Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 61, Issue 10, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202117205
Keywords
CO2 Hydrogenation; DMT Hydrogenation; Dual-Promotion; One-Pot Catalysis; PET Methanolysis
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Funding
- Natural Science Foundation of China [21725301, 22072002, 21932002, 21821004]
- National Key R&D Program of China [2017YFB0602200]
- Key Research Program of Nanjing IPE Institute of Green Manufacturing Industry
- Jacob F. Buckman Chair Fund
- Tencent Foundation through the XPLORER PRIZE
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Polyethylene terephthalate (PET) and CO2, two chemical wastes that urgently need to be transformed in the environment, are simultaneously converted in a one-pot catalytic process through the synergistic coupling of three reactions. The chemical equilibria of both reactions are shifted forward, leading to significantly enhanced PET depolymerization. This synergistic catalytic process provides an effective way to simultaneously recycle two wastes and produce high-value chemicals.
Polyethylene terephthalate (PET) and CO2, two chemical wastes that urgently need to be transformed in the environment, are converted simultaneously in a one-pot catalytic process through the synergistic coupling of three reactions: CO2 hydrogenation, PET methanolysis and dimethyl terephthalate (DMT) hydrogenation. More interestingly, the chemical equilibria of both reactions were shifted forward due to a revealed dual-promotion effect, leading to significantly enhanced PET depolymerization. The overall methanol yield from CO2 hydrogenation exceeded the original thermodynamic equilibrium limit since the methanol was in situ consumed in the PET methanolysis. The degradation of PET by a stoichiometric ratio of methanol was significantly enhanced because the primary product, DMT was hydrogenated to dimethyl cyclohexanedicarboxylate (DMCD) or p-xylene (PX). This synergistic catalytic process provides an effective way to simultaneously recycle two wastes, polyesters and CO2, for producing high-value chemicals.
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