Dynamics and control of active sites in hierarchically nanostructured cobalt phosphide/chalcogenide-based electrocatalysts for water splitting

Delicate Control on the Shell Structure of Hollow Spheres Enables Tunable Mass Transport in Water Splitting

(2021) Ping Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visualizing the Conversion of Metal–Organic Framework Nanoparticles into Hollow Layered Double Hydroxide Nanocages

(2021) Wenhui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Constructing Atomic Heterometallic Sites in Ultrathin Nickel-Incorporated Cobalt Phosphide Nanosheets via a Boron-Assisted Strategy for Highly Efficient Water Splitting

(2021) Yufei Zhao et al.   NANO LETTERS

Redirecting dynamic surface restructuring of a layered transition metal oxide catalyst for superior water oxidation

(2021) Jian Wang et al.   Nature Catalysis

In Situ Reconstruction of V‐Doped Ni 2 P Pre‐Catalysts with Tunable Electronic Structures for Water Oxidation

(2021) Tingwen Zhao et al.   ADVANCED FUNCTIONAL MATERIALS

In Situ Anchoring Polymetallic Phosphide Nanoparticles within Porous Prussian Blue Analogue Nanocages for Boosting Oxygen Evolution Catalysis

(2021) Guangxun Zhang et al.   NANO LETTERS

Correlative operando microscopy of oxygen evolution electrocatalysts

(2021) J. Tyler Mefford et al.   NATURE

Self-Templating Strategies for Transition Metal Sulfide Nanoboxes as Robust Bifunctional Electrocatalysts

(2020) Yonggui Zhao et al.   CHEMISTRY OF MATERIALS

Operando Spectral and Electrochemical Investigation into the Heterophase Stimulated Active Species Transformation in Transition-Metal Sulfides for Efficient Electrocatalytic Oxygen Evolution

(2020) Miao Wang et al.   ACS Catalysis

Identifying Dense NiSe 2 /CoSe 2 Heterointerfaces Coupled with Surface High‐Valence Bimetallic Sites for Synergistically Enhanced Oxygen Electrocatalysis

(2020) Xuerong Zheng et al.   ADVANCED MATERIALS

Structural Designs and in‐situ X‐ray Characterizations of Metal Phosphides for Electrocatalysis

(2020) Youkui Zhang et al.   ChemCatChem

Dynamic active-site generation of atomic iridium stabilized on nanoporous metal phosphides for water oxidation

(2020) Kang Jiang et al.   Nature Communications

In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution

(2020) Fabio Dionigi et al.   Nature Communications

Approaching the activity limit of CoSe2 for oxygen evolution via Fe doping and Co vacancy

(2020) Yuhai Dou et al.   Nature Communications

Potential-Dependent Phase Transition and Mo-Enriched Surface Reconstruction of γ-CoOOH in a Heterostructured Co-Mo2C Precatalyst Enable Water Oxidation

(2020) Zongkui Kou et al.   ACS Catalysis

In Situ/Operando Studies for Designing Next-Generation Electrocatalysts

(2020) Yanping Zhu et al.   ACS Energy Letters

Vacancy Occupation-Driven Polymorphic Transformation in Cobalt Ditelluride for Boosted Oxygen Evolution Reaction

(2020) Ziliang Chen et al.   ACS Nano

Metal–Organic Framework‐Derived Co 2 P Nanoparticle/Multi‐Doped Porous Carbon as a Trifunctional Electrocatalyst

(2020) Haitao Liu et al.   ADVANCED MATERIALS

Operando Identification of the Dynamic Behavior of Oxygen Vacancy-Rich Co3O4 for Oxygen Evolution Reaction

(2020) Zhaohui Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Oxygen Evolution Catalyzed by Cobalt Oxyhydroxide: Cobalt Superoxide Species as a Key Intermediate and Dioxygen Release as a Rate-Determining Step

(2020) Aliki Moysiadou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lattice oxygen activation enabled by high-valence metal sites for enhanced water oxidation

(2020) Ning Zhang et al.   Nature Communications

Tailoring the d-Band Centers Endows (NixFe1–x)2P Nanosheets with Efficient Oxygen Evolution Catalysis

(2020) Shanfu Sun et al.   ACS Catalysis

Enabling Iron‐Based Highly Effective Electrochemical Water‐Splitting and Selective Oxygenation of Organic Substrates through In Situ Surface Modification of Intermetallic Iron Stannide Precatalyst

(2020) Biswarup Chakraborty et al.   Advanced Energy Materials

Bifunctional Single Atom Electrocatalysts: Coordination–Performance Correlations and Reaction Pathways

