Heterodinuclear Mg(II)M(II) (M=Cr, Mn, Fe, Co, Ni, Cu and Zn) Complexes for the Ring Opening Copolymerization of Carbon Dioxide/Epoxide and Anhydride/Epoxide

Alternating Copolymerization of Carbon Dioxide with Epoxides Using Highly Active Dinuclear Nickel Complexes: Catalysis and Kinetics

(2021) Yu-Chia Su et al.   INORGANIC CHEMISTRY

Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity

(2021) Alex J. Plajer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Record Productivity and Unprecedented Molecular Weight for Ring‐Opening Copolymerization of Epoxides and Cyclic Anhydrides Enabled by Organoboron Catalysts

(2021) Rui Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sequence Control from Mixtures: Switchable Polymerization Catalysis and Future Materials Applications

(2021) Arron C. Deacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trinuclear salphen–chromium( III )chloride complexes as catalysts for the alternating copolymerization of epoxides and cyclic anhydrides

(2021) Lei Cui et al.   JOURNAL OF POLYMER SCIENCE

Catalytic Synergy Using Al(III) and Group 1 Metals to Accelerate Epoxide and Anhydride Ring-Opening Copolymerizations

(2021) Wilfred T. Diment et al.   ACS Catalysis

Switchable Catalysis Improves the Properties of CO2-Derived Polymers: Poly(cyclohexene carbonate-b-ε-decalactone-b-cyclohexene carbonate) Adhesives, Elastomers, and Toughened Plastics

(2020) Gregory S. Sulley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Characterization, and Low-Toxicity Study of a Magnesium(II) Complex Containing an Isovanillate Group

(2020) Rafael C. Marchi et al.   ACS Omega

Effect of Distortions on the Geometric and Electronic Structures of One-Electron Oxidized Vanadium(IV), Copper(II), and Cobalt(II)/(III) Salen Complexes

(2020) Hussein Kanso et al.   INORGANIC CHEMISTRY

Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides

(2020) Arron C. Deacy et al.   Nature Chemistry

Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt–Lanthanide Mixed Multinuclear Complexes

(2020) Hiroki Asaba et al.   INORGANIC CHEMISTRY

Catalysis and kinetics for alternating copolymerization of carbon dioxide with epoxides using dinuclear nickel catalysts of pyrazolyl based diamine-bisphenolate ligands

(2020) Yu-Chia Su et al.   POLYMER

Bio‐based and Degradable Block Polyester Pressure‐Sensitive Adhesives

(2020) Thomas T. D. Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-catalyzed reactions of CO2 and epoxides to yield cyclic and polycarbonates

(2020) Kori A. Andrea et al.   POLYMER JOURNAL

Metabolically Active, Fully Hydrolysable Polymersomes

(2019) Yunqing Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Chemical Bond between Transition Metals and Oxygen: Electronegativity, d-Orbital Effects, and Oxophilicity as Descriptors of Metal–Oxygen Interactions

(2019) Klaus A. Moltved et al.   Journal of Physical Chemistry C

Easy access to oxygenated block polymers via switchable catalysis

(2019) Tim Stößer et al.   Nature Communications

Iron Complexes for Cyclic Carbonate and Polycarbonate Formation: Selectivity Control from Ligand Design and Metal-Center Geometry

(2019) Kori A. Andrea et al.   INORGANIC CHEMISTRY

Mechanism-Inspired Design of Bifunctional Catalysts for the Alternating Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides

(2019) Brooks A. Abel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed copolymerization of carbon dioxide with internal epoxides by di-nuclear bis(benzotriazole iminophenolate) complexes

(2019) Ming-Han Li et al.   EUROPEAN POLYMER JOURNAL

Lanthanide Complexes Supported by a Trizinc Crown Ether as Catalysts for Alternating Copolymerization of Epoxide and CO2 : Telomerization Controlled by Carboxylate Anions

