Magnetic adsorbent developed with alkali-thermal pretreated biogas slurry solids for the removal of heavy metals: optimization, kinetic, and equilibrium study

Discharge of effluents containing heavy metal without adequate treatment causes contamination of water resources and creates environmental and health issues. Adsorption could be applied to remediate heavy metals from wastewater effectively. In this study, a low-cost adsorbent was prepared by magnetic modification of pretreated biogas slurry solids (BSS) to remove heavy metals such as Cu2+, Cd2+, and Pb2+. The temperature (423 K) and time (1.5 h) of pretreatment, the BSS to KOH ratio (1:10 w/v), and the ratio of magnetic iron nanoparticle (MIN) to pretreated BSS (PSS) (1:2 w/w) were optimized for the preparation of adsorbent. The magnetically modified pretreated biogas slurry solid (MMPSS) adsorbent was characterized by BET isotherm, FTIR, XRD, FESEM, VSM, and EDX analysis. MMPSS attained equilibrium at 60 min and showed an adsorption capacity of 26.84 mg/g, 24.79 mg/g, and 23.86 mg/g with removal percentages 89.46%, 82.63%, and 79.54% for Cu2+, Cd2+, and Pb2+, respectively, at 310 K and pH 6 with an initial concentration of 150 mg/L. The adsorption process followed a pseudo second-order model with an R-2 value above 0.9 for all metals with a well-approaching equilibrium pattern. The good fit of experimental data by the Langmuir isotherm model implied monolayer adsorption. The metal ions adsorbed onto MMPSS were able to desorb effectively in the presence of HCl and retained 83.01%, 84.66%, and 81.83% of the initial adsorption capacity for Cu2+, Cd2+, and Pb2+ respectively after 5 consecutive cycles.

Automated summary

In this study, a low-cost adsorbent was prepared by magnetic modification of pretreated biogas slurry solids (BSS) to effectively remove heavy metals from wastewater. The adsorbent showed good adsorption performance at 310 K and pH 6, and could be used for multiple cycles.