Article
Chemistry, Multidisciplinary
Junkuo Gao, Youlie Cai, Xuefeng Qian, Puxu Liu, Hui Wu, Wei Zhou, De-Xuan Liu, Libo Li, Rui-Biao Lin, Banglin Chen
Summary: This study presents a functionalized HOF-16 with free -COOH sites for efficient separation of propylene/propane mixtures, showing high selectivity and uptake difference. Through crystal engineering, the recognition and high-density packing of gas molecules are facilitated for improved separation performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Xiang Yu Gao, Yao Wang, Enyu Wu, Chen Wang, Bin Li, Yaming Zhou, Banglin Chen, Peng Li
Summary: A series of isoreticular multivariate hydrogen-bonded organic frameworks (MTV-HOFs) were successfully synthesized, which exhibited tunable hydrophobicity and the ability to capture a mustard gas simulant. This work is an important advance in the development of porous molecular materials for various applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Ying Liu, Hui Wu, Lidong Guo, Wei Zhou, Zhiguo Zhang, Qiwei Yang, Yiwen Yang, Qilong Ren, Zongbi Bao
Summary: Two isostructural metal-nucleobase frameworks are capable of separating Xe/Kr under ambient conditions and strike an excellent balance between capacity and selectivity.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Youlie Cai, Junkuo Gao, Jing-Hong Li, Puxu Liu, Yanchun Zheng, Wei Zhou, Hui Wu, Libo Li, Rui-Biao Lin, Banglin Chen
Summary: By incorporating structure-directing agents (SDAs) into the hydrogen-bonding network of TCPP, a series of HOFs with different pore structures were obtained. Among them, HOF-ZSTU-2 forms a strong layered hydrogen-bonding network with ammonium (NH4+) through multiple carboxyl groups and has a suitable 1D pearl-chain channel for the selective capture of propylene (C3H6). HOF-ZSTU-2 achieves a C3H6 storage density of 0.6 kg L-1 at 298 K and 1 bar, and exhibits a propylene/propane (C3H6/C3H8) selectivity of 12.2.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Xiaojun Ding, Yi Xie, Qiang Gao, Yilin Luo, Jing Chen, Gang Ye
Summary: Constructing well-organized organic frameworks with tailor-made functionalities has the potential to enhance multi-domain applications. Hydrogen bonding is a type of weak intermolecular interaction, different from covalent bonding or metal-ligand coordination. Hydrogen-bonded organic frameworks (HOFs) assembled using hydrogen bonding have the advantage of decomposing and regenerating, improving processability and expanding applicability. This paper summarizes the basic building concepts of HOFs, including feasible hydrogen bonded motifs, effective molecular structures, and their emerging applications.
Article
Chemistry, Multidisciplinary
Phonlakrit Muang-Non, Adrian W. Markwell-Heys, Christian J. Doonan, Nicholas G. White
Summary: Anionic hydrogen bonded frameworks were synthesized using di or tetra-amidinium hydrogen bond donor components and a charge mis-matched tecton. The presence of a cation in the framework channel is required due to the net negative charge on the framework skeletons. The organic cation initially incorporated in one of the frameworks was displaced by smaller inorganic cations or the cationic dye methylene blue, enabling effective and selective removal of the dye from water.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Wei-Kang Qin, Duan-Hui Si, Qi Yin, Xiang-Yu Gao, Qian-Qian Huang, Ya-Nan Feng, Lei Xie, Shuo Zhang, Xin-Song Huang, Tian-Fu Liu, Rong Cao
Summary: This article successfully synthesizes hydrogen-bonded organic frameworks (HOFs) with predicted structure through mechanosynthesis method, and demonstrates the applicability of reticular chemistry to HOF assemblies with different building blocks. The obtained crystalline HOFs have uniform nano-sized morphology, and the one-pot mechanosynthesis generates Pd@HOF composites with different CO oxidation activities. In situ DRIFTS studies reveal the vital role of porous matrix in catalytic performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Ying Liu, Qianqian Xu, Lihang Chen, Changhua Song, Qiwei Yang, Zhiguo Zhang, Dan Lu, Yiwen Yang, Qilong Ren, Zongbi Bao
Summary: This research introduces two hydrogen-bonded metal-nucleobase frameworks capable of efficiently separating light hydrocarbons and removing impurities from natural gas, showing great potential for various industrial applications.
