Article
Engineering, Environmental
Luchao Yue, Dong Wang, Zhenguo Wu, Wenxi Zhao, Yuchun Ren, Longcheng Zhang, Benhe Zhong, Na Li, Bo Tang, Qian Liu, Yonglan Luo, Abdullah M. M. Asiri, Xiaodong Guo, Xuping Sun
Summary: A productive approach of in-situ coating conductive polymer carbon is proposed to preserve the structure of copper selenide (Cu2Se) anode in sodium-ion batteries (SIBs). The encapsulation of Cu2Se nanosheets with polypyrrole (PPy) shell improves electronic conductivity and alleviates volume swelling, resulting in satisfactory electrochemical performance including high specific capacity and impressive rate capacity.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Jay Singh, Seulgi Lee, Priya Yadav, Sungjin Kim, Jaekook Kim, Alok Kumar Rai
Summary: In this study, a hydrothermal synthesis method was used to produce a mulberry-like mesoporous CoMoO4 anode material with improved electrochemical properties for lithium ion and sodium ion batteries. The unique morphology of the CoMoO4 material led to high reversible discharge capacity and long cycle stability, making it a promising alternative high-performance anode material for sodium ion battery applications.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Junyang Hu, Huwei Wang, Shuwei Wang, Yu Lei, Lei Qin, Xiaojing Li, Dengyun Zhai, Baohua Li, Feiyu Kang
Summary: Research shows that the deposition mechanism of sodium and potassium in metal batteries differs from that of lithium, resulting in the formation of micrometer-scale granules, which may cause short circuits in the battery.
ENERGY STORAGE MATERIALS
(2021)
Article
Energy & Fuels
Jens Sandherr, Max-Jonathan Kleefoot, Sara Nester, Christian Weisenberger, Anjali K. M. DeSilva, Dominik Michel, Sarah Reeb, Mathias Fingerle, Harald Riegel, Volker Knoblauch
Summary: This paper proposes a novel approach of micro embossing for improving the performance of graphite-based anodes in lithium-ion batteries. The method enhances the hole structure, reduces the resistance, and increases the charging speed. Compared to laser processing, micro embossing results in better hole geometry and less loss of active material, leading to improved capacity retention.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Physical
Guocui Xi, Tianbiao Zeng
Summary: In this work, GeS2/C composites were synthesized and a three-dimensional flexible electrode (3D-GeS2/C electrode) was prepared. The carbon layer of GeS2/C and the CNT network in the 3D-GeS2/C electrode effectively restrained volume expansion and enhanced electric conductivity, thus improving the cycling stability of GeS2. These results provide inspiration for improving the performance of GeS2 and fabricating 3D flexible electrodes.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Tianbiao Zeng, Zhongming Li, Dong Feng, Yuanzhi Zhu
Summary: This study prepared a 3D thick anode for sodium ion batteries using binary metal sulfide on graphene, which can improve sodium ion transfer rate and achieve higher mass capacity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Hanhao Liu, Dan Li, Honglang Liu, Chao Wang, Yanzhong Wang, Yanjun Chen, Yaoyao Linghu, Zhen Tian, Huaihe Song, Jisheng Zhou, Li Guo
Summary: Due to its low cost and abundant sodium resource, sodium ion batteries (SIBs) are considered as a promising alternative to lithium-ion batteries (LIBs). However, the slow sodium kinetics and serious volume expansion of the anode material remain major challenges. In this study, Cu2Se nanoarrays with a three-dimensional (3D) skeleton structure were developed on the surface of copper foam by in situ selenization, and used as high-performance binder-free anodes for sodium ion batteries. The Cu2Se-1 nanoarrays exhibited high reversible capacity, remarkable rate capability, and enhanced storage kinetics of sodium ions.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Ying Wang, Ping Niu, Jianzhong Li, Shulan Wang, Li Li
Summary: Phosphorus composite anodes are considered promising candidates for sodium-ion batteries and potassium-ion batteries, but their practical use is limited by poor cycling stability and sluggish electrochemical reaction dynamics caused by volume variation and low electronic conductivity. Compositing with a suitable second component has been proposed as an effective strategy to potentially resolve these issues.
