4.5 Article

One-part alkali activated slag using Ca(OH)2 and Na2CO3 instead of NaOH as activator: more excellent compressive strength and microstructure

Journal

MATERIALS RESEARCH EXPRESS
Volume 8, Issue 8, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/2053-1591/ac16f4

Keywords

alkali activated slag; calcium hydroxide; sodium carbonate; compressive strength

Funding

  1. Fundamental Research Funds for the Central Universities [18CX02098A]
  2. Open Foundation of Sinopec Key Laboratory of Cementing and Completion [20-GWJ-KF-4]

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In this study, sodium carbonate and calcium hydroxide were used as composite activators to prepare one-part alkali-activated slag, and compared with slag activated by sodium hydroxide. It was found that the one-part alkali-activated slag had higher compressive strength, potentially attributed to the lower porosity caused by the generation of calcium carbonate during hydration.
In this paper, sodium carbonate and calcium hydroxide instead of sodium hydroxide used as composite activators, and slag are applied to prepare one-part alkali-activated slag. Furthermore, the properties of the slag activated by sodium hydroxide are compared. The compressive strength, XRD, TGA, MIP, and SEM analysis of the two systems are performed. The results show that the one-part alkali-activated slag prepared from sodium carbonate and calcium hydroxide has a superior compressive strength against the slag activated by sodium hydroxide. It is also found that the hydration speed of the sodium hydroxide activated slag is faster, and thus the higher compressive strength of the one-part alkali-activated slag is not caused by the hydration speed. The hydration of one-part alkali-activated slag produces a certain amount of calcium carbonate, resulting in a lower porosity in comparison with the slag activated by sodium hydroxide, which may be the reason for the better compressive strength of one-part alkali-activated slag.

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