(2018) Haruki Nagae et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Well-Defined and Structurally Diverse Aromatic Alternating Polyesters Synthesized by Simple Phosphazene Catalysis

(2018) Heng Li et al.   MACROMOLECULES

Alternating copolymerization of epoxides with carbon dioxide or cyclic anhydrides using bimetallic nickel and cobalt catalysts: Preparation of hydrophilic nanofibers from functionalized polyesters

(2018) Chi-Hang Chang et al.   POLYMER

A synthetic polymer system with repeatable chemical recyclability

(2018) Jian-Bo Zhu et al.   SCIENCE

Unraveling substituent effects on the glass transition temperatures of biorenewable polyesters

(2018) Xiaopeng Yu et al.   Nature Communications

[OSSO]-Type Iron(III) Complexes for the Low-Pressure Reaction of Carbon Dioxide with Epoxides: Catalytic Activity, Reaction Kinetics, and Computational Study

(2018) Francesco Della Monica et al.   ACS Catalysis

Electroactive Co(iii) salen metal complexes and the electrophoretic deposition of their porous organic polymers onto glassy carbon

(2018) Marcello B. Solomon et al.   RSC Advances

Dinuclear iron(iii) complexes bearing phenylene-bridged bis(amino triphenolate) ligands as catalysts for the copolymerization of cyclohexene oxide with carbon dioxide or phthalic anhydride

(2018) Zhan Shi et al.   Polymer Chemistry

Groups 1, 2 and Zn(II) Heterodinuclear Catalysts for Epoxide/CO2 Ring-Opening Copolymerization

(2018) Arron C. Deacy et al.   INORGANIC CHEMISTRY

Characterization of Oxo-Bridged Iron Amino-bis(phenolate) Complexes Formed Intentionally or in Situ: Mechanistic Insight into Epoxide Deoxygenation during the Coupling of CO2 and Epoxides

(2018) Kori A. Andrea et al.   INORGANIC CHEMISTRY

Copolymerization of Carbon Dioxide with Epoxides Catalyzed by Structurally Well-Characterized Dinickel Bis(benzotriazole iminophenolate) Complexes: Influence of Carboxylate Ligands on the Catalytic Performance

(2017) Li-Shin Huang et al.   INORGANIC CHEMISTRY

Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates

(2017) Chunliang Li et al.   ACS Macro Letters

Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides with Discrete Metal Complexes: Structure–Property Relationships

(2016) Julie M. Longo et al.   CHEMICAL REVIEWS

A Quantitative Scale of Oxophilicity and Thiophilicity

(2016) Kasper P. Kepp   INORGANIC CHEMISTRY

Dinuclear and Trinuclear Nickel Complexes as Effective Catalysts for Alternating Copolymerization on Carbon Dioxide and Cyclohexene Oxide

(2016) Chen-Yen Tsai et al.   INORGANIC CHEMISTRY

Halogenated meso -phenyl Mn(III) porphyrins as highly efficient catalysts for the synthesis of polycarbonates and cyclic carbonates using carbon dioxide and epoxides

(2016) Laia Cuesta-Aluja et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Asymmetric Alternating Copolymerization of Meso-epoxides and Cyclic Anhydrides: Efficient Access to Enantiopure Polyesters

(2016) Jie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Highly Active and Regioselective Catalysts for the Copolymerization of Epoxides with Cyclic Anhydrides: An Unanticipated Effect of Electronic Variation

(2016) Angela M. DiCiccio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Cis/Trans-Stereoselective (ONSO)CrCl-Catalyzed Ring-Opening Copolymerization of Norbornene Anhydrides and Epoxides

(2016) Bing Han et al.   MACROMOLECULES

Alternating Copolymerization of Propylene Oxide and Cyclohexene Oxide with Tricyclic Anhydrides: Access to Partially Renewable Aliphatic Polyesters with High Glass Transition Temperatures

(2016) Maria J. Sanford et al.   MACROMOLECULES

Sustainable polymers from renewable resources

(2016) Yunqing Zhu et al.   NATURE

Catalysts for CO2/epoxide ring-opening copolymerization

(2016) G. Trott et al.   PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Bimetallic bis(benzotriazole iminophenolate) cobalt, nickel and zinc complexes as versatile catalysts for coupling of carbon dioxide with epoxides and copolymerization of phthalic anhydride with cyclohexene oxide

(2016) Chun-Yue Yu et al.   Catalysis Science & Technology

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates

(2015) Shyeni Paul et al.   CHEMICAL COMMUNICATIONS

Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

(2015) S. Kissling et al.   CHEMICAL COMMUNICATIONS

Mechanistic Aspects of a Highly Active Dinuclear Zinc Catalyst for the Co-polymerization of Epoxides and CO2

(2015) Stefan Kissling et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Iron Pyridylamino-Bis(Phenolate) Catalyst for Converting CO2into Cyclic Carbonates and Cross-Linked Polycarbonates

(2015) Masoumeh Taherimehr et al.   ChemSusChem

Dinuclear Zinc Salen Catalysts for the Ring Opening Copolymerization of Epoxides and Carbon Dioxide or Anhydrides

(2015) Arnaud Thevenon et al.   INORGANIC CHEMISTRY

Prediction of the pKa’s of Aqueous Metal Ion +2 Complexes

(2015) Virgil E. Jackson et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Greater than the Sum of Its Parts: A Heterodinuclear Polymerization Catalyst

(2015) Jennifer A. Garden et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controllable Synthesis of Stereoregular Polyesters by Organocatalytic Alternating Copolymerizations of Cyclohexene Oxide and Norbornene Anhydrides

(2015) Bing Han et al.   MACROMOLECULES

Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of γ-butyrolactone

(2015) Miao Hong et al.   Nature Chemistry

Functional polyesters derived from alternating copolymerization of norbornene anhydride and epoxides

(2015) Ryan Baumgartner et al.   Polymer Chemistry

Adding Value to Power Station Captured CO2: Tolerant Zn and Mg Homogeneous Catalysts for Polycarbonate Polyol Production

(2015) A. M. Chapman et al.   ACS Catalysis

Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts

(2014) Jong Yeob Jeon et al.   Beilstein Journal of Organic Chemistry

Manganese-Corrole Complexes as Versatile Catalysts for the Ring-Opening Homo- and Co-Polymerization of Epoxide

(2014) Carine Robert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

(2014) Chi-Huan Li et al.   Polymer Chemistry

Di-magnesium and zinc catalysts for the copolymerization of phthalic anhydride and cyclohexene oxide

(2014) Prabhjot K. Saini et al.   Polymer Chemistry

Chromium(iii) amine-bis(phenolate) complexes as catalysts for copolymerization of cyclohexene oxide and CO2

(2014) Hua Chen et al.   Catalysis Science & Technology

Flexibly Tethered Dinuclear Zinc Complexes: A Solution to the Entropy Problem in CO2/Epoxide Copolymerization Catalysis?

(2013) Maximilian W. Lehenmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High activity and switchable selectivity in the synthesis of cyclic and polymeric cyclohexene carbonates with iron amino triphenolate catalysts

(2013) Masoumeh Taherimehr et al.   GREEN CHEMISTRY

Chromium complexes with tridentate NN′O Schiff base ligands as catalysts for the coupling of CO2 and epoxides

(2013) Siham Iksi et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Iron–Corrole Complexes: Synthesis of a Crystalline Copolymer

(2013) Koji Nakano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Method of Depolymerization of Poly(cyclopentene carbonate) to Its Comonomers: Cyclopentene Oxide and Carbon Dioxide

(2013) Donald J. Darensbourg et al.   MACROMOLECULES

CO2 Copolymers from Epoxides: Catalyst Activity, Product Selectivity, and Stereochemistry Control

