Regulation of High Miscibility for Efficient Charge-Transport in n-Doped Conjugated Polymers

Strong interchain interactions of conjugated polymers usually result in poor miscibility with molecular dopants, limiting the doping efficiency because of uncontrolled phase separation. We have developed a strategy to achieve efficient charge-transport and high doping miscibility in n-doped conjugated polymers. We solve the miscibility issue through disorder side-chains containing dopants better. Systemic structural characterization reveals a farther side-chain branching point will lead to higher disorders, which provides appropriate sites to accommodate extrinsic molecular dopants without harming original chain packings and charge-transport channels. Therefore, better sustainability of solid-state microstructure is obtained, yielding a stable conductivity even when overloading massive dopants. This work highlights the importance of realizing high host-dopant miscibility in molecular doping of conjugated polymers.

Automated summary

This study presents a strategy for achieving efficient charge transport and high doping compatibility in n-doped conjugated polymers. By using disorder side-chains, the issue of compatibility is addressed, allowing for the accommodation of molecular dopants without compromising the original chain packing and charge transport channels.