4.6 Article

Performance Evaluation of Enzyme Breaker for Fracturing Applications under Simulated Reservoir Conditions

Journal

MOLECULES
Volume 26, Issue 11, Pages -

Publisher

MDPI
DOI: 10.3390/molecules26113133

Keywords

hydraulic fracturing; gel breaking; enzyme breaker; mannanase

Funding

  1. management of the State Key Laboratory of Bio-based material & Green Papermaking

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This study demonstrated that mannanase II is an effective enzyme breaker for fracturing operations in alkaline and medium-temperature reservoirs. Mannanase II showed excellent gel-breaking performance, while requiring only one fifth of the concentration needed for other enzyme breakers. Additionally, it had minimal adverse effects on the fracturing fluid's performance and generated significantly lower residue compared to other breaker additives.
Fracturing fluids are being increasingly used for viscosity development and proppant transport during hydraulic fracturing operations. Furthermore, the breaker is an important additive in fracturing fluid to extensively degrade the polymer mass after fracturing operations, thereby maximizing fracture conductivity and minimizing residual damaging materials. In this study, the efficacy of different enzyme breakers was examined in alkaline and medium-temperature reservoirs. The parameters considered were the effect of the breaker on shear resistance performance and sand-suspending performance of the fracturing fluid, its damage to the reservoir after gel breaking, and its gel-breaking efficiency. The experimental results verified that mannanase II is an enzyme breaker with excellent gel-breaking performance at medium temperatures and alkaline conditions. In addition, mannanase II did not adversely affect the shear resistance performance and sand-suspending performance of the fracturing fluid during hydraulic fracturing. For the same gel-breaking result, the concentration of mannanase II used was only one fifth of other enzyme breakers (e.g., mannanase I, galactosidase, and amylase). Moreover, the amount of residue and the particle size of the residues generated were also significantly lower than those of the ammonium persulfate breaker. Finally, we also examined the viscosity-reducing capability of mannanase II under a wide range of temperatures (104-158 degrees F) and pH values (7-8.5) to recommend its best-use concentrations under different fracturing conditions. The mannanase has potential for applications in low-permeability oilfield development and to maximize long-term productivity from unconventional oilwells.

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