Journal
HELVETICA CHIMICA ACTA
Volume 99, Issue 7, Pages 494-498Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.201600030
Keywords
Unonopsisstipitata; Aporphine alkaloid; Rotamers; (+)-N-Formylnorglaucine; Annonaceae
Categories
Funding
- CAPES
- FAPEAM
- CNPq
- FINEP
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(+)-N-formylnorglaucine (1), an aporphine alkaloid containing a formyl group linked to the heterocyclic nitrogen, was isolated from the leaves of Unonopsisstipitata, an Amazon medicinal plant. The chemical structure was characterized based on 1D- and 2D-NMR spectroscopy and HR-ESI-MS. NMR spectra revealed that 1 is composed of two rotamers (1a and 1b) in a ratio of approximately 2:1. In addition, the fragmentation behavior of 1 displayed an unusual fragmentation pattern compared to regular aporphine alkaloids. Thus, this compound is reported for the first time as a natural product in this study.
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