Article
Chemistry, Physical
Ying Liu, Qianqian Xu, Lihang Chen, Changhua Song, Qiwei Yang, Zhiguo Zhang, Dan Lu, Yiwen Yang, Qilong Ren, Zongbi Bao
Summary: This work presents two hydrogen-bonded metal-nucleobase frameworks capable of efficiently separating C3H8/CH4, C2H6/CH4, and CH4/N-2. The frameworks exhibit strong affinity for C3H8 and C2H6, and show excellent performance in CH4 adsorption and CH4/N-2 selectivity. These findings are of great importance for natural gas upgrading and the concentration of low-quality coalbed methane.
Article
Nanoscience & Nanotechnology
Ellen Dautzenberg, Guanna Li, Louis C. P. M. De Smet
Summary: CO2 is a significant exhaust gas that contributes to global warming. The capture of CO2 emissions from industrial processes is essential to mitigate the negative effects of global warming. Covalent organic frameworks (COFs) have shown potential in selectively adsorbing CO2, and the new COF Me3TFB-(NH2)2BD demonstrated high CO2/N2 selectivity and adsorption capacity. The material's porosity was maintained despite the dynamic linker exchange, making it energy-efficient for regeneration.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Review
Chemistry, Multidisciplinary
Junyu Ren, Dan Zhao
Summary: The article explores the application of reticular chemistry in addressing global crises such as clean energy, carbon emissions, and water shortage. It provides insights into the research field and anticipates future directions for development.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Zhuxi Yang, Taito Hashimoto, Ryusei Oketani, Takayoshi Nakamura, Ichiro Hisaki
Summary: This study demonstrates a method to construct porous organic frameworks with interactive free sites using the concept of geometrically mismatched frameworks, resulting in the successful preparation of CP-Phen-1 framework with such sites. The framework undergoes a two-step structural transformation upon loss of solvent molecules, yet exhibits good thermal stability up to 360 degrees C and selective CO2 adsorption.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Xiaojun Ding, Zeyu Liu, Yusheng Zhang, Gang Ye, Jianfeng Jia, Jing Chen
Summary: A binary solvent synthetic strategy is proposed to construct molecule-based hydrogen-bonded organic frameworks (HOFs) with permanent ultra-micropores and surface polarization. The activated HOFs showed highly selective separation of CO2/N-2 under ambient temperature and pressure, making them potentially useful for gas separation applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Chuan-Zhi Liu, Jing-Jing Wang, Bo Yang, Zhong-Yi Li, Meng Yan, Xin-Ming Liu, Zhi-Yuan Hu, Lan-Tao Liu, Zhan-Ting Li
Summary: This paper selectively constructed two types of 2D and 3D XBOFs by changing the crystallization solvent. These XBOFs were formed from identical building blocks and the 3D XBOF is a novel hybrid supramolecular organic framework with synergistic control of hydrogen and halogen bonds.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Chuan-Zhi Liu, Jing-Jing Wang, Bo Yang, Zhong-Yi Li, Meng Yan, Xin-Ming Liu, Zhi-Yuan Hu, Lan-Tao Liu, Zhan-Ting Li
Summary: In this study, two types of solid phase 2D and 3D XBOFs were selectively constructed from identical building blocks by changing the crystallization solvent. The novel 3D XBOF formed in this process is a hybrid supramolecular organic framework that combines the control of hydrogen and halogen bonds. The selective construction of two types of 2D and 3D XBOFs was achieved by altering the crystallization solvent.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Ying Liu, Juanjuan Dai, Lidong Guo, Zhiguo Zhang, Yiwen Yang, Qiwei Yang, Qilong Ren, Zongbi Bao
Summary: Two novel isostructural ionic supramolecular MOFs have been reported for efficient separation of Xe and Kr. The adsorption performance and industrial application potential of these materials have been validated through theoretical calculations and breakthrough experiments. This is the first report of using supramolecular MOFs for Xe/Kr separation, proposing a new strategy based on the synergistic effect of amino and inorganic anions.