4.8 Article

Triboelectric nanogenerator-integrated structural supercapacitor with in situ MXene-dispersed N-doped Zn-Cu selenide nanostructured woven carbon fiber for energy harvesting and storage

Journal

ENERGY STORAGE MATERIALS
Volume 43, Issue -, Pages 402-410

Publisher

ELSEVIER
DOI: 10.1016/j.ensm.2021.09.027

Keywords

Triboelectric nanogenerator (TENG); Structural supercapacitor; Energy harvesting; Carbon fiber; Energy storage

Funding

  1. National Research Foundation of Korea (NRF) - Ministry of Science and ICT of Korea [2018R1A2B3007806, 2017R1A5A1015311]
  2. UNIST (Ulsan National Institute of Science and Technology) [1.210038.01]
  3. National Research Foundation of Korea [2017R1A5A1015311, 2018R1A2B3007806] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The WCF-based multifunctional TENG can efficiently generate energy in harsh environments and store energy effectively in a connected supercapacitor, with high energy density and power density; Coating with N-doped materials can enhance the device's energy generation and storage capacity, and the multifunctional device has great potential applications in various sectors.
A woven carbon fiber (WCF)-based triboelectric nanogenerator (TENG)-cum-structural supercapacitor is an excellent multifunctional device for clean energy harvesting and storage. This type of device has high load-bearing capacity and functions smoothly under severe outdoor conditions. Herein, WCF-based multifunctional TENG is reported that generated 8.9 W m(-2) power with 84% energy conversion efficiency. The energy generated by the TENG was simultaneously stored in a connected supercapacitor that provide 1.93 Wh kg(-1) of energy density and delivers 39.23 W kg(-1) of power density. The specific surface area of the WCF was enhanced several hundred-fold by coating with an N-doped Zn-Cu selenide nanoporous material, thereby enabling higher energy generation and elevated storage capacity of the device. The TENG use a polyester-based solid polymer electrolyte as the negative electrode and polydimethylsiloxane-coated WCF as the positive electrode. The device has a very high coulombic efficiency with high mechanical strength and ability to resist massive impact. An application of the multifunctional device was demonstrated. These types of multifunctional devices have great potential in the self-charging automobile, aerospace, sensor, and electronics sectors.

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