Catalytic Asymmetric Inverse‐Electron‐Demand Diels–Alder Reactions of 2‐Pyrones with Indenes: Total Syntheses of Cephanolides A and B

Asymmetric Inverse-Electron-Demand Diels-Alder Reactions of 2-Pyrones by Lewis Acid Catalysis

(2021) Xu-Ge Si et al.   SYNLETT

Total Synthesis of the Cephalotaxus Norditerpenoids (±)-Cephanolides A–D

(2021) Maximilian Haider et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Total Synthesis of (+)‐Mannolide C

(2021) Qiaoqiao Ao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (+)‐3‐Deoxyfortalpinoid F, (+)‐Fortalpinoid A, and (+)‐Cephinoid H

(2021) Zhiqiang Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Axially Chiral Biaryls by Diels–Alder/Retro-Diels–Alder Reaction of 2-Pyrones with Alkynes

(2021) Meng-Meng Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An enantioselective ambimodal cross-Diels–Alder reaction and applications in synthesis

(2021) Meng-Meng Xu et al.   Nature Catalysis

Enantioselective Synthesis of cis‐Decalin Derivatives by the Inverse‐Electron‐Demand Diels–Alder Reaction of 2‐Pyrones

(2020) Quan Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Total Synthesis of Cephanolide A

(2020) Hongyuan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diterpenoids from Cephalotaxus fortunei var. alpina and their cytotoxic activity

(2020) Yanzhi Li et al.   BIOORGANIC CHEMISTRY

Inverse‐Electron‐Demand Diels‒Alder Reactions of 2‐Pyrones: Bridged Lactones and Beyond

(2020) Guanghao Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Scalable Total Synthesis of (−)-Vinigrol

(2019) Xuerong Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Asymmetric Inverse‐Electron‐Demand Diels‐Alder Reaction of Pyrrolidone‐Dienes with Enals

(2019) Shu-Xiao Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Synthesis of Arene cis-Dihydrodiols from 2-Pyrones

(2019) Quan Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The [4 + 2] Cycloaddition of 2‐Pyrone in Total Synthesis

(2019) Quan Cai   CHINESE JOURNAL OF CHEMISTRY

17-nor-Cephalotane-Type Diterpenoids from Cephalotaxus fortunei

(2019) Zhan-Peng Ge et al.   JOURNAL OF NATURAL PRODUCTS

Cephasinenoside A, a new cephalotane diterpenoid glucoside from Cephalotaxus sinensis

(2019) Chun-Xue Zhao et al.   TETRAHEDRON LETTERS

Asymmetric Inverse-Electron-Demand Diels-Alder Reaction of 2-Pyrone and 2,5-Dienones via HOMO-Activation

(2018) Yuanchun Zhou et al.   ACTA CHIMICA SINICA

Total Synthesis of (±)-Cephanolides B and C via a Palladium-Catalyzed Cascade Cyclization and Late-Stage sp3 C–H Bond Oxidation

(2018) Lun Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sidearm Modified Bisoxazoline Ligands and Their Applications

(2018) Lijia Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Bioactive norditerpenoids from Cephalotaxus fortunei var. alpina and C. lanceolata

(2018) Ling Ni et al.   PHYTOCHEMISTRY

Cephanolides A–J, Cephalotane-Type Diterpenoids from Cephalotaxus sinensis

(2017) Yao-Yue Fan et al.   JOURNAL OF NATURAL PRODUCTS

Diterpenoids and Lignans from Cephalotaxus fortunei

(2017) Jin-Xin Zhao et al.   JOURNAL OF NATURAL PRODUCTS

Asymmetric Total Syntheses of (−)-Jerantinines A, C, and E, (−)-16-Methoxytabersonine, (−)-Vindoline, and (+)-Vinblastine

(2017) Nengzhong Wang et al.   ORGANIC LETTERS

Catalytic Asymmetric Desymmetrization of Cyclopentendiones via Diels–Alder Reaction of 3-Hydroxy-2-pyrones: Construction of Multifunctional Bridged Tricyclic Lactones

