A review of bio-refining process intensification in catalytic conversion reactions, separations and purifications of hydroxymethylfurfural (HMF) and furfural

Recent advances in biotransformation of 5‐Hydroxymethylfurfural : Challenges and future aspects

(2021) Kongkona Saikia et al.   JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY

Novel Hybrid Reactive Distillation with Extraction and Distillation Processes for Furfural Production from an Actual Xylose Solution

(2021) Le Cao Nhien et al.   Energies

A critical review of recent advances in the production of furfural and 5-hydroxymethylfurfural from lignocellulosic biomass through homogeneous catalytic hydrothermal conversion

(2021) Yuan Zhao et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Confinement effects and acid strength in zeolites

(2021) Emanuele Grifoni et al.   Nature Communications

Enhanced HMF yield from glucose with H-ZSM-5 catalyst in water-tetrahydrofuran/2-butanol/2-methyltetrahydrofuran biphasic systems

(2020) Si-quan Xu et al.   Journal of Central South University

Conversion of Glucose to 5-Hydroxymethylfurfural in a Microreactor

(2020) Tiprawee Tongtummachat et al.   Frontiers in Chemistry

Current situation of the challenging scale‐up development of hydroxymethylfurfural production

(2020) Catherine Thoma et al.   ChemSusChem

5-Hydroxymethylfurfural Synthesis from Monosaccharides by a Biphasic Reaction–Extraction System Using a Microreactor and Extractor

(2020) Yosuke Muranaka et al.   ACS Omega

Zeolite (In)Stability under Aqueous or Steaming Conditions

(2020) Christopher James Heard et al.   ADVANCED MATERIALS

Recent advances in catalytic and autocatalytic production of biomass-derived 5-hydroxymethylfurfural

(2020) Lei Hu et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Selective fructose dehydration to 5-hydroxymethylfurfural from a fructose-glucose mixture over a sulfuric acid catalyst in a biphasic system: Experimental study and kinetic modelling

(2020) Wenze Guo et al.   CHEMICAL ENGINEERING JOURNAL

Synthesis of 5-hydroxymethylfurfural (5-HMF) from fructose over cation exchange resin in a continuous flow reactor

(2019) Chaloemkrit Sonsiam et al.   CHEMICAL ENGINEERING AND PROCESSING

Furfural Production by Continuous Reactive Extraction in a Millireactor under the Taylor Flow Regime

(2019) Myrto Papaioannou et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Furfural Production by Reactive Stripping: Process Optimization by a Combined Modeling and Experimental Approach

(2019) V. Krzelj et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Recent advances in catalytic conversion of biomass to 5-hydroxymethylfurfural and 2, 5-dimethylfuran

(2019) Haiyong Wang et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

High yield 5‐hydroxymethylfurfural synthesis from crude sugar beet juice in a biphasic microreactor

(2019) Ria M Abdilla-Santes et al.   ChemSusChem

A highly selective and efficient method for the production of 5-hydroxymethylfurfural from dehydration of fructose using SACS/DES catalytic system

(2019) Phuong Hoang Tran et al.   FUEL

Highly efficient Cr/β zeolite catalyst for conversion of carbohydrates into 5‑hydroxymethylfurfural: Characterization and performance

(2019) Siquan Xu et al.   FUEL PROCESSING TECHNOLOGY

C10MI·CF3SO3: a hydrophobic ionic liquid medium for the production of HMF from sugars avoiding the use of organic solvent

(2019) Fernanda Colpo de Melo et al.   Biomass Conversion and Biorefinery

Solvent Effect on the Degradative Condensation Side Reactions of Fructose in the Initial Stage of Fructose Dehydration

(2019) Xing Fu et al.   ChemSusChem

Strategies for the Separation of the Furanic Compounds HMF, DFF, FFCA, and FDCA from Ionic Liquids

(2019) Amir Al Ghatta et al.   ACS Sustainable Chemistry & Engineering

Continuous synthesis of 5-hydroxymethylfurfural using deep eutectic solvents and its kinetic study in microreactors

(2019) Hong Zhang et al.   CHEMICAL ENGINEERING JOURNAL

Continuous synthesis of 5-hydroxymethylfurfural from glucose using a combination of AlCl3 and HCl as catalyst in a biphasic slug flow capillary microreactor

(2019) Wenze Guo et al.   CHEMICAL ENGINEERING JOURNAL

Adsorption isotherm, kinetics simulation and breakthrough analysis of 5-hydroxymethylfurfural adsorption/desorption behavior of a novel polar-modified post-cross-linked poly (divinylbenzene-co-ethyleneglycoldimethacrylate) resin

