Journal
APPLIED SURFACE SCIENCE
Volume 568, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2021.150919
Keywords
Sulfur-doped V2O5/rGO; Sandwich-like structure; Zn2+ storage; Electrochemical properties; Aqueous Zn-ion battery
Categories
Funding
- Fundamental Research Funds for the Central Universities [DUT21LK34]
- Natural Science Foundation of Liaoning Province [2020-MS-113]
- National Natural Science Foundation of China [21771030, 21771029]
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The novel sandwich-like composite S-V2O5/rGO exhibits improved electrochemical properties for Zn2+ storage due to its enhanced electrical conductivity and facilitated ion and electron migration, leading to fast redox reaction kinetics. This structure combination with sulfur dopant provides a novel strategy for designing V-based architectures for aqueous multivalent ions batteries, demonstrating high capacity, stable cycle performance, and excellent rate stability.
The synthesis of V2O5 with novel architectures for aqueous Zn-ion batteries (AZIBs) has been developed great advances but is still a huge challenge. Herein, a sandwich-like composite, sulfur-doped V2O5/reduced graphene oxide/sulfur-doped V2O5 (denoted as S-V2O5/rGO) core-shell structure, is synthesized by the combination of hydrothermal and calcining processes, and this material exhibits improved electrochemical properties for Zn2+ storage. The rGO in the middle and S-dopant facilitate ion diffusion and electron transport and make the material easier for the electrolyte to enter, resulting in outstanding Zn2+ storage of S-V2O5/rGO. The Zn//S-V2O5/rGO battery delivers a high capacity up to 610 mAh.g(-1) at 0.1 A.g(-1) and stable cycle performance. The battery also delivers excellent rate stability with about 467, 458, 454, 447 and 442 mAh.g(-1) at 0.4, 0.8, 1.0, 1.5 and 2.0 A.g(-1). The energy densities are achieved as high as 333 Wh.kg(-1) at 286 W.kg(-1) and 306 Wh.kg(-1) at 1392 W.kg(-1) based on the mass of S-V2O5/rGO. The results prove that this sandwich-like structure combination with S-dopant can improve the electrical conductivity and facilitate the migration of Zn2+ and electrons, leading to fast redox reaction kinetics. These findings provide a novel strategy for designing novel V-based architectures for aqueous multivalent ions batteries.
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