4.8 Article

Silk-Waste-Derived Porous Carbon for Fast Electric Heating under Safe Voltage

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 4, Pages 6005-6015

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c21874

Keywords

silk waste; activator; pore structure; safe voltage; electric heating

Funding

  1. National Natural Science Foundation of China [U20A20264, 52003243]
  2. China Agriculture Research System of MOF
  3. Zhejiang Provincial Natural Science Foundation of China [LQ21E030010]
  4. High-level Talents Startup Funds of Zhejiang Sci-Tech University [19012394-Y]
  5. Fundamental Research Funds of Zhejiang Sci-Tech University [2021Q013]
  6. China Agriculture Research System of MARA

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Porous activated carbon derived from silk waste was prepared using a simple method, with different activators influencing its properties significantly. Among them, the porous carbon activated by 0.05 M KHCO3 showed larger specific surface area, higher graphitization degree, and lower resistance, resulting in higher electrothermal efficiency and better electric heating performance. The electric heating cotton@carbon composite fabric prepared using the same method also exhibited good electric heating properties and stability.
Fast and safe electric heating is highly needed in extreme climates or thermal therapy. Herein, porous activated carbon derived from silk waste is prepared by a simple method. Various porous activated carbons are obtained using different types and concentrations of activator (KOH, KCl, and KHCO3). The effect of the microstructure on the electric heating performance of these carbons is investigated carefully. The type, activator concentration, and carbonization temperature play key roles in the regulation of electric heating properties. The porous carbon activated by 0.05 M KHCO3 at 800 degrees C demonstrates larger specific surface area (3077 m(2) g(-1)), higher graphitization degree, and lower resistance (2.4 Omega cm), which synergistically contribute greatly to its higher electrothermal efficiency and better electric heating performance. The equilibrium temperature could reach 73 degrees C in 2 min under a safe voltage of 12 V, proving the better pore-forming capacity and activating function of KHCO3. An electric heating cotton@carbon composite fabric with quite good electric heating property and stability is also prepared, which could reach 38 degrees C in 2 min under 12 V safe voltage and maintain a temperature 10 degrees C higher than the ambient temperature even when bent at an angle of 55 degrees. This activated carbon derived from waste protein using a simple and cheap process has great potential in practical applications.

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