(2020) Wenchao Wan et al.   ACS Nano

Phase‐junction Electrocatalysts towards Enhanced Hydrogen Evolution Reaction in Alkaline Media

(2020) Qiang Fu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unveiling the Promotion of Surface‐Adsorbed Chalcogenate on the Electrocatalytic Oxygen Evolution Reaction

(2020) Yanmei Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spectroscopic and electrokinetic evidence for a bifunctional mechanism of the oxygen evolution reaction

(2020) Lichen Bai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy

(2020) Janis Timoshenko et al.   CHEMICAL REVIEWS

Achieving delafossite analog by in situ electrochemical self-reconstruction as an oxygen-evolving catalyst

(2020) Juzhe Liu et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Dynamic evolution and reversibility of single-atom Ni(II) active site in 1T-MoS2 electrocatalysts for hydrogen evolution

(2020) Brian Pattengale et al.   Nature Communications

Understanding and Optimizing Ultra‐Thin Coordination Polymer Derivatives with High Oxygen Evolution Performance

(2020) Yonggui Zhao et al.   Advanced Energy Materials

High-valence metals improve oxygen evolution reaction performance by modulating 3d metal oxidation cycle energetics

(2020) Bo Zhang et al.   Nature Catalysis

Anodic Oxidation Enabled Cation Leaching for Promoting Surface Reconstruction in Water Oxidation

(2020) Yan Duan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elevating the d‐Band Center of Six‐Coordinated Octahedrons in Co 9 S 8 through Fe‐Incorporated Topochemical Deintercalation

(2020) Zongpeng Wang et al.   Advanced Energy Materials

Formation of FeOOH Nanosheets Induces Substitutional Doping of CeO 2− x with High‐Valence Ni for Efficient Water Oxidation

(2020) Jun Yu et al.   Advanced Energy Materials

In Situ-Grown Cobalt–Iron Phosphide-Based Integrated Electrode for Long-Term Water Splitting under a Large Current Density at the Industrial Electrolysis Temperature

(2020) Xinying Liu et al.   ACS Sustainable Chemistry & Engineering

Interface Engineering of Co‐LDH@MOF Heterojunction in Highly Stable and Efficient Oxygen Evolution Reaction

(2020) Zhenxing Li et al.   Advanced Science

Faster hydrogen production in alkaline media

(2020) Michael John Craig et al.   Nature Catalysis

Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts

(2019) Zhen-Feng Huang et al.   Nature Energy

Operando Unraveling the Structural/Chemical Stability of P-substituted CoSe2 Electrocatalysts toward Hydrogen/Oxygen Evolution Reactions in Alkaline Electrolyte

(2019) Yanping Zhu et al.   ACS Energy Letters

Defect-Rich NiCeOx Electrocatalyst with Ultrahigh Stability and Low Overpotential for Water Oxidation

(2019) Jun Yu et al.   ACS Catalysis

Functional Role of Fe-Doping in Co-Based Perovskite Oxide Catalysts for Oxygen Evolution Reaction

(2019) Bae-Jung Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single platinum atoms embedded in nanoporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction

(2019) Kang Jiang et al.   Nature Communications

A Cobalt–Iron Double-Atom Catalyst for the Oxygen Evolution Reaction

(2019) Lichen Bai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One‐Step Controllable Synthesis of Catalytic Ni 4 Mo/MoO x /Cu Nanointerfaces for Highly Efficient Water Reduction

(2019) Yiming An et al.   Advanced Energy Materials

Iron-facilitated dynamic active-site generation on spinel CoAl2O4 with self-termination of surface reconstruction for water oxidation

(2019) Tianze Wu et al.   Nature Catalysis

Synergistically Interactive Pyridinic-N-MoP Sites: Identified Active Centers for Enhanced Hydrogen Evolution in Alkaline Solution

(2019) Di Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Identification of Key Reversible Intermediates in Self-Reconstructed Nickel-Based Hybrid Electrocatalysts for Oxygen Evolution

(2019) Jianwen Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electron density modulation of Fe1-xCoxP nanosheet arrays by iron incorporation for highly efficient water splitting

(2019) Haopeng Feng et al.   Nano Energy

In Situ Spatially Coherent Identification of Phosphide-Based Catalysts: Crystallographic Latching for Highly Efficient Overall Water Electrolysis

(2019) Sung-Fu Hung et al.   ACS Energy Letters

Cubic Co-Co prussian blue MOF-based transition metal phosphide as an efficient catalyst for visible light-driven water oxidation

(2019) Yinjuan Dong et al.   JOURNAL OF CATALYSIS

Surface Activation and Reconstruction of Non-Oxide-Based Catalysts Through in Situ Electrochemical Tuning for Oxygen Evolution Reactions in Alkaline Media