ENERGY STORAGE MATERIALS
(2021)
Article
Engineering, Environmental
Shan Cai, Fen Yan, Yanxu Zhao, Mingqi Li, Yiwen Chen, Xinrui He, Chao Wang
Summary: Developing anode materials with excellent comprehensive electrochemical performance and low cost is crucial for the practical application of sodium-ion batteries on a large scale. In this study, a novel hierarchical micro-composite (H-BiS/EGF) assembled from Bi nano/submicron spheres and expanded graphite flakes is fabricated using cost-effective methods. The H-BiS/EGF micro-composite shows promising performance as an anode for sodium-ion half cells, with high coulombic efficiency, reversible capacity, cycle stability, and rate capability. Additionally, the sodium-ion full cell constructed with the H-BiS/EGF anode and C coated Na3V2(PO4)(3)/rGO cathode exhibits high energy density and good cycle performance.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Nanoscience & Nanotechnology
Tianbiao Zeng, Huaibo Yu, Dan Luo, Huibin Guan, Hanna He, Chuhong Zhang
Summary: This study proposes a novel chemical cross-linking strategy to fabricate GeP thick electrodes for high areal capacity sodium-ion batteries. The 3D network formed by chemical cross-linking enhances charge transfer, stress relief, and volume expansion/shrinkage of the electrode. The hierarchical porous structure ensures uncompromised reaction kinetics as the electrode thickness increases.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Gaofeng Li, Junxiao Wang, Jun Chu, Minle Li, Zijun Hu, Feng Wang, Yan Han, Taotao Cai, Zhiping Song
Summary: This study systematically investigated the electrochemical performance and behaviors of two organic anode materials for sodium-ion batteries. It found that one of the materials, Na4PTC, exhibited exceptional ultrafast and ultrastable Na-ion storage performance in the ether electrolyte, setting new records for organic anode materials. Mechanism analysis revealed the factors contributing to its excellent performance.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Ji Ma, Yuankun Li, Xiaojie Wei, Chunting Liu
Summary: Reduction roasting strategy was employed to transform hematite into powerful anode materials to store Li+, Na+, and K+ ions, constructing a porous structure to enhance ion accessibility. The newly-designed anodes were tested for storage capacity, cycling stability, and rate performances, while cyclic voltammetry curves and electrochemical impedance spectra were measured to unveil ion-storage mechanisms.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Review
Electrochemistry
Yao Liu, Wei Li, Yongyao Xia
Summary: While carbon, oxide, and silicon-based materials have limitations in current LIB applications, polyanionic compounds have gained attention for their ability to stabilize structures, adjust redox couples, and provide migration channels for guest ions, leading to electrode materials with long-term cycling, high energy density, and outstanding rate capability.
ELECTROCHEMICAL ENERGY REVIEWS
(2021)
Article
Agricultural Engineering
Lianghao Yu, Linlin Zhang, Xuedong He, Xin Tao, Guangzhen Zhao, Haoliang Xie, Ruilin Zhu, Guang Zhu
Summary: In this study, low-cost puffball was thermally treated to produce cost-effective porous carbon as an anode material for sodium-ion batteries. The resulting carbon material exhibited a unique morphology and showed remarkable performance, including excellent reversible capacity, impressive cycling stability, and high initial coulombic efficiency.
INDUSTRIAL CROPS AND PRODUCTS
(2024)
Article
Chemistry, Multidisciplinary
Dong Zhou, Xiao Tang, Xiuyun Zhang, Fan Zhang, Junru Wu, Feiyu Kang, Baohua Li, Guoxiu Wang
Summary: The introduction of sodium ions enhances the conversion of calcium polysulfides, while the presence of calcium ions forms a protective shield around the sodium metal anode, effectively suppressing dendrite growth. This multi-ion strategy shows promise in developing low-cost non-lithium metal-sulfur batteries with high reversible capacity and long cycle life.
