4.8 Article

Enhancing output performance of triboelectric nanogenerator via large polarization difference effect

Journal

NANO ENERGY
Volume 84, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.nanoen.2021.105892

Keywords

Triboelectric nanogenerator; Performance enhancement; Large polarization difference effect; Flexibility; Inorganic antiferroelectric ceramic

Funding

  1. Science and Technology Innovation Guide Fund of Inner Mongolia Autonomous Region [KCBJ2018034]
  2. Major Program for Science and Technology of Inner Mongolia Autonomous Region [2019ZD12]
  3. Support Program for Grassland Talents Innovation Team of Inner Mongolia
  4. Plan Project for Science and Technology of Baotou [2019P3070]

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The use of antiferroelectric ceramics as inner-layer materials in TENGs shows a significant enhancement in output performance due to their nearly zero remnant polarization and large polarization difference, which improves charge flow and output performance.
The utilization of inorganic ferroelectric ceramics is thought to be an effective approach to enhance output performances of triboelectric nanogenerators (TENGs). However, the large remnant polarization from ferroelectric ceramics traps partial charges on electrodes all the time, which limits the performance improvement of TENGs and their applications in energy harvesting and self-powered sensing. Herein, achieving absolute exploitation of dielectric polarization from inorganic ceramics for significant performance enhancement is unprecedentedly proposed by using antiferroelectric ceramics with large polarization difference. The features of nearly zero remnant polarization and large maximum polarization for antiferroelectric ceramics perfectly match the working cycle mechanism of TENGs, enabling all polarization induced charges to flow through the external circuit. Based on this concept, an ideal flexible Pb0.94La0.04Zr0.98Ti0.02O3 (PLZT) antiferroelectric ceramic innerlayer with record-high polarization difference is developed and assembled into a triboelectric nanogenerator (PLZT-TENG). The PLZT-TENG exhibits an outstanding output of 13.5 nC cm-2, a 1.6-fold enhancement compared with the TENG with a PbZr0.52Ti0.48O3 (PZT) ferroelectric ceramic inner-layer. Thanks to excellent flexibility, stability, and durability, the PLZT-TENG can serve as a biomechanical energy harvester and a selfpowered sensor to be applied in practice. Our findings open a generic and upgradable way to the evolution and optimization of TENGs.

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