(2019) Jiayi Zheng et al.   CHEMOSPHERE

Novel hybrid-blower-and-evaporator-assisted distillation for separation and purification in biorefineries

(2018) Nguyen Van Duc Long et al.   CHEMICAL ENGINEERING AND PROCESSING

Acid Modified H-USY Zeolite for Efficient Catalytic Transformation of Fructose to 5-Hydroxymethyl Furfural (Biofuel Precursor) in Methyl Isobutyl Ketone–Water Biphasic System

(2018) Ashwini Pande et al.   ENERGY & FUELS

Selective separation of furfural and hydroxymethylfurfural from an aqueous solution using a supported hydrophobic deep eutectic solvent liquid membrane

(2018) Carin H. J. T. Dietz et al.   FARADAY DISCUSSIONS

Structural analysis of humins formed in the Brønsted acid catalyzed dehydration of fructose

(2018) Ziwei Cheng et al.   GREEN CHEMISTRY

Continuous pervaporation-assisted furfural production catalyzed by CrCl3

(2018) Alex Wang et al.   GREEN CHEMISTRY

Experimental and Mathematical Simulation of Noncompetitive and Competitive Adsorption Dynamic of Formic Acid–Levulinic Acid–5-Hydroxymethylfurfural from Single, Binary, and Ternary Systems in a Fixed-Bed Column of SY-01 Resin

(2018) Jiayi Zheng et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

A microwave-assisted process for the in-situ production of 5-hydroxymethylfurfural and furfural from lignocellulosic polysaccharides in a biphasic reaction system

(2018) Nick Sweygers et al.   JOURNAL OF CLEANER PRODUCTION

Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars: A review

(2018) Bhumica Agarwal et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Role of bioenergy, biorefinery and bioeconomy in sustainable development: Strategic pathways for Malaysia

(2018) Jhuma Sadhukhan et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Selective separation of furfural and hydroxymethylfurfural from an aqueous solution using a supported hydrophobic deep eutectic solvent liquid membrane

(2018) Carin H. J. T. Dietz et al.   FARADAY DISCUSSIONS

Efficient Production of 5-Hydroxymethylfurfural Enhanced by Liquid–Liquid Extraction in a Membrane Dispersion Microreactor

(2018) Caijin Zhou et al.   ACS Sustainable Chemistry & Engineering

Production of 5-HMF from Cellulosic Biomass: Experimental Results and Integrated Process Simulation

(2018) M. A. Kougioumtzis et al.   Waste and Biomass Valorization

Efficient glucose dehydration to HMF onto Nb-BEA catalysts

(2018) Natalia Candu et al.   CATALYSIS TODAY

From a Sequential Chemo-Enzymatic Approach to a Continuous Process for HMF Production from Glucose

(2018) Alexandra Gimbernat et al.   Catalysts

Production of 5-Hydroxymethylfurfural from Starch Through an Environmentally-Friendly Synthesis Pathway

(2018) Agneev Mukherjee et al.   CATALYSIS LETTERS

Inherently Safer Design and Optimization of Intensified Separation Processes for Furfural Production

(2018) G. Contreras-Zarazúa et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Production of 5‐Hydroxymethylfurfural from D‐Fructose in Low‐Transition‐Temperature Mixtures Enhanced by Chloride Anions and Low Amounts of Organic Acids

(2018) Thibaut Istasse et al.   ChemPlusChem

Controllable and scalable synthesis of hollow-structured porous aromatic polymer for selective adsorption and separation of HMF from reaction mixture of fructose dehydration

(2018) Yuan-Bao Zhang et al.   CHEMICAL ENGINEERING JOURNAL

Suppression of oligomer formation in glucose dehydration by CO2 and tetrahydrofuran

(2017) Xing Fu et al.   GREEN CHEMISTRY

Continuous 5-Hydroxymethylfurfural Production from Monosaccharides in a Microreactor

(2017) Yosuke Muranaka et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Reactive extraction and recovery of levulinic acid, formic acid and furfural from aqueous solutions containing sulphuric acid

(2017) Thomas Brouwer et al.   SEPARATION AND PURIFICATION TECHNOLOGY

Integrated production of furfural and levulinic acid from corncob in a one-pot batch reaction incorporating distillation using step temperature profiling

(2017) Hairui Ji et al.   RSC Advances

The Key Role of Textural Properties of Aluminosilicates in the Acid-Catalysed Dehydration of Glucose into 5-Hydroxymethylfurfural

(2017) Mercedes Moreno-Recio et al.   ChemistrySelect

Kinetics of homogeneous 5-hydroxymethylfurfural oxidation to 2,5-furandicarboxylic acid with Co/Mn/Br catalyst

(2016) Xiaobin Zuo et al.   AICHE JOURNAL

Chemical conversion and liquid-liquid extraction of 5-hydroxymethylfurfural from fructose by slug flow microreactor

