Article
Chemistry, Physical
Fucheng Wang, Yuxiao Meng, Xuanqi Chen, Lu Zhang, Guohua Li, Zhangfeng Shen, Yangang Wang, Yongyong Cao
Summary: The size of Ni-based catalysts plays a crucial role in the catalytic activity and selectivity of CO2RR, with larger Ni-based catalysts exhibiting higher catalytic activity and selective reduction of CO2 to CH4.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Multidisciplinary Sciences
Qiubo Zhang, Jiawei Wan, Junyi Shangguan, Sophia Betzler, Haimei Zheng
Summary: The study demonstrates that low temperature significantly affects the electrochemical deposition of Cu nanoparticles, resulting in the formation of Cu nanoparticles with different morphologies and crystallinity.
Article
Chemistry, Physical
Saemi Im, Heesun Park, Yeonseo Kim, Eunji Kwon, Somin Chae, Hyung-Kyu Lim, Sangheon Lee
Summary: This study identifies the novel structure-activity correlations resulting from the interfaces between Ag surface and Cu oxide subsurface, highlighting the pivotal role of oxygen atoms in promoting Cu-Ag alloy catalysts. The oxygen-induced activity promotion effect is anticipated to be a practical reference for the development of high-performance electrochemical CO2-to-CO conversion catalysts.
APPLIED SURFACE SCIENCE
(2022)
Article
Nanoscience & Nanotechnology
M. Nur Hossain, Rachelle M. Choueiri, Sharon Abner, Leanne D. Chen, Aicheng Chen
Summary: In this study, TiO2/Au nanocomposite was synthesized via a tailored galvanic replacement reaction (GRR). The synthesized TiO2/Au nanocomposites exhibited improved catalytic activities for CO2 reduction and generated more hydrocarbon molecules. Density functional theory calculations showed that TiO2/Au nanocomposites can increase the binding energy of the formed CO intermediate, reduce the free energy, and favor the generation of multicarbon products.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Zhongjun Ma, Xilin Zhang, Xueyun Han, Dapeng Wu, Hongju Wang, Zhiyong Gao, Fang Xu, Kai Jiang
Summary: By incorporating nickel phthalocyanine into defect-rich Ketjenblack through pi-pi stacking, the ECR performance can be greatly improved, showing high selectivity and activity in converting CO2 to CO. This synergistic catalytic effect is achieved by enhancing electron acceptability, reducing the formation energy of *COOH, and inhibiting the rival hydrogen evolution reaction.
APPLIED SURFACE SCIENCE
(2021)
Review
Chemistry, Multidisciplinary
Domenico Grammatico, Andrew J. Bagnall, Ludovico Riccardi, Marc Fontecave, Bao-Lian Su, Laurent Billon
Summary: This review discusses the state of the art of different catalyst-support systems for CO2RR and proposes necessary steps for future developments. The article emphasizes the need for standard benchmarking for comparison of these support systems and the development of advanced techniques to aid rational design principles.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Multidisciplinary Sciences
Peng Zhu, Zhen-Yu Wu, Ahmad Elgazzar, Changxin Dong, Tae-Ung Wi, Feng-Yang Chen, Yang Xia, Yuge Feng, Mohsen Shakouri, Jung Yoon (Timothy) Kim, Zhiwei Fang, T. Alan Hatton, Haotian Wang
Summary: This study demonstrates a continuous electrochemical carbon-capture design using an oxygen/water redox couple and a modular solid-electrolyte reactor. By performing oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) redox electrolysis, the device can efficiently absorb dilute carbon dioxide (CO2) molecules and continuously output a high-purity CO2 stream. The system achieves high capture rates, high Faradaic efficiencies, high carbon-removal efficiency, and low energy consumption.
Article
Chemistry, Applied
Devina Thasia Wijaya, Andi Haryanto, Hyun Woo Lim, Kyoungsuk Jin, Chan Woo Lee
Summary: This article reports a synthetic method using MOF-derived carbon as a template to prepare sub-2 nm mixed metal oxide (MMO) catalysts for CO2 electroreduction. The Ni-rich (Pd20-Ni80/ZC) catalyst exhibits superior performance compared to other Pd-Ni compositions, with improved CO production and Faradaic efficiency. This work provides a general synthetic strategy for MMO electrocatalysts and can pave a new way for screening multimetallic catalysts with a dynamic electrochemical interface.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Christoph J. Bondue, Matthias Graf, Akansha Goyal, Marc T. M. Koper
Summary: The study focuses on the electrochemical reduction of CO2 at gold electrodes under mildly acidic conditions. Increasing the CO2 partial pressure enhances the rate of CO2 reduction and suppresses hydrogen evolution, leading to high Faradaic efficiencies close to 100%. By suppressing hydrogen evolution and using protons for water formation, the study derived a general design principle for acid CO2 electrolyzers to match the mass transfer of protons to the electrode surface.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Review
Chemistry, Multidisciplinary
Paramita Saha, Sk Amanullah, Abhishek Dey
Summary: This article discusses the progress in the field of electrochemical CO2RR, focusing on the issue of selectivity and exploring the factors that influence selectivity. Mechanistic investigations of CO2RR, through the detection and characterization of reaction intermediates, provide a basis for developing highly selective CO2RR catalysts.
