Basaltic glass formed from hydrovolcanism and impact processes: Characterization and clues for detection of mode of origin from VNIR through MWIR reflectance and emission spectroscopy

The CheMin X-ray diffraction instrument on-board the Curiosity rover in Gale crater has measured a consistent X-ray amorphous component in drill core samples examined to-date, clearly demonstrating that X-ray amorphous materials are a significant fraction of the martian surface layer. Glasses are potential components of this amorphous material and in this study, basaltic tephras from several hydro and glaciovolcanic centers, as well as impact melts from India's Lonar Crater, were examined using thin section petrography, visible and near-infrared reflectance and mid-wave infrared emission spectroscopy as well as measuring major and minor element chemistry of representative samples using X-ray fluorescence (XRF)spectroscopy. The objectives of this study have been to look for distinguishing characteristics between volcanic and impact glasses and to determine features that indicate whether the glasses are fresh or altered using methods available on current and planned Mars rovers. Spectral features in the visible and near-infrared (VNIR) that can be used as indicators of alteration include the development of hydration features at 1.9 and similar to 3 mu m and a feature attributed to ferric oxide development at 0.48 mu m. In the mid-wave infrared, it was observed that glass-rich tephra field samples did not display a broad, disordered glass feature near 9-10 mu m (as is observed in pristine basaltic glasses) but rather a doublet with centers near 9.5 and 11 mu m attributed in earlier work to incipient devitrification into SiO4 chain and sheet structures respectively. A tentative observation was made that the Si-O bending feature, observed in all the sample spectra near 22 mu m was broader in the hydro- and glaciovolcanic glass samples than in the impact glass samples. Hydro- and glaciovolcanic glass-rich tephra samples were used as library spectra in linear deconvolution analyses of Mars Global Surveyor Thermal Emission Spectrometer (MGS TES) surface spectral types. These incipiently devitrified glass spectra were selected for all of the surface types and formed close to 40% of the N. Acidalia Planitia spectral type. (C) 2016 Elsevier Inc. All rights reserved.