(2016) Toshinori Shimanouchi et al.   AICHE JOURNAL

Design and optimization of intensified biorefinery process for furfural production through a systematic procedure

(2016) Le Cao Nhien et al.   BIOCHEMICAL ENGINEERING JOURNAL

Waste biorefinery models towards sustainable circular bioeconomy: Critical review and future perspectives

(2016) S. Venkata Mohan et al.   BIORESOURCE TECHNOLOGY

Single stage and countercurrent extraction of 5-hydroxymethylfurfural from aqueous phase systems

(2016) Eva C. Sindermann et al.   CHEMICAL ENGINEERING JOURNAL

Brönsted and Lewis acid ZSM-5 zeolites for the catalytic dehydration of glucose into 5-hydroxymethylfurfural

(2016) Mercedes Moreno-Recio et al.   CHEMICAL ENGINEERING JOURNAL

Heterogeneously Catalyzed Hydrothermal Processing of C5–C6 Sugars

(2016) Xingguang Zhang et al.   CHEMICAL REVIEWS

Furfural: a renewable and versatile platform molecule for the synthesis of chemicals and fuels

(2016) R. Mariscal et al.   Energy & Environmental Science

Pervaporation-assisted catalytic conversion of xylose to furfural

(2016) Alex Wang et al.   GREEN CHEMISTRY

High yield 5-(hydroxymethyl)furfural production from biomass sugars under facile reaction conditions: a hybrid enzyme- and chemo-catalytic technology

(2016) Siamak Alipour   GREEN CHEMISTRY

Highly efficient and selective CO2-adjunctive dehydration of xylose to furfural in aqueous media with THF

(2016) Ana Rita C. Morais et al.   GREEN CHEMISTRY

Adsorption of sucrose on zeolites

(2016) Iris Fornefett et al.   GREEN CHEMISTRY

A green and efficient approach to selective conversion of xylose and biomass hemicellulose into furfural in aqueous media using high-pressure CO2 as a sustainable catalyst

(2016) Ana Rita C. Morais et al.   GREEN CHEMISTRY

Insights into the Kinetics and Reaction Network of Aluminum Chloride-Catalyzed Conversion of Glucose in NaCl–H2O/THF Biphasic System

(2016) Jinqiang Tang et al.   ACS Catalysis

Furfural: A Promising Platform Compound for Sustainable Production of C4 and C5 Chemicals

(2016) Xiaodan Li et al.   ACS Catalysis

Recovery and Separation of Carbohydrate Derivatives from the Lipid Extracted Alga Dunaliella by Mild Liquefaction

(2016) Liisa K. Rihko-Struckmann et al.   ACS Sustainable Chemistry & Engineering

OSDA-Free Zeolite Beta with High Aluminum Content Efficiently Catalyzes a Tandem Reaction for Conversion of Glucose to 5-Hydroxymethylfurfural

(2015) Ryoichi Otomo et al.   ChemCatChem

Organic Solvent Effects in Biomass Conversion Reactions

(2015) Li Shuai et al.   ChemSusChem

Reactive distillation process for the production of furfural using solid acid catalysts

(2015) Pranit S. Metkar et al.   GREEN CHEMISTRY

Insights into the Hydrothermal Stability of ZSM-5 under Relevant Biomass Conversion Reaction Conditions

(2015) David W. Gardner et al.   ACS Catalysis

Using Sub/Supercritical CO2 as “Phase Separation Switch” for the Efficient Production of 5-Hydroxymethylfurfural from Fructose in an Ionic Liquid/Organic Biphasic System

(2015) Chunyan Shi et al.   ACS Sustainable Chemistry & Engineering

Adsorption process and mechanism for furfural separation with macroporous resin

(2014) Chunmei Jia et al.   Desalination and Water Treatment

Fermentation of hydrolysate detoxified by pervaporation through block copolymer membranes

(2014) Douglas R. Greer et al.   GREEN CHEMISTRY

Hydroxymethylfurfural production from bioresources: past, present and future

(2014) Siew Ping Teong et al.   GREEN CHEMISTRY

Dehydration of fructose into furans over zeolite catalyst using carbon black as adsorbent

(2014) Paul Dornath et al.   MICROPOROUS AND MESOPOROUS MATERIALS

One-Pot Degradation of Cellulose into Furfural Compounds in Hot Compressed Steam with Dihydric Phosphates

(2014) Ning Shi et al.   ACS Sustainable Chemistry & Engineering

Reactive adsorption for the selective dehydration of sugars to furans: Modeling and experiments