ACCOUNTS OF CHEMICAL RESEARCH
(2022)
Article
Chemistry, Inorganic & Nuclear
Lei Gong, Baotong Chen, Ying Gao, Baoqiu Yu, Yinhai Wang, Bin Han, Chenxiang Lin, Yongzhong Bian, Dongdong Qi, Jianzhuang Jiang
Summary: We have developed a 2D COF based on tetraphenyl-p-phenylenediamine and metalloporphyrin for electrocatalytic CO2 reduction. The COF shows high reaction efficiency and current density.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Analytical
Silvia Mena, Esteve Ribas, Clara Richart, Iluminada Gallardo, Jordi Faraudo, Scott K. Shaw, Gonzalo Guirado
Summary: The paper focuses on the role of carbon dioxide in controlling the Earth's temperature and the environmental problems caused by its increased concentration in the atmosphere. It discusses the use of ionic liquids for efficient CO2 capture and conversion, utilizing electrochemical, spectroscopic, and molecular dynamics techniques to understand the reduction mechanism under various conditions. The research opens up possibilities for theoretical-experimental approaches to determine the CO2 reduction mechanism and the dependency of product formation on the electrode material and solvent used.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Xuan Yang, Ji Hoon Lee, Shyam Kattel, Bingjun Xu, Jingguang G. Chen
Summary: The electrochemical reduction reaction of carbon dioxide (CO2RR) can be manipulated by engineering the surface structure of Pd-based catalysts. In Ag@Pd1-2L core-shell nanocubes, the formation of PdH becomes difficult, leading to the production of formic acid. On the other hand, Pd nanocubes show high selectivity for CO due to the formation of PdH. Ag nanocubes exhibit high selectivity for H-2.
Article
Multidisciplinary Sciences
Burcu Gurkan, Xiao Su, Aidan Klemm, Yonghwan Kim, Shaama Mallikarjun Sharada, Andres Rodriguez-Katakura, Kareesa J. Kron
Summary: The growing interest in using electricity for CO2 separation is driven by its potential advantages over traditional thermal and pressure swing processes. However, the practical application is still limited by the availability of renewable electricity. Significant advances have been made in the past decade in electrolytes and electrodes, opening up new possibilities for future research and applications.
Article
Chemistry, Multidisciplinary
Longlong Fan, Qinghong Geng, Lian Ma, Chengming Wang, Jun-Xuan Li, Wei Zhu, Ruiwen Shao, Wei Li, Xiao Feng, Yusuke Yamauchi, Cuiling Li, Lei Jiang
Summary: In this study, three-dimensional ordered porous cuprous oxide cuboctahedra were designed and synthesized, and exhibited outstanding electrochemical CO2-to-C2+ conversion. The ordered pores effectively confined and accumulated *CO adsorption during the reduction of CO2, facilitating efficient dimerization for the formation of C2+ products. The 3DOP structure also induced a higher local pH value, enhancing the C-C coupling reaction and suppressing competing H2 evolution.
