4.1 Article

Self-Propagating High-Temperature Synthesis of Ceramic Material Based on Aluminum-Magnesium Spinel and Titanium Diboride

Journal

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 66, Issue 8, Pages 1115-1120

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023621080039

Keywords

oxide ceramics; refractory materials; combustion; nanostructure; self-propagating high-temperature synthesis

Funding

  1. Russian Science Foundation [20-73-00235]
  2. Russian Science Foundation [20-73-00235] Funding Source: Russian Science Foundation

Ask authors/readers for more resources

The aim of this project is to synthesize ceramic composite materials based on aluminum-magnesium spinel strengthened by titanium diboride particles using the self-propagating high-temperature synthesis (SHS) method, and study their combustion characteristics, microstructure, and phase composition. It is found that changing the ratio of magnesium and aluminum in the composition results in changes in the phase composition of the synthesized products, and with an increase in combustion temperature, the morphology of the powder particles obtained with composite structures changes.
The aim of this work is to synthesize ceramic composite materials based on aluminum-magnesium spinel strengthened by titanium diboride particles by the self-propagating high-temperature synthesis (SHS) and study the combustion characteristics of synthesized materials, their microstructure, and phase composition. For the synthesis of materials, powders of boron oxide, aluminum, magnesium, and titanium have been used. It is shown that changing the ratio of magnesium and aluminum in the composition of the initial charge results in changes in the phase composition of the synthesis products. As a result of the synthesis, composite materials based on aluminum-magnesium spinel with different contents of aluminum cations have been obtained: MgAl3O4, MgAl2O4, MgAlO4, and Mg1.5Ti1.5O4. It is shown that with an increase in the combustion temperature of the studied compositions, the morphology of the particles of the powders obtained with composite structures changes. It is shown that after SHS, crystallites of aluminum-magnesium spinel with a size of about 50 nm are formed.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.1
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Ceramics

Structure and mechanical characteristics of a layered composite material based on TiB/TiAl/Ti

Arina Bazhina, Alexander Konstantinov, Andrey Chizhikov, Pavel Bazhin, Alexander Stolin, Varvara Avdeeva

Summary: In this study, a layered composite material consisting of TiB/TiAl/alpha-Ti was successfully synthesized through unrestricted SHS compression. It was observed that combustion and subsequent high-temperature shear deformation led to the orientation of ceramic (TiB/Ti) and intermetallic (TiAl, Ti3Al) layers along the material flow direction and perpendicular to the applied load. The synthesis of the material followed a solid/liquid-phase mechanism. Mechanical properties such as hardness, microhardness, and fracture toughness were studied, and the mechanism of crack propagation and the relationship between stress intensity factor values and microvolume orientation were determined.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Multidisciplinary

In-situ study of the process of self-propagating high-temperature synthesis of titanium carbide with a nichrome binder

Pavel Bazhin, Mikhail Antipov, Alexander Konstantinov, Natalia Khomenko

Summary: Experimental results show that during the self-propagating high-temperature synthesis of titanium carbide with a nichrome binder, the metal binder undergoes melting and subsequent crystallization, leading to a change in its stoichiometry.

MATERIALS LETTERS (2022)

Article Materials Science, Coatings & Films

Features of the carbo-vibroarc surfacing in the development of multicomponent cermet wear-resistant coatings

P. M. Bazhin, N. Titov, A. O. Zhidovich, V. V. Avdeeva, A. Kolomeichenko, A. M. Stolin

Summary: This paper presents a simple and economical method of carbovibro-arc surfacing of metal surfaces. The method has been used to apply protective cermet coatings on steel substrates, which showed significantly lower coefficient of friction and higher wear resistance compared to uncoated samples. Field tests have demonstrated that the developed cermet coating technology can significantly increase the service life of commercial parts and improve the performance of agricultural machinery.

SURFACE & COATINGS TECHNOLOGY (2022)

Article Chemistry, Multidisciplinary

Mechanical Activation of Smectite-Based Nanocomposites for Creation of Smart Fertilizers

Maxim Rudmin, Santanu Banerjee, Boris Makarov, Kanipa Ibraeva, Alexander Konstantinov

Summary: This research presents the mechanical creation of smart fertilizers using the planetary milling technique. The study shows intercalation between urea and mineral in the created fertilizers, resulting in slower release rates of nitrogen compared to traditional urea fertilizers. Different forms of nitrogen within the fertilizers affect the quality and quantity of oat yield.

APPLIED SCIENCES-BASEL (2022)

Article Thermodynamics

MECHANISMS OF MOLDING, PHASE FORMATION, AND STRUCTURING OF MATERIALS BASED IN TITANIUM BORIDES UNDER THE CONDITIONS OF COMBUSTION PROCESSES AND HIGH-TEMPERATURE SHEAR DEFORMATION

P. M. Bazhin, A. S. Konstantinov, A. P. Chizhikov, A. D. Prokopets, M. S. Antipov, A. M. Stolin

Summary: By using x-ray diffraction with a high time resolution, the authors investigated the phase formation and structuring of titanium borides in the process of SHS with subsequent molding. The formation of an intermediate plastic matrix was found to play a key role in the molding process, serving as both a plasticizer and a reactant for strengthening phase formation.

JOURNAL OF ENGINEERING PHYSICS AND THERMOPHYSICS (2022)

Article Materials Science, Multidisciplinary

Influence of technological parameters on the process of SHS-extrusion of composite material MgAl2O4-TiB2

A. P. Chizhikov, A. S. Konstantinov, P. M. Bazhin, M. S. Antipov

Summary: Ceramic rods based on MgAl2O4-TiB2 material were obtained by SHS-extrusion. The deformation rate was found to have the greatest influence on the process, and changing this parameter allowed for the production of both compact and hollow rods.

LETTERS ON MATERIALS (2022)

Article Nanoscience & Nanotechnology

Structure, phase composition and mechanical characteristics of layered composite materials based on TiB/xTi-Al/α-Ti (x=1, 1.5, 3) obtained by combustion and high-temperature shear deformation

Arina Bazhina, Andrei Chizhikov, Alexander Konstantinov, Natalia Khomenko, Pavel Bazhin, Varvara Avdeeva, Olga Chernogorova, Ekaterina Drozdova

Summary: The study systematically investigates the effect of the titanium and aluminum ratio in the Ti-Al intermetallic layer on the microstructure, phase composition, and mechanical characteristics of layered composite materials based on TiB/xTi-Al/alpha-Ti. The results show that the mechanical characteristics of the obtained composites depend on the location of macrolayers relative to the applied load during high-temperature shear deformation, and have excellent properties compared to known analogs.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2022)

Article Chemistry, Inorganic & Nuclear

Formability, Phase Composition, and Microstructure of TiC-(5-50 wt %) NiCr-Based Materials Obtained by Free SHS Compression

M. S. Antipov, P. M. Bazhin, A. P. Chizhikov, A. S. Konstantinov, A. M. Stolin, N. Yu Khomenko

Summary: The effect of the delay time before applying pressure on the formability and properties of TiC-NiCr-based material was studied in this research. It was found that the combustion temperature of the initial sample increased and then sharply decreased with the increase of relative density. The mechanism of material formation and the synthesis route of the initial reagents were identified.

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY (2022)

Article Chemistry, Inorganic & Nuclear

Influence of Conditions of Self-Propagating High-Temperature Synthesis on Phase Composition and Structure of Materials Based on Ti-B

P. M. Bazhin, A. S. Konstantinov, A. P. Chizhikov, M. S. Antipov, E. V. Kostitsyna, A. M. Stolin

Summary: The effects of shear deformation and medium on the phase composition and structure of Ti-B based materials were studied. The results showed that shear deformation promotes a more complete phase formation process and a uniform distribution of titanium monoboride in the matrix.

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY (2022)

Article Nanoscience & Nanotechnology

Titanium-titanium boride matrix composites prepared in-situ under conditions combining combustion processes and high-temperature shear deformation

Pavel Bazhin, Andrei Chizhikov, Arina Bazhina, Alexander Konstantinov, Varvara Avdeeva

Summary: In this study, regularities for the effects of combustion processes and high-temperature shear deformation on the properties of compact composite materials based on TiB-(20-40 wt %) Ti have been determined. The resulting composites exhibit a TiB whisker texture depending on the deformation direction of the synthesized material. The size of TiB whiskers decreases up to 10 times with an increase in the proportion of free titanium in the composite material and a decrease in the delay time before pressure is applied. The improved mechanical characteristics of the obtained composites are explained based on a proposed crack propagation mechanism during three-point bending.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2023)

Article Materials Science, Multidisciplinary

Relationship between Structure and Properties of Intermetallic Materials Based on γ-TiAl Hardened In Situ with Ti3Al

Varvara Avdeeva, Arina Bazhina, Mikhail Antipov, Alexander Stolin, Pavel Bazhin

Summary: In this study, intermetallic materials based on & gamma;-TiAl in situ strengthened with the Ti3Al phase were obtained through a one-step process of combustion synthesis (SHS) and high-temperature shear deformation. The actual combustion temperature of the chosen compositions increased from the initial range to a higher range. X-ray powder diffraction and SEM results were used to measure the mechanical and tribological characteristics of the obtained materials, and 3D images of wear grooves were provided. It was found that a decrease in Ti molar fraction and an increase in Al molar fraction led to improved mechanical and tribological properties of the intermetallic materials.

METALS (2023)

Article Materials Science, Multidisciplinary

Influence of Layer-Thickness Proportions and Their Strength and Elastic Properties on Stress Redistribution during Three-Point Bending of TiB/Ti-Based Two-Layer Ceramics Composites

Kirill Khvostunkov, Pavel Bazhin, Qing-Qing Ni, Arina Bazhina, Andrey Chizhikov, Alexander Konstantinov

Summary: A mathematical model was developed to determine the order of failure and conditions for achieving maximum limit load in a two-layer ceramics composite under three-point loading. Experimental results confirmed the adequacy of the model. The experimental samples consisted of a cermet layer TiB/Ti and a layer of a-Ti.

METALS (2023)

Article Materials Science, Multidisciplinary

Compactability Regularities Observed during Cold Uniaxial Pressing of Layered Powder Green Samples Based on Ti-Al-Nb-Mo-B and Ti-B

Pavel Bazhin, Alexander Konstantinov, Andrey Chizhikov, Mikhail Antipov, Pavel Stolin, Varvara Avdeeva, Anna Antonenkova

Summary: In this study, the compactability regularities of layered powder green samples during cold uniaxial pressing were determined, considering factors such as composition, height, and number of layers. It was found that reducing the TNM content in the charge billet composition improves the compaction of powder materials, while increasing the boron content and decreasing the amount of titanium in the Ti-B composition enhances the compactability. A relationship between the compaction pressure interval and the density of the layered powder green sample was also established.

METALS (2023)

Article Materials Science, Multidisciplinary

Coatings Prepared by Electro-Spark Alloying with SHS Electrode Materials Based on Ti-B-Fe-AlN

Anastasia Bolotskaia, Varvara Avdeeva, Pavel Bazhin, Maksim Mikheev, Alexander Stolin, Vseslav Novikov, Marina Kovaleva, Viacheslav Sirota

Summary: The phase composition, structures, and properties of coatings on a high-speed steel substrate (steel R6M5) were studied using the ESA method. Electrode materials prepared through self-propagating high-temperature synthesis (SHS) with the addition of nanosized AlN particles were used. The coatings inherited the structure of the SHS electrode material and demonstrated improved surface hardness and wear resistance compared to the uncoated substrate.

COATINGS (2023)

No Data Available