(2019) Arumugam Sivanantham et al.   ACS Catalysis

Electrochemical Instability of Metal–Organic Frameworks: In Situ Spectroelectrochemical Investigation of the Real Active Sites

(2019) Weiran Zheng et al.   ACS Catalysis

Enlarged CoO Covalency in Octahedral Sites Leading to Highly Efficient Spinel Oxides for Oxygen Evolution Reaction

(2018) Ye Zhou et al.   ADVANCED MATERIALS

Metal-Organic Framework Hybrid-Assisted Formation of Co3 O4 /Co-Fe Oxide Double-Shelled Nanoboxes for Enhanced Oxygen Evolution

(2018) Xiao Wang et al.   ADVANCED MATERIALS

Operando X-ray spectroscopic tracking of self-reconstruction for anchored nanoparticles as high-performance electrocatalysts towards oxygen evolution

(2018) Sanzhao Song et al.   Energy & Environmental Science

Elucidating Surface Restructuring-Induced Catalytic Reactivity of Cobalt Phosphide Nanoparticles under Electrochemical Conditions

(2018) Zishan Wu et al.   Journal of Physical Chemistry C

Core–Shell ZIF-8@ZIF-67-Derived CoP Nanoparticle-Embedded N-Doped Carbon Nanotube Hollow Polyhedron for Efficient Overall Water Splitting

(2018) Yuan Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evaluating the Stability of Co2P Electrocatalysts in the Hydrogen Evolution Reaction for Both Acidic and Alkaline Electrolytes

(2018) Yue Zhang et al.   ACS Energy Letters

Operando X-Ray Absorption Spectroscopy Shows Iron Oxidation Is Concurrent with Oxygen Evolution in Cobalt-Iron (Oxy)hydroxide Electrocatalysts

(2018) Lisa J. Enman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual-template engineering of triple-layered nanoarray electrode of metal chalcogenides sandwiched with hydrogen-substituted graphdiyne

(2018) Sifei Zhuo et al.   Nature Communications

Engineering Sulfur Defects, Atomic Thickness, and Porous Structures into Cobalt Sulfide Nanosheets for Efficient Electrocatalytic Alkaline Hydrogen Evolution

(2018) Chao Zhang et al.   ACS Catalysis

Direct Observation of Structural Evolution of Metal Chalcogenide in Electrocatalytic Water Oxidation

(2018) Ke Fan et al.   ACS Nano

Electronic structure and d-band center control engineering over M-doped CoP (M = Ni, Mn, Fe) hollow polyhedron frames for boosting hydrogen production

(2018) Yuan Pan et al.   Nano Energy

Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption

(2017) Xueli Zheng et al.   Nature Chemistry

Dynamic surface self-reconstruction is the key of highly active perovskite nano-electrocatalysts for water splitting

(2017) Emiliana Fabbri et al.   NATURE MATERIALS

Sub-1.1 nm ultrathin porous CoP nanosheets with dominant reactive {200} facets: a high mass activity and efficient electrocatalyst for the hydrogen evolution reaction

(2017) Chao Zhang et al.   Chemical Science

Are Metal Chalcogenides, Nitrides, and Phosphides Oxygen Evolution Catalysts or Bifunctional Catalysts?

(2017) Song Jin   ACS Energy Letters

Metal–organic-framework-engaged formation of Co nanoparticle-embedded carbon@Co9S8 double-shelled nanocages for efficient oxygen reduction

(2016) Han Hu et al.   Energy & Environmental Science

Hollow Cobalt-Based Bimetallic Sulfide Polyhedra for Efficient All-pH-Value Electrochemical and Photocatalytic Hydrogen Evolution

(2016) Zhen-Feng Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Complex CoS Hollow Structures with Enhanced Electrochemical Properties for Hybrid Supercapacitors

(2016) Han Hu et al.   Chem

Water oxidation by amorphous cobalt-based oxides: in situ tracking of redox transitions and mode of catalysis

(2015) Marcel Risch et al.   Energy & Environmental Science

Nanoporous Hollow Transition Metal Chalcogenide Nanosheets Synthesized via the Anion-Exchange Reaction of Metal Hydroxides with Chalcogenide Ions

(2014) Weiwei Zhao et al.   ACS Nano

EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH

(2010) J. Gregory McAlpin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Next-nearest neighbour contributions to the XPS binding energies and XANES absorption energies of P and As in transition-metal arsenide phosphides MAs1−yPy having the MnP-type structure

(2008) Andrew P. Grosvenor et al.   JOURNAL OF SOLID STATE CHEMISTRY