Article
Polymer Science
Liyuan Qiao, Chengde Liu, Cheng Liu, Lishuai Zong, Hongjian Gu, Chenghao Wang, Xigao Jian
Summary: By utilizing Schiff-base reaction and hydrogen bonding interaction, a self-healing, pH-sensitive, and shape memory hydrogel of PDAAc-A was successfully developed, showing significant improvements in mechanical properties and functionalities.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Engineering, Environmental
Hailong Yang, Hantian Lu, Yueyue Miao, Yang Cong, Yubin Ke, Jun Wang, Hua Yang, Jun Fu
Summary: Non-swelling super-tough polymer hydrogels with high strength and toughness have been developed using non-covalent crosslinkers. These hydrogels are self-healable and responsive to environmental stimuli in a controllable manner, making them suitable for various applications.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Nanoscience & Nanotechnology
Shanshan Wu, Jing Guo, Yilei Wang, Hui Xie, Shaobing Zhou
Summary: A new type of cryopolymerized polyampholyte gel with the multifunctionality of antidehydration, self-healing, and shape-memory has been developed for wearable sensing electronics, enabling automatic repair of physical damages and manual adjustment of performance.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Polymer Science
Wenqiang Yan, Yun Ding, Run Zhang, Xinjie Luo, Pinghou Sheng, Ping Xue, Jimin He
Summary: Tunable thermo-responsive shape memory and self-healing bifunctional blends are fabricated by melt blending of poly(ethylene-co-methacrylic acid sodium salt) (EMNa) and poly(ethylene-comethyl acrylate) (EMA) copolymers. The blends exhibit rapid shape recovery, repeatable self-healing capability, and superior mechanical strength, making them promising in various cutting-edge applications.
Article
Chemistry, Applied
Xiaoqin Shang, Qingling Wang, Jinghao Li, Guojie Zhang, Jianguo Zhang, Peng Liu, Liming Wang
Summary: Hybrid double network hydrogels containing starch networks exhibit improved mechanical strength and self-healing efficiency, with the gelatinization of starch being a key process; the composite gel can achieve a self-healing efficiency of up to 99% at room temperature; enhancing dynamic physical bonding in hydrogels through a simple starch reinforcing tactic is demonstrated.
CARBOHYDRATE POLYMERS
(2021)
Article
Polymer Science
Han Shi, Chuanzhi Hu, Aoqi Li, Xuewei Lin, Mingyu Deng, Bo Jiang, Bo Xiao
Summary: CMCS was prepared through carboxymethylation of chitosan, resulting in 58% substitution on -OH groups and 5% substitution on -NH2 groups. Hydrogels were obtained by mixing CMCS with 4r-PEG-CHO and ZnCl2, which improved the mechanical properties of the hydrogels due to the synergistic effect of imine bonds, metal coordination, and hydrogen bonding. The hydrogels exhibited good injectability, pH sensitivity, and rapid self-healing ability, making them potential candidates for biomedical applications.
JOURNAL OF POLYMER RESEARCH
(2023)
Article
Materials Science, Multidisciplinary
Shishan Xue, Guanfei Liu, Jingjuan Lai, Peng An, Yang Liu, Yuanpeng Wu, Yu Wang, Zhiyong Ye, Qiao Tang, Hongwei Zhou
Summary: The introduction of boron nitride nanosheets enhances the mechanical properties of PVA/borax hydrogels while maintaining self-healing abilities. The obtained hydrogels exhibit excellent mechanical properties and self-healing efficiency, along with rapid pH-driven shape memory effects.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2021)
Article
Polymer Science
Xiangrui Guo, Wenqiang Yan, Mingshuo Liu, Yun Ding, Jin Qu, Pinghou Sheng, Jingwan Hu, Zhicheng Zhang
Summary: This study successfully fabricated a composite material with controllable shape memory and repeatable self-healing properties by incorporating halloysite nanotubes into polyethylene-sodium methacrylate salt/poly epsilon-caprolactone blend. The introduction of nanotubes not only maintained good shape memory properties, but also greatly enhanced the self-healing effect.