Article
Materials Science, Ceramics
Ghulam Asghar, Xue Dong, Sudong Chae, Chan-Sei Yoo, Seungbae Oh, Kyung Hwan Choi, Jiho Jeon, Chaeheon Woo, Tae Yeong Kim, Jungyoon Ahn, Hyung-Suk Oh, Hak Ki Yu, Jae-Young Choi
Summary: In the current ubiquitous age of wireless communication technologies operating at higher frequencies, there is a high demand for dielectrics with low dielectric constant and low dielectric loss. This study presents a novel coating method for synthesizing hollow forsterite ceramics. Utilizing magnesium glycolate as the core material, forsterite phases with high purity and uniform sizes were obtained at a relatively low calcination temperature of 900°C/2 h. The synthesized forsterite ceramics exhibited excellent dielectric properties at 1 GHz, with a dielectric constant (er) of 1.85 and dielectric loss of 0.007.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Multidisciplinary
Sang Hoon Lee, Byung Joo Jeong, Kyung Hwan Choi, Jiho Jeon, Bom Lee, Sooheon Cho, Han Eol Jang, Hyeon Ho Cho, Hyung-Suk Oh, Bum Jun Kim, Hak Ki Yu, Jae-Young Choi
Summary: In this study, a one-dimensional (1D) van der Waals material Nb2Se9 was grown as nanowire arrays using a liquid precursor-assisted chemical vapor deposition (CVD) process. Compared to other synthesis methods, the aligned Nb2Se9 nanowires exhibit higher photoresponse and stability. This controllable CVD growth offers a possibility of using aligned Nb2Se9 nanowires as building blocks for large integrated circuits based on 1D materials.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Materials Science, Multidisciplinary
Ghulam Asghar, Xue Dong, Sudong Chae, Chan-Sei Yoo, Jiho Jeon, Chaeheon Woo, Tae Yeong Kim, Jungyoon Ahn, Xiaojie Zhang, Hyung-Suk Oh, Hak Ki Yu, Jae-Young Choi
Summary: Dielectric materials with low dielectric constant and low loss are in high demand in the rapid development of telecommunication systems toward 5G and 6G. A modified solid-state reaction method was used to synthesize low dielectric constant forsterite (Mg2SiO4) at low calcination temperatures by using MgO and fumed silica nanoparticles (NPs). The forsterite phase was obtained at 1000 degrees C, where the sintering temperature was reduced from 1500 degrees C to 1200 degrees C. The as-synthesized forsterite has a low dielectric constant of 3.9 with low tan delta = 0.00047 at 1 GHz. Low-temperature sintered forsterite is suitable for microelectronics applications.
Article
Chemistry, Physical
Hee Jun Kim, Sang Heon Kim, Sun-Woo Kim, Jin-Kyeom Kim, Chentian Cao, Yongchul Kim, Ungsoo Kim, Geunsik Lee, Jae-Young Choi, Hyung-Suk Oh, Hyun-Cheol Song, Won Jun Choi, Hyesung Park, Jeong Min Baik
Summary: This study presents a simple and cost-effective method to achieve the crystallization of LaFeO3 perovskite at low temperatures (300-500 degrees C), resulting in an excellent oxygen evolution reaction (OER) catalyst with inherent catalytic surface. The synthesis involved the formation of a cyanogel-peroxo-complex as a metastable molecular precursor, which was obtained via ligand exchange using potassium cyanide solution. The electrocatalysts based on LaFeO3 nanoparticles exhibited remarkable OER performance, surpassing the commercialized IrOx/C catalysts in terms of overpotential and Tafel slope under alkaline conditions. The catalyst's high stability was confirmed by the insignificant potential change during a 50-hour long-term stability test.
Article
Chemistry, Physical
Jialu Wang, Hyunchul Kim, Hojin Lee, Young-Jin Ko, Man Ho Han, Woong Kim, Jeong Min Baik, Jae -Young Choi, Hyung-Suk Oh, Woong Hee Lee
Summary: In this study, it was found that the FeCoSbOx electrode showed better stability in acidic conditions compared to the FeCoOx electrode. The presence of Sb in the FeCoSbOx electrode resulted in a higher oxidation state of Sb and a shorter lattice distance, indicating a strong Sb-O bonding. Thus, the incorporation of Sb enhanced stability in acidic media by increasing thermodynamic stability and inhibiting distortion during the reaction. This research offers new principles for designing electrocatalysts that are stable in acidic media.
Article
Chemistry, Physical
Woong Hee Lee, Kyeongsu Kim, Jai Hyun Koh, Dong Ki Lee, Da Hye Won, Hyung-Suk Oh, Ung Lee, Byoung Koun Min
Summary: Carbon dioxide emissions from burning fossil fuels have contributed to global warming and increased climate change risks. To mitigate these impacts, a new energy economic concept called the green-alcohol economy is proposed, where green-alcohol can be used as fuel for transportation and as a liquid organic hydrogen carrier. The production and dehydrogenation of green-alcohol are crucial steps in building a feasible green-alcohol economy.
Article
Multidisciplinary Sciences
Jiwon Kim, Jae Hyung Kim, Cheoulwoo Oh, Hyewon Yun, Eunchong Lee, Hyung-Suk Oh, Jong Hyeok Park, Yun Jeong Hwang
Summary: An electro-assisted approach using acid-treated carbon electrocatalyst and in-situ cathodically generated reactive oxygen species is proposed for the partial oxidation of methane at ambient temperature and pressure. Reactive oxygen species activate methane and methanol, leading to selective methane partial oxidation. This study presents a method for the electrochemically assisted partial oxidation of methane to produce liquid oxygenate, HCOOH, selectively.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Hyewon Yun, Woong Choi, Dongwoo Shin, Hyung-Suk Oh, Yun Jeong Hwang
Summary: Tailoring catalyst performance in zero-gap MEA electrolyzers is crucial. However, few studies have directly focused on MEA systems combined with operando techniques. This study demonstrates improved catalytic performance of AuAg bimetallic catalyst by adjusting the atomic arrangement and extrinsic properties. The catalyst achieved high CO selectivity and CO partial current density and mass activity through proper adjustment of the carbon support.
