Journal
DALTON TRANSACTIONS
Volume 51, Issue 8, Pages 3051-3059Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt04174f
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Funding
- Russian Science Foundation [19-72-30005]
- Ministry of Science and Higher Education of the Russian Federation
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The synthesis of acetonitrilium and propionitrilium derivatives of closo-dodecaborate [B12H12](2-) was discussed. Nucleophilic addition reactions of water, alcohols, and secondary amines to the activated triple bond of the nitrilium derivatives yielded corresponding iminols, imidates, and amidines. The obtained results were supported by X-ray diffraction studies and DFT calculations.
The synthesis of the acetonitrilium and propionitrilium derivatives of closo-dodecaborate [B12H12](2-) was discussed. The nucleophilic addition reactions of water, alcohols and secondary amines to the activated triple bond of the nitrilium derivatives yielded the corresponding iminols, imidates and amidines. The obtained results were supported by X-ray diffraction studies and DFT calculations.
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