(2012) Xiao-Bing Lu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Reaction of CO2with propylene oxide and styrene oxide catalyzed by a chromium(iii) amine-bis(phenolate) complex

(2012) Rebecca K. Dean et al.   DALTON TRANSACTIONS

Efficient Magnesium Catalysts for the Copolymerization of Epoxides and CO2; Using Water to Synthesize Polycarbonate Polyols

(2012) Michael R. Kember et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Di-cobalt(ii) catalysts for the copolymerisation of CO2 and cyclohexene oxide: support for a dinuclear mechanism?

(2012) Michael R. Kember et al.   Chemical Science

Ring-Opening Co- and Terpolymerization of an Alicyclic Oxirane with Carboxylic Acid Anhydrides and CO2in the Presence of Chromium Porphyrinato and Salen Catalysts

(2011) Saskia Huijser et al.   MACROMOLECULES

Catalysts for CO2/epoxide copolymerisation

(2010) Michael R. Kember et al.   CHEMICAL COMMUNICATIONS

A bimetallic iron(iii) catalyst for CO2/epoxide coupling

(2010) Antoine Buchard et al.   CHEMICAL COMMUNICATIONS

Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms

(2010) Stephan Klaus et al.   COORDINATION CHEMISTRY REVIEWS

CoII, NiII, CuII and ZnII complexes of a bipyridine bis-phenol conjugate: Generation and properties of coordinated radical species

(2010) Himanshu Arora et al.   DALTON TRANSACTIONS

Highly Active Di- and Trimetallic Cobalt Catalysts for the Copolymerization of CHO and CO2at Atmospheric Pressure

(2010) Michael R. Kember et al.   MACROMOLECULES

Highly Active, Bifunctional Co(III)-Salen Catalyst for Alternating Copolymerization of CO2with Cyclohexene Oxide and Terpolymerization with Aliphatic Epoxides

(2010) Wei-Min Ren et al.   MACROMOLECULES

Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure

(2009) Michael R. Kember et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copolymerization of CO2 and cyclohexene oxide using a lysine-based (salen)CrIIICl catalyst

(2009) Liping Guo et al.   DALTON TRANSACTIONS

Binding of 4-(N,N-dimethylamino)pyridine to Salen- and Salan-Cr(III) Cations: A Mechanistic Understanding on the Difference in Their Catalytic Activity for CO2/Epoxide Copolymerization

(2009) Dun-Yan Rao et al.   INORGANIC CHEMISTRY

A Highly Active and Recyclable Catalytic System for CO2/Propylene Oxide Copolymerization

(2008) Sujith S et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

X-Ray crystal structures of five-coordinate (salen)MnN3 derivatives and their binding abilities towards epoxides: chemistry relevant to the epoxide–CO2 copolymerization process

(2008) Donald J. Darensbourg et al.   DALTON TRANSACTIONS

Studies of the Carbon Dioxide and Epoxide Coupling Reaction in the Presence of Fluorinated Manganese(III) Acacen Complexes: Kinetics of Epoxide Ring-Opening

(2008) Donald J. Darensbourg et al.   INORGANIC CHEMISTRY

An Exploration of the Coupling Reactions of Epoxides and Carbon Dioxide Catalyzed by Tetramethyltetraazaannulene Chromium(III) Derivatives: Formation of Copolymers versus Cyclic Carbonates

(2008) Donald J. Darensbourg et al.   INORGANIC CHEMISTRY

Asymmetric, regio- and stereo-selective alternating copolymerization of CO2and propylene oxide catalyzed by chiral chromium Salan complexes

(2008) Bo Li et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Bimetallic Calcium and Zinc Complexes with Bridged β-Diketiminate Ligands: Investigations on Epoxide/CO2Copolymerization

(2008) Dirk F.-J. Piesik et al.   ORGANOMETALLICS