(2017) Li-Min Shi et al.   ORGANIC LETTERS

Enantioselective Total Synthesis of (+)-Iso-A82775C, a Proposed Biosynthetic Precursor of Chloropupukeananin

(2017) Takahiro Suzuki et al.   ORGANIC LETTERS

Total Synthesis of the Diterpenoid (+)-Harringtonolide

(2016) Hai-Jun Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyrone Diels-Alder Routes to Indolines and Hydroindolines: Syntheses of Gracilamine, Mesembrine, and Δ7 -Mesembrenone

(2016) Pei Gan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cephalotanins A-D, Four Norditerpenoids Represent Three Highly Rigid Carbon Skeletons fromCephalotaxus sinensis

(2016) Jin-Biao Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mannolides A–C with an Intact Diterpenoid Skeleton Providing Insights on the Biosynthesis of Antitumor Cephalotaxus Troponoids

(2016) Gang Ni et al.   ORGANIC LETTERS

Side Arm Strategy for Catalyst Design: Modifying Bisoxazolines for Remote Control of Enantioselection and Related

(2014) Saihu Liao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Switchable Diastereoselectivity in Enantioselective [4+2] Cycloadditions with Simple Olefins by Asymmetric Binary Acid Catalysis

(2013) Jian Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Gelsemiol

(2013) Patrick Burch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereoselective Total Synthesis of Hainanolidol and Harringtonolide via Oxidopyrylium-Based [5 + 2] Cycloaddition

(2013) Min Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Concise Total Synthesis of (+)-Scholarisine A Empowered by a Unique C–H Arylation

(2013) Myles W. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Natural products from Cephalotaxus sp.: chemical diversity and synthetic aspects

(2012) Hajer Abdelkafi et al.   NATURAL PRODUCT REPORTS

Total Syntheses of (±)-α-Lycorane and (±)-1-Deoxylycorine

(2012) Yong-Geun Jung et al.   ORGANIC LETTERS

Asymmetric Diels–Alder reaction of β,β-disubstituted enals and chromone-fused dienes: construction of collections with high molecular complexity and skeletal diversity

(2012) Jun-Long Li et al.   Chemical Science

Asymmetric Synthesis of Tetrahydroquinolines with Quaternary Stereocenters through the Povarov Reaction

(2011) Mingsheng Xie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Binary-Acid Catalysis with InBr3 in the Inverse-Electron-Demanding Hetero-Diels-Alder Reaction of Mono- and Bis-Substituted Cyclopentadienes: Remote Fluoro-Effect on Stereocontrol

(2011) Jian Lv et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic asymmetric [4 + 2] additions with aliphatic nitroalkenes

(2011) Keith J. Bartelson et al.   Chemical Science

Organocatalytic Asymmetric Inverse-Electron-Demand Diels-Alder Reaction of Electron-Deficient Dienes and Crotonaldehyde

(2010) Jun-Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Three-Component Inverse Electron-Demand Aza-Diels-Alder Reaction: Efficient Synthesis of Ring-Fused Tetrahydroquinolines

(2010) Mingsheng Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Diels-Alder and Inverse-Electron-Demand Hetero-Diels-Alder Reactions of β,γ-Unsaturated α-Ketoesters with Cyclopentadiene Catalyzed by N,N′-Dioxide Copper(II) Complex

(2010) Yin Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amino-Indanol Catalyzed Enantioselective Reactions of 3-Hydroxy-2-Pyridones

(2009) Julian Ying-Teck Soh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Catalyzed Inverse-Electron-Demand Diels−Alder Reaction of Tropones

(2009) Pingfan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Diels−Alder Reaction of Simple α,β-Unsaturated Ketones with a Cinchona Alkaloid Catalyst

(2008) Ravi P. Singh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Further Studies of the Norditerpene (+)-Harringtonolide Isolated fromCephalotaxus harringtoniavar.drupacea: Absolute Configuration, Cytotoxic and Antifungal Activities

(2008) Laurent Evanno et al.   PLANTA MEDICA