4.7 Article

Rationally designed Mn2O3/CuxO core-shell heterostructure generated on copper foam as binder-free electrode for flexible asymmetric supercapacitor

Journal

APPLIED SURFACE SCIENCE
Volume 566, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2021.150715

Keywords

Core-shell heterostructure; Mn2O3 nanosheets; CUx O foam; All-solid-state supercapacitor

Funding

  1. Key R&D Program of Zhenjiang [GY2018016]
  2. Student Innovation Project of Jiangsu University [Y19A011]

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A unique core-shell heterostructure of Mn2O3 nanosheets attached to CuxO nanowires was successfully constructed, improving the poor conductivity and agglomeration issues of CuxO in supercapacitors and enhancing the capacitance and stability of the electrode material. The flexible asymmetric supercapacitor (FASC) device exhibited outstanding performance at power density, showing potential application prospects in the field of flexible supercapacitors.
Inherent poor conductivity and agglomeration of CuxO phase limit its further development in supercapacitors. High theoretical capacitance of Mn2O3 and the construction of core-shell heterostructure may provide a new strategy to solve these problems. Herein, the unique core-shell heterostructure of Mn2O3 nanosheets attached to CuxO nanowires is formed on copper foam (CF). This electrode material is prepared via an in-situ oxidation reaction followed by the combination of calcination and hydrothermal method. The areal capacitance of the asobtained Mn2O3/CuxO/CF electrode at hydrothermal time of 9 h is 1403.5 mF cm-2 (779.7F g-1) at current density of 2 mA cm-2 (1 A g-1), which is much greater than that of other electrodes. It also exhibits a good stability with 92.8% retention of initial capacitance after 10,000 cycles. Besides, the flexible asymmetric supercapacitor (FASC) device is assembled by Mn2O3/CuxO/CF-9 and activated carbon (AC) coated on nickel foam (NF) as respective positive and negative electrodes. It can deliver specific capacitance of 512.7 mF cm-2 at 2 mA cm-2, and reaches 120.2 mu Wh cm-2 at a power density of 1.3 mW cm-2. The outstanding electrochemical characteristics may be ascribed to the unique core-shell heterostructure, making it potential application in the field of flexible supercapacitors.

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