(2013) T. Dallas Swift et al.   AICHE JOURNAL

Adsorption of glucose into zeolite beta from aqueous solution

(2013) Peng Bai et al.   AICHE JOURNAL

Dealuminated Beta zeolite as effective bifunctional catalyst for direct transformation of glucose to 5-hydroxymethylfurfural

(2013) Ryoichi Otomo et al.   APPLIED CATALYSIS A-GENERAL

Production of furfural from pentosan-rich biomass: Analysis of process parameters during simultaneous furfural stripping

(2013) I. Agirrezabal-Telleria et al.   BIORESOURCE TECHNOLOGY

Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity

(2013) Bingfeng Chen et al.   ChemSusChem

High yield production of 5-hydroxymethylfurfural from cellulose by high concentration of sulfates in biphasic system

(2013) Ning Shi et al.   GREEN CHEMISTRY

A PDMS membrane with high pervaporation performance for the separation of furfural and its potential in industrial application

(2013) Fan Qin et al.   GREEN CHEMISTRY

Advances in 5-hydroxymethylfurfural production from biomass in biphasic solvents

(2013) Basudeb Saha et al.   GREEN CHEMISTRY

Functionalized partially hydroxylated MgF2 as catalysts for the dehydration of d-xylose to furfural

(2013) I. Agirrezabal-Telleria et al.   JOURNAL OF CATALYSIS

Direct degradation of cellulose to 5-hydroxymethylfurfural in hot compressed steam with inorganic acidic salts

(2013) Ning Shi et al.   RSC Advances

Pervaporation of ethanol from lignocellulosic fermentation broth

(2012) Sushil S. Gaykawad et al.   BIORESOURCE TECHNOLOGY

Conversion of Hemicellulose to Furfural and Levulinic Acid using Biphasic Reactors with Alkylphenol Solvents

(2012) Elif I. Gürbüz et al.   ChemSusChem

Enabling integrated biorefineries through high-yield conversion of fractionated pentosans into furfural

(2012) Anurag Mandalika et al.   GREEN CHEMISTRY

Furfural production from xylose + glucose feedings and simultaneous N2-stripping

(2012) I. Agirrezabal-Telleria et al.   GREEN CHEMISTRY

Entrainer-intensified vacuum reactive distillation process for the separation of 5-hydroxylmethylfurfural from the dehydration of carbohydrates catalyzed by a metal salt–ionic liquid

(2012) Zuojun Wei et al.   GREEN CHEMISTRY

The effect of solvent addition on fructose dehydration to 5-hydroxymethylfurfural in biphasic system over zeolites

(2012) V.V. Ordomsky et al.   JOURNAL OF CATALYSIS

Metal–organic framework ZIF-8 nanocomposite membrane for efficient recovery of furfural via pervaporation and vapor permeation

(2012) Xinlei Liu et al.   JOURNAL OF MEMBRANE SCIENCE

Production of 5-Hydroxymethylfurfural from Glucose Using a Combination of Lewis and Brønsted Acid Catalysts in Water in a Biphasic Reactor with an Alkylphenol Solvent

(2012) Yomaira J. Pagán-Torres et al.   ACS Catalysis

Furfural production from xylose using sulfonic ion-exchange resins (Amberlyst) and simultaneous stripping with nitrogen

(2011) I. Agirrezabal-Telleria et al.   BIORESOURCE TECHNOLOGY

Process intensification in the future production of base chemicals from biomass

(2011) J.P.M. Sanders et al.   CHEMICAL ENGINEERING AND PROCESSING

Biorefining: Heterogeneously Catalyzed Reactions of Carbohydrates for the Production of Furfural and Hydroxymethylfurfural

(2011) Reetta Karinen et al.   ChemSusChem

“One-Pot” Synthesis of 5-(Hydroxymethyl)furfural from Carbohydrates using Tin-Beta Zeolite

(2011) Eranda Nikolla et al.   ACS Catalysis

Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited

(2010) Joseph J. Bozell et al.   GREEN CHEMISTRY

Stability of Zeolites in Hot Liquid Water

(2010) Ryan M. Ravenelle et al.   Journal of Physical Chemistry C

Microreactor Process for the Optimized Synthesis of 5-Hydroxymethylfurfural: A Promising Building Block Obtained by Catalytic Dehydration of Fructose

(2009) T. Tuercke et al.   CHEMICAL ENGINEERING & TECHNOLOGY

Pervaporative separation of furfural from aqueous solution using modified polyurethaneurea membrane

(2009) Ujjal K. Ghosh et al.   DESALINATION

Solvent Effects on Fructose Dehydration to 5-Hydroxymethylfurfural in Biphasic Systems Saturated with Inorganic Salts

(2009) Yuriy Román-Leshkov et al.   TOPICS IN CATALYSIS