Article
Engineering, Environmental
Pengfeng Jiang, Guangyuan Du, Yuansheng Shi, Fengquan She, Pengqian Guo, Guoyu Qian, Xueyi Lu, Fangyan Xie, Xia Lu
Summary: The smart manufacturing of solid-state electrolytes (SSEs) is crucial for the assembly and performance improvement of solid-state batteries. This study employed an ultrafast high-temperature sintering method to prepare Na3Zr2Si2PO12 ceramic SSEs with high ionic conductivity. The prepared SSEs exhibited excellent electrochemical performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Jieduo Guan, Qiaofeng Huang, Lianyi Shao, Xiaoyan Shi, DongDong Zhao, Liubin Wang, Zhipeng Sun
Summary: Aqueous zinc ion batteries (AZIBs) have shown promising potential as next-generation energy storage devices due to their high safety and low cost. However, the low electronic conductivity of polyanionic cathode materials has limited their cycling stability and rate performance. In this study, a 3D composite (N3VPF@rGO) consisting of mesoporous Na3V2(PO4)(2)F-3 nanocuboids cladded by reduced graphene oxide (rGO) was successfully synthesized using a novel microwave hydrothermal and subsequent calcination strategy. The N3VPF@rGO composite exhibited enhanced conductivity, pseudocapacitive behavior, enlarged D-Zn(2+), and stable structure, leading to excellent Zn2+ storage performance, including high capacity, high redox potentials, high rate capacity, and extreme cycling stability. The results also demonstrated the practical application values of the soft package batteries. In situ X-ray diffraction, ex situ transmission electron microscopy, and X-ray photoelectron spectroscopy were employed to investigate the reversible Zn2+ insertion/extraction mechanism.
Review
Chemistry, Multidisciplinary
Jiaqi Cao, Guoyu Qian, Xueyi Lu, Xia Lu
Summary: This review discusses the fabrication methods of 3D framework-based composite Li metal anodes, including electrodeposition, molten Li infusion, and pressure-derived fabrication. Designing a 3D framework with high specific surface area and sufficient space is crucial for improving the inherent drawbacks of Li metal. These methods can provide insights for future Li metal batteries with high energy density and low N/P ratio.
Review
Chemistry, Multidisciplinary
Xueyi Lu, Mohang Cai, Xuemin Wu, Yongfei Zhang, Shuai Li, Shijun Liao, Xia Lu
Summary: 2D materials have attracted significant attention in various fields, such as electronics, biology, sensors, and energy storage. The preparation of high-quality and high-yield 2D nanosheets is crucial for their important applications in energy storage and conversion. Electrochemical exfoliation is considered as a promising and convenient method for the large-scale production of uniform 2D nanosheets. This review provides an overview of recent developments in electrochemical delamination, including protocols, categories, principles, and operating conditions. The applications of electrochemically exfoliated 2D materials in energy storage and conversion are also discussed.
Review
Energy & Fuels
Pengfeng Jiang, Guangyuan Du, Jiaqi Cao, Xianyong Zhang, Chuanchao Zou, Yitao Liu, Xia Lu
Summary: Solid-state batteries (SSBs) are promising candidates for next-generation energy storage technologies due to their safety, high-energy density, wide temperature tolerance, and simple packaging. Developing solid-state electrolytes with high ionic conductivity, wide electrochemical window, and low interface resistance is essential for practical SSBs. This review summarizes recent progress in oxide inorganic solid-state electrolytes and discusses the critical issues and opportunities for oxide-based SSBs.
Article
Chemistry, Inorganic & Nuclear
Rui Wang, Yang Yang, Xiaocheng Xu, Sijie Chen, Alex Trukhanov, Ruiying Wang, Lianyi Shao, Xia Lu, Hui Pan, Zhipeng Sun
Summary: In this study, a three-dimensional gallium-doped FeOOH/Ni3S2 nanosheet array has been successfully designed and fabricated, demonstrating outstanding electrocatalytic performance for the oxygen evolution reaction. Ga doping in Ni3S2 creates exposed active sites and enhances the interfacial coupling effects between FeOOH and Ni3S2. The optimized electrocatalyst requires a low overpotential of 274 mV at 100 mA cm(-2) and exhibits impressive durability of up to 24 h.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Materials Science, Multidisciplinary
Fengquan She, Aosong Gao, Pengfeng Jiang, Yifan Zhou, Xiaoqi Zhang, Muzi Yang, Li Gong, Jian Chen, Xia Lu, Fangyan Xie
Summary: The energy density of solid-state lithium metal battery can be greatly improved by using lithium metal as the anode due to its high theoretical capacity and most negative electrode potential. However, the presence of a passivation layer on the highly active surface of lithium metal affects the performance and safety of the battery. In this study, X-ray photoelectron spectroscopy (XPS) is used to analyze the composition and thickness of the passivation layer and investigate its impact on the stability of the lithium metal surface.