Article
Chemistry, Physical
Geunsu Bae, Minho M. Kim, Man Ho Han, Junsic Cho, Dong Hyun Kim, Moulay-Tahar Sougrati, Jinjong Kim, Kug-Seung Lee, Sang Hoon Joo, William A. Goddard, Hyung-Suk Oh, Hyungjun Kim, Frederic Jaouen, Chang Hyuck Choi
Summary: This study shows the time-resolved changes in active site density and turnover frequency of Fe-N-C catalysts, along with the decrease in oxygen reduction reaction current. The mechanism of Fe leaching is identified through operando diagnosis, and a strategy using Pt ions as stabilizers is proposed to enhance fuel cell stability. This research provides guidance for designing durable Fe-N-C catalysts.
Article
Nanoscience & Nanotechnology
Sudong Chae, Chaeheon Woo, Geun Ho Gu, Tae Yeong Kim, Jiho Jeon, Hyeok Jin Kwon, Seungbae Oh, Kyung Hwan Choi, Xue Dong, Jungyoon Ahn, Ghulam Asghar, Hyung-Suk Oh, Hak Ki Yu, Hyo Won Kim, Jae-Young Choi
Summary: This study reports an extremely selective and sensitive electrocatalyst for dopamine sensing, which is prepared by vanadium selenide. The electrocatalyst exhibits unique affinity characteristics, allowing it to detect dopamine only in the presence of interferents.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Seokmin Shin, Siraj Sultan, Zong-Xian Chen, Hojeong Lee, Hansaem Choi, Tae-Ung Wi, Changhyun Park, Taewon Kim, Chanhee Lee, Jihong Jeong, Hyeju Shin, Tae-Hee Kim, Hyungkuk Ju, Hyung Chul Yoon, Hyun-Kon Song, Hyun-Wook Lee, Mu-Jeng Cheng, Youngkook Kwon
Summary: Electrochemical co-reduction of CO2 and NO3- to urea is a promising alternative industrial process with lower energy consumption and CO2 emission. However, the lack of suitable catalysts leads to low efficiency and yield. In this study, copper with atomic-scale spacings between its facets significantly improves the electrochemical synthesis of urea.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Physical
Young-Jin Ko, Hyunchul Kim, Woong Hee Lee, Man Ho Han, Cheoulwoo Oh, Chang Hyuck Choi, Woong Kim, Jeong Min Baik, Jae-Young Choi, Peter Strasser, Hyung-Suk Oh
Summary: In this study, dendritic Pt (PtND) and Ir (IrND) combined with a stable oxide support (antimony doped tin oxide, ATO) were designed for the oxygen electrode. The PtND-IrND/ATO catalyst showed lower average oxidation states and less dissolution than a Pt-Ir/C catalyst, leading to enhanced stability and high round trip efficiency in URFCs.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Haesol Kim, Chang Hyuck Choi, Junsic Cho, Hyung-Suk Oh
Summary: Securing the electrochemical durability of platinum is crucial for the success of PEMFC. The dissolution of platinum is a major cause of PEMFC degradation, and its mechanism is still not well understood. In this study, a chemical dissolution process of platinum under various electrocatalytic conditions is elucidated. The process occurs intensively during potential perturbations with a millisecond timescale, which has not been seriously considered before. The results suggest that stable platinum electrocatalysis can be achieved with further development of rational synthetic or systematic strategies.
Article
Chemistry, Physical
Cheoulwoo Oh, Man Ho Han, Young-Jin Ko, Jun Sik Cho, Min Wook Pin, Peter Strasser, Jae-Young Choi, Hansung Kim, Chang Hyuck Choi, Woong Hee Lee, Hyung-Suk Oh
Summary: This study synthesized a Pt-Ni alloy catalyst to improve the durability of anion exchange membrane-based unitized regenerative fuel cells (AEM-URFCs) and revealed the underlying mechanism.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Ji Hwan Song, Seohyeon Ka, Chulwan Lim, Man Ho Han, Dong Ki Lee, Hyung-Suk Oh, Woong Hee Lee
Summary: We have revealed the reaction environment of the anode during the CO2 reduction reaction, finding that the pH fluctuations caused by nonuniform ion and water distribution result in rapid phase transition and severe degradation of nickel-based electrodes in MEA.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)