channels using triethylamine/propionic acid as DES. The effects of various operating parameters and micro-channel geometrical parameters on sulfur removal and mass transfer were investigated. Multiple extractive desulfurization cycles and regeneration of the spent DES were also studied. The results showed that the sulfur removal efficiency was high, and deep sulfur removal could be achieved using multiple-extraction cycles.
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
(2023)
Article
Engineering, Chemical
Linlan Wu, Zhengxin Jiao, Suhang Xun, Minqiang He, Lei Fan, Chao Wang, Wenshu Yang, Wenshuai Zhu, Huaming Li
Summary: A series of novel binary deep eutectic solvents (DESs) composed of choline chloride (ChCI) and formic acid (HCOOH) with different molar ratios have been successfully synthesized and applied in extractive desulfurization (EDS) with the help of a polyoxometallate ionic liquid catalyst. The optimization of molar ratios significantly improved the desulfurization capacity, and the photocatalytic oxidative process played a crucial role in the desulfurization system. The study demonstrates the efficiency of this approach in enhancing the extractive desulfurization performance in DES.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Environmental Sciences
Zulfiqar Ahmad Rehan, Muhammad Zahid, Sidra Kanwal, Nimra Nadeem, Asif Hafeez, Asif Jamil, Zakariya Zubair
Summary: Carboxylated graphene oxide (C-GO) embedded in polysulfone (PSF) membrane composites with different wt. % were prepared using the NIPS method and UF assembly, showing significant improvements in membrane efficiency and application in various research fields. The C-GO content in the polymer matrix was optimized and found to positively impact the permeation performance of the developed membranes. SEM, XRD, and FTIR were used to characterize the membranes in terms of surface morphology, crystallinity, and functional groups identification. Results showed that increasing the C-GO content increased the water permeability and hydrophilicity of the membranes, with M-3 membrane exhibiting the best performance in terms of water flux and efficient dye rejection. Photocatalytic testing of the M-3 membrane with 0.4% C-GO content showed high dye removal capability under UV-254 nm irradiation.
Article
Environmental Sciences
Amir Ikhlaq, Umar Fiaz, Osama Shaheen Rizvi, Asia Akram, Umair Yaqub Qazi, Zafar Masood, Mobeen Irfan, Khaled A. Alawi Al-Sodani, Mamoona Kanwal, Sami M. Ibn Shamsah, Rahat Javaid
Summary: The increasing water scarcity and depletion of natural resources have led to a challenging situation, pushing the scientific community to find alternative solutions. In this study, a hybrid treatment system was developed for the effective treatment and recycling of automobile service station wastewater. The results showed that the system was efficient for irrigation purposes.
Article
Materials Science, Multidisciplinary
S. Sadia Nimra, Z. A. Rehan, S. Hasan Ali, Salman Atir, Kinza Fatima, Fatima Shahzadi, H. M. Fayzan Shakir, Mohammed A. Alamir, Tarek Mohamed Ahmed Ali EL-Bagory, Imran Shahid
Summary: Polymerization was used to successfully coat polyester fibers (PEF) with Polyaniline (PANI), resulting in electrically conductive fibers (ECF). Analysis confirmed the synthesis and coating of PANI on the PEF surface. The coated fibers demonstrated improved DC conductivity, tensile strength, and modulus. The fabric showed effective blocking of UV and near-infrared rays, as well as high electromagnetic interference (EMI) shielding.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Chemistry, Analytical
Amara Nasrullah, Muhammad Zahid, Asghar Ali, Mirza Nadeem Ahmad, Adnan Mujahid, Tajamal Hussain, Usman Latif, Muhammad Imran Din, Adeel Afzal
Summary: In this study, polymer-based synthetic receptors incorporating Ag-ZnS microspheres in molecularly imprinted poly(methacrylic acid-co-ethylene glycol dimethacrylate) (MIPs) were designed for the gravimetric detection of human serum albumin (HSA). The MIPs with a methacrylic acid and ethylene glycol dimethacrylate volume ratio of 3:2 exhibited enhanced HSA sensitivity in the concentration range of 5-200 ng/mL. The quartz crystal microbalance (QCM) based gravimetric sensors achieved a remarkably low limit of detection (LOD = 0.364 ng/mL). The Ag-ZnS@MIPs/QCM sensors showed high selectivity for HSA compared to other proteins. Therefore, the gravimetric quantification of HSA enables a highly sensitive, selective, and label-free detection mechanism with a limit of quantification down to 1.1 ng/mL.
Article
Multidisciplinary Sciences
Faisal Saleem, Asif Hussain Khoja, Rabia Sharif, Abdul Rehman, Salman Raza Naqvi, Umair Yaqub Qazi, Kui Zhang, Adam Harvey
Summary: In this study, a DBD reactor was used to investigate the cracking of toluene into C1-C6 hydrocarbons. The effects of temperature (20-400 degrees C) and plasma power (10-40 W) on the reactor performance were studied. The main gaseous products from toluene decomposition were lower hydrocarbons (C1-C6). The cracking of toluene increased with power at all temperatures but decreased as the temperature increased from 20 to 400 degrees C. However, the methane yield increased with increasing temperature and plasma input power.