Article
Chemistry, Physical
Junzhi Hong, Ling Xie, Chenglong Shi, Xiaoyi Lu, Xiaoyan Shi, Junjie Cai, Yanxue Wu, Lianyi Shao, Zhipeng Sun
Summary: The poor electronic conductivity and structural instability of vanadium-based cathode materials for aqueous zinc-ion batteries restrict their electrochemical properties. Zinc dendrites can puncture the separator and cause a short circuit in the battery. A unique multidimensional nanocomposite is designed to enhance the structural stability and electronic conductivity of the electrode material. The addition of Na2SO4 in the electrolyte prevents cathode material dissolution and suppresses zinc dendrite growth. The V2O3@SWCNHs@rGO electrode shows high initial and discharge capacity.
Article
Materials Science, Multidisciplinary
Jiangling Luo, Lianyi Shao, Lu Yu, Xiaoyan Shi, Junling Xu, Jianchao Sun, Lifeng Hang, Yanxue Wu, Zhipeng Sun
Summary: Sodium-ion batteries (SIBs) are promising for large-scale energy storage applications, but face challenges due to hindrance of sodium ion diffusion. Researchers have developed a three-dimensional carbon network composed of V5Se8 and multi-walled carbon nanotubes to enhance the reversible sodium ion storage capacity and cycling stability. The V5Se8/MWCNTs electrodes exhibit outstanding rate capacity, initial reversible capacity, and cyclic stability. The reaction mechanism of the electrode in SIBs has been investigated, and the full cell coupled with a Na3V2(PO4)(2-)F-3@reduced graphene oxide cathode demonstrates excellent discharge capacity and cycling stability.
MATERIALS TODAY PHYSICS
(2023)
Article
Engineering, Environmental
Qiaofeng Huang, Lianyi Shao, Xiaoyan Shi, Jieduo Guan, Junling Xu, Yanxue Wu, Zhipeng Sun
Summary: In this work, Na3V2O2(PO4)2F nanoparticles wrapped by reduced graphene oxide (rGO) were successfully prepared using a facile microwave-assisted solvothermal approach with postheat treatment. The optimized electrolyte composition and rGO content contribute to the high pseudocapacitive contribution, high diffusion coefficient, low electrochemical impedance, favorable electrode wettability, and stable structure, resulting in excellent electrochemical properties of Na3V2O2(PO4)2F@rGO in hybrid aqueous electrolyte. Moreover, the in situ X-ray diffraction, ex situ X-ray photoelectron spectroscopy, transmission electron microscopy, and scanning electron microscopy reveal reversible Zn2+ insertion/extraction process.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Lian Ren, Wei Zhu, Shuting Li, Lei Han, Huixi Li, Meng Wang, Linxia Li, Shutong Li, Xia Lu, Yize Wu, Jiali Yuan, Qiang Yu, Zhen Chen
Summary: This study successfully reduces sulfation in the positive plate of lead-carbon batteries (LCBs) by adding a lead dioxide nanoparticle-doped graphene oxide composite material. The addition improves the battery capacity and cycle life, making it a reference for enhancing LCB performance through electrode structure modification.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Multidisciplinary Sciences
Guoyu Qian, Yiwei Li, Haibiao Chen, Lin Xie, Tongchao Liu, Ni Yang, Yongli Song, Cong Lin, Junfang Cheng, Naotoshi Nakashima, Meng Zhang, Zikun Li, Wenguang Zhao, Xiangjie Yang, Hai Lin, Xia Lu, Luyi Yang, Hong Li, Khalil Amine, Liquan Chen, Feng Pan
Summary: This study investigates the aging mechanism and evolution process of solid electrolyte interphase (SEI) in silicon oxide (SiOx) negative electrodes. It reveals the non-homogeneous structure and conduction mechanism of SEI, and proposes a strategy to improve the capacity decay issue of SiOx by mechanically restricting the growth of SEI. This work provides insights for future improvement of SiOx negative electrodes.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Shuwei Sun, Xiaoning Li, Liqin Yan, Weixin Chen, Xia Lu, Ying Bai
Summary: This study is the first to design and construct a magnetic Fe3O4 interfacial layer on the Na2/3Ni1/3Mn2/3O2 surface, which functions as a surface ion accelerator and effectively improves the interfacial kinetic behavior. Electrochemical tests have demonstrated high capacity and capacity retention of the decorated cathode.
ACS ENERGY LETTERS
(2023)