Flexibility of a Metal–Organic Framework Enhances Gas Separation and Enables Quantum Sieving

Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework

(2021) Omid T. Qazvini et al.   Nature Communications

Chemistry of Soft Porous Crystals – Structural Dynamics and Gas Adsorption Properties

(2020) Simon Krause et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effect of Ligand Functionalization on the Separation of Small Hydrocarbons and CO2 by a Series of MUF-15 Analogues

(2020) Omid T. Qazvini et al.   CHEMISTRY OF MATERIALS

Control of structural flexibility of layered-pillared metal-organic frameworks anchored at surfaces

(2019) Suttipong Wannapaiboon et al.   Nature Communications

Design and control of gas diffusion process in a nanoporous soft crystal

(2019) Cheng Gu et al.   SCIENCE

A Robust Ethane-Trapping Metal–Organic Framework with a High Capacity for Ethylene Purification

(2019) Omid T. Qazvini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Induced Fit of C2 H2 in a Flexible MOF Through Cooperative Action of Open Metal Sites

(2019) Heng Zeng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multipurpose Metal–Organic Framework for the Adsorption of Acetylene: Ethylene Purification and Carbon Dioxide Removal

(2019) Omid T. Qazvini et al.   CHEMISTRY OF MATERIALS

Enhanced Gas Uptake in a Microporous Metal–Organic Framework via a Sorbate Induced-Fit Mechanism

(2019) Mei-Hui Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploiting Dynamic Opening of Apertures in a Partially Fluorinated MOF for Enhancing H2 Desorption Temperature and Isotope Separation

(2019) Linda Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Guest-dependent pressure induced gate-opening effect enables effective separation of propene and propane in a flexible MOF

(2018) Xiaoqing Wang et al.   CHEMICAL ENGINEERING JOURNAL

Theoretical Insight into Gate-Opening Adsorption Mechanism and Sigmoidal Adsorption Isotherm into Porous Coordination Polymer

(2018) Jia-Jia Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ultrahigh Effective H2/D2 Separation in an Ultramicroporous Metal-organic Framework Material through Quantum Sieving

(2018) Dawei Cao et al.   Journal of Materials Chemistry A

Selective Hydrogen Isotope Separation via Breathing Transition in MIL-53(Al)

(2017) Jin Yeong Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solvent-switchable continuous-breathing behaviour in a diamondoid metal–organic framework and its influence on CO2 versus CH4 selectivity

(2017) Elliot J. Carrington et al.   Nature Chemistry

Controlling flexibility of metal–organic frameworks

(2017) Jie-Peng Zhang et al.   National Science Review

Molecular separations with breathing metal–organic frameworks: modelling packed bed adsorbers

(2016) Tom R. C. Van Assche et al.   DALTON TRANSACTIONS

Quantum Sieving for Separation of Hydrogen Isotopes Using MOFs

(2016) Hyunchul Oh et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Aromatic Substituent Effects on the Flexibility of Metal–Organic Frameworks

(2016) Hyungwoo Hahm et al.   INORGANIC CHEMISTRY

Structural Investigation of a Flexible MOF [Cu(BF4)2(1,3-bis(4-pyridyl)propane)2] Showing Selective Gate Adsorption with Dynamic Pore-Opening/Pore-Closing Processes

(2016) Takayuki Suzuki et al.   Journal of Physical Chemistry C

Exploiting the gate opening effect in a flexible MOF for selective adsorption of propyne from C1/C2/C3 hydrocarbons

(2016) Libo Li et al.   Journal of Materials Chemistry A

Flexible Metal-Organic Frameworks: Recent Advances and Potential Applications

(2015) Ze Chang et al.   ADVANCED MATERIALS

Modeling and simulation pressure–temperature swing adsorption process to remove mercaptan from humid natural gas; a commercial case study

(2015) Omid Taheri Qazvini et al.   SEPARATION AND PURIFICATION TECHNOLOGY

Prediction of flexibility of metal–organic frameworks CAU-13 and NOTT-300 by first principles molecular simulations

(2014) Aurélie U. Ortiz et al.   CHEMICAL COMMUNICATIONS

Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications

(2014) Zu-Jin Lin et al.   CHEMICAL SOCIETY REVIEWS

Flexible metal–organic frameworks

(2014) A. Schneemann et al.   CHEMICAL SOCIETY REVIEWS

Highly Effective Hydrogen Isotope Separation in Nanoporous Metal–Organic Frameworks with Open Metal Sites: Direct Measurement and Theoretical Analysis

(2013) Hyunchul Oh et al.   ACS Nano

Approaches for synthesizing breathing MOFs by exploiting dimensional rigidity

(2013) Christopher R. Murdock et al.   COORDINATION CHEMISTRY REVIEWS

The Chemistry and Applications of Metal-Organic Frameworks

(2013) H. Furukawa et al.   SCIENCE

Free energy landscapes for the thermodynamic understanding of adsorption-induced deformations and structural transitions in porous materials

(2012) D. Bousquet et al.   JOURNAL OF CHEMICAL PHYSICS

Directing the Breathing Behavior of Pillared-Layered Metal–Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents

(2012) Sebastian Henke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning the Gate Opening Pressure of Metal–Organic Frameworks (MOFs) for the Selective Separation of Hydrocarbons

(2012) Nour Nijem et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Quantum Molecular Sieving Separation of D2 from H2–D2 Mixture with Nanoporous Materials

(2012) Subaru Niimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modeling the Effect of Structural Changes during Dynamic Separation Processes on MOFs

(2011) Tom Remy et al.   LANGMUIR

Co-adsorption and Separation of CO2−CH4 Mixtures in the Highly Flexible MIL-53(Cr) MOF

(2009) Lomig Hamon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions

(2009) Thomas Devic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Soft porous crystals

(2009) Satoshi Horike et al.   Nature Chemistry

Broadly Hysteretic H2Adsorption in the Microporous Metal−Organic Framework Co(1,4-benzenedipyrazolate)

(2008) Hye Jin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY