4.8 Article

Three-Component Carbosilylation of Alkenes by Merging Iron and Visible-Light Photocatalysis

Journal

ORGANIC LETTERS
Volume 23, Issue 16, Pages 6510-6514

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c02322

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Funding

  1. SERB-DST [CRG/2020/000362]
  2. CSIR

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A mild, efficient, and one-pot protocol for three-component carbosilylation of alkenes with imidazoheterocycle and silanes has been developed by merging iron(II) and visible-light photocatalysis. This C-C and C-Si bond-forming method provides functionalized organosilicon derivatives having imidazoheterocycles moieties in good yields. The reaction possibly proceeds through a radical pathway.
A mild, efficient, and one-pot protocol for three-component carbosilylation of alkenes with imidazoheterocycle and silanes has been developed by merging iron(II) and visible-light photocatalysis. This C-C and C-Si bond-forming method provides functionalized organosilicon derivatives having imidazoheterocycles moieties in good yields. The reaction possibly proceeds through a radical pathway.

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