Defect Engineering in a Eu2+-Doped β-Al2O3 Structure Blue Phosphor and Its Controllable Zero-Thermal Quenching Luminescence

A series of K1-2x-2yBayAl11O17(KBAO):xEu(2+) phosphors are designed to develop a blue phosphor with excellent thermal properties. All of the samples present similar beta-Al2O3 structures with P63/mmc space group; the K+ vacancy can exist stably until the Ba2+ concentration exceeds around y = 0.3. KBAO:Eu2+ exhibits strong absorption for near-ultraviolet light and relatively standard blue emission. The mechanisms for excitation and emission spectrum variations have also been studied in detail. Based on the adjustment of K+ vacancy numbers in the defect structure, K0.6Ba0.1Eu0.1Al11O17 exhibits a remarkable quantum yield of around 91.2% and a terrific high-temperature characteristic. The zero-thermal quenching performance mainly results from stabilization of the flowing electron number between Eu2+ 5d levels and K+ defect epsilon(0/-1) and epsilon(+1/0) levels in the processes of thermal ionization and recombination. A bright fabricated white-light-emitting diode (WLED) gives a color rendering index (CRI) of R-a = 87 and a correlated color temperature (CCT) of 4510 K, demonstrating that KBAO:Eu2+ has application potential to provide a blue light component in WLED. In addition, our research is a significant attempt to achieving stable zero-thermal quenching by subjective structure design, which provides a reference value for investigating the excellent new phosphors.

Automated summary

A series of KBAO:Eu2+ phosphors with excellent thermal properties have been designed, achieving stable zero-thermal quenching performance through structure adjustment, providing reference value for investigating excellent new phosphors.