Article
Chemistry, Physical
Muhammad Zafarullah Kazim, Mudassir Ishfaq, Shatha A. Aldaghfag, Muhammad Zahid, Muhammad Yaseen
Summary: This study reports the physical characteristics of halide double perovskites, revealing their geometrical and thermodynamical stability as well as low bandgap behavior. The materials exhibit excellent optical conductivity in the infrared and visible range and have a high figure of merit at room temperature.
CHEMICAL PHYSICS LETTERS
(2023)
Article
Environmental Sciences
Noor Tahir, Muhammad Zahid, Asim Jillani, Suman Tahir, Muhammad Yaseen, Qamar Abbas, Rana Abdul Shakoor, Syed Zajif Hussain, Imran Shahid
Summary: The present study investigates and compares the photocatalytic and antibacterial activity of in situ Manganese doped ternary nanocomposites. The Mn-doped Ag2WO4 coupled with MoS2-GO and Mn-doped MoS2 coupled with Ag2WO4-GO both show efficient plasmonic catalysts for wastewater treatment. The nanocomposites exhibit excellent sunlight harvesting ability for dye degradation and show good photocatalytic stability.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2023)
Article
Electrochemistry
Rizwan Haider, Yi Wan, Yu Huang, Ayaz Muzammil, Renhuan Li, Muhammad Zahid, Asif Mahmood, Yi Fan, Xianxia Yuan
Summary: Hollow nitrogen-doped carbon spheres (HNCS-1000) with high onset and halfwave potentials, excellent stability, and durability have been successfully prepared. The ORR performance of HNCS-1000 surpasses most of the previously reported nitrogen-doped carbon catalysts, making it one of the best catalysts for ORR in alkaline environment.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Biochemistry & Molecular Biology
Muhammad Irfan, Noor Tahir, Muhammad Zahid, Saima Noreen, Muhammad Yaseen, Muhammad Shahbaz, Ghulam Mustafa, Rana Abdul Shakoor, Imran Shahid
Summary: Rapid industrialization and urbanization are significant issues causing environmental pollution. This study successfully improved the degradation efficiency of dyes by synthesizing a novel photocatalytic nanocomposite.
Article
Physics, Condensed Matter
Mehwish Khalid Butt, Shatha A. Aldaghfag, Muhammad Zafarullah Kazim, Muhammad Yaseen, Muhammad Zahid, Mudassir Ishfaq
Summary: The optoelectronic and magnetic properties of La1-xVxAlO3 perovskites were investigated using density functional theory. The effects of different percentages of vanadium substitution on the properties of LaAlO3 were studied and confirmed to be stable. The compounds exhibited half-metallic ferromagnetic behavior and showed potential for optoelectronic applications. The magnetic moment in La1-xVxAlO3 was mainly contributed by the V-3d states. The regulated reduction in bandgap with increasing V doping makes them suitable for spintronic and magnetic devices.
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
(2023)
Article
Chemistry, Physical
Tayyaba Jamil, Saima Yasin, Naveed Ramzan, Zaheer Aslam, Amir Ikhlaq, Umair Yaqub Qazi, Rahat Javaid
Summary: This study investigates the treatment of real textile wastewater using a novel bentonite clay/TiO2/ZnO-based ozonation catalyst. The results show that the synergic process using the clay/TiO2/ZnO catalyst has the highest removal efficiencies for COD and color in textile wastewater, under specific operating conditions.
Review
Energy & Fuels
Atif Khan, Muhammad Rashid, Abdul Rehman, Faisal Saleem, Salman Raza Naqvi, Shabana Afzal, Umair Y. Qazi, Waqar Ahmad, Iftikhar Nisar Butt, Khalid Mahmood
Summary: The use of fossil fuels has led to an increase in greenhouse gases, negatively impacting the environment and human health. The search for an alternative green fuel has brought attention to hydrogen, which has zero carbon emissions. Methane decomposition using gliding arc discharge reactors has been explored as a potential method for hydrogen production. This review focuses on the application of gliding arc discharge reactors for methane conversion, discussing the effects of various parameters on reactor performance.
JOURNAL OF THE ENERGY INSTITUTE
(2023)
Article
Chemistry, Physical
Abdul Saeed, Z. A. Rehan, Deyi Zhan, Muhammad Zahid, Qi Hu, Asif Ali Haider, Suman Tahir, Weihong Xu, Jinhuai Liu
Summary: The current global environmental challenge is largely caused by oil contamination, and the preparation of oil-water separation materials faces various issues. In this study, a superhydrophobic oil-water separation membrane was successfully prepared using a simple dip coating approach. The membrane exhibited excellent separation efficiency, mechanical stability, and reusability. This strategy offers a solution for constructing advanced oil-water separation membranes.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Energy & Fuels
Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen
Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
Article
Energy & Fuels
Mohammad Saeid Rostami, Mohammad Mehdi Khodaei
Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
Article
Energy & Fuels
Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang
Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
Article
Energy & Fuels
Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani
Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
Article
Energy & Fuels
Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi
Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
Article
Energy & Fuels
Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang
Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
Article
Energy & Fuels
Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz
Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
Article
Energy & Fuels
Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang
Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
Article
Energy & Fuels
He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi
Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
Article
Energy & Fuels
Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue
Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
Article
Energy & Fuels
Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq
Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
Article
Energy & Fuels
Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao
Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
Article
Energy & Fuels
Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy
Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
Article
Energy & Fuels
Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao
Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
Article
Energy & Fuels
Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li
Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.