EUROPEAN POLYMER JOURNAL
(2023)
Article
Materials Science, Multidisciplinary
Huihui Zheng, Hongwei Zhou, Zhao Wang, Shuman Zhang, Hongli Zhang
Summary: In this work, self-healing polyampholyte hydrogels are developed and explored in constructing wearable mechanosensors, including resistive strain sensors and capacitive pressure sensors. The resulting hydrogels exhibit outstanding self-healing ability, transparency, ionic conductivity, and stretchability. The resistive strain sensors show a gauge factor of 2.9 over a strain range of 0-350% and a low response time of 250 ms, while the capacitive pressure sensors achieve a gauge factor of 2.17 kPa(-1) and a sensing range of 0-7.35 kPa, with high cycling stability.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Polymer Science
Liying Wan, Peijie Li, Meiling Yan, Jianhong Wang, Xibao Li
Summary: A multifunctional conductive hydrogel has been developed via interpenetrating network (IPN) and multiple hydrogen bond interaction. The hydrogel exhibits excellent mechanical performance, self-healing capability, shape memory and conductive capability. It has potential applications in self-healing electronic devices, soft robots, and sensors.
EUROPEAN POLYMER JOURNAL
(2023)
Article
Multidisciplinary Sciences
Matteo Caprioli, Ignazio Roppolo, Annalisa Chiappone, Liraz Larush, Candido Fabrizio Pirri, Shlomo Magdassi
Summary: This study demonstrates a rapidly self-healing hydrogel processed by DLP printing, which can be used for 3D printing of complex structures and autonomously repair at room temperature.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Hangli Ling, Yong Shen, Lihui Xu, Hong Pan, Nan Shen, Kai Li, Kai Ni
Summary: The smart hydrogel based on L-cysteine polymer and hydroxyethyl cellulose shows promising shape memory and self-healing properties, as well as improved mechanical performance. Testing has revealed that the hydrogel has multi-response triple shape memory and excellent self-healing capabilities.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Materials Science, Multidisciplinary
Yao Huang, Panjun Wang, Weimin Tan, Wenkui Hao, Lingwei Ma, Jinke Wang, Tong Liu, Fan Zhang, Chenhao Ren, Wei Liu, Dawei Zhang
Summary: A novel self-healing coating with photothermal and pH dual-responsive properties has been developed to protect carbon steel from corrosion. The coating utilizes stimuli-responsive microcapsules loaded into a shape memory epoxy coating. Under near-infrared light irradiation, the coating exhibits a photothermal effect and releases corrosion inhibitors. Additionally, the pH-responsive gatekeeper controls the release of inhibitors under acidic conditions. The coating demonstrates efficient self-healing performance, as evaluated by surface morphology analysis and electrochemical techniques.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Applied
Guifa Xiao, Shiyu Fu, Lucian Amerigo Lucia
Summary: The Poly(aminobenzeneboronic acid)-cellulose nanocrystals (PABA@CNCs) mediated hydrogel demonstrates excellent mechanical strength, fast self-healing, and shape memory properties, making it a promising material for various applications.
CARBOHYDRATE POLYMERS
(2021)
Article
Polymer Science
Ying Qin, Hao Li, Hai-Xia Shen, Cai-Feng Wang, Su Chen
Summary: This paper presents a fast, energy-efficient, and convenient method of frontal polymerization (FP) for the rapid fabrication of new hydrogels with super water swelling capacity and self-healing ability. The resulting hydrogels, poly(AM-co-SBMA-co-AA), exhibit high transparency, stretchability, and sensitivity to pH. The properties of the hydrogels can be tuned by adjusting the monomer ratio, making them highly versatile in various applications.
Article
Polymer Science
Jiageng Pan, Liang Gao, Weixiang Sun, Shuting Wang, Xuetao Shi
Summary: This study investigates the effects of short alkyl side chain length on the phase-separated structure, mechanics, and dynamics of hydrogels. It was found that longer side chains lead to thicker polymer-rich domains and higher glass-transition temperatures, resulting in tougher and stronger hydrogels regardless of the side chain length when tested at specific temperatures or stretch rates.
Article
Nanoscience & Nanotechnology
Weixiang Sun, Ning Luo, Yubo Liu, Hao Li, Daoai Wang
Summary: With the demand for carbon neutrality increasing, researchers have turned their attention to the development of renewable and recycle green energy. In this study, a novel self-healing triboelectric nanogenerator was constructed using a linear silicone-modified polyurethane coating. This coating effectively alleviated the damages of the TENG devices during long-term energy harvesting. The self-healing TENG exhibited stable output performance and was used to power a self-powered cathodic protection system for anti-corrosion effect.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Engineering, Environmental
Sainan Zhang, Tongtong Yu, Ying Liu, Min Feng, Xiaojuan Li, Weixiang Sun, Daoai Wang
Summary: In this study, SiP quantum dots were introduced as a hole-migration cocatalyst with TiO2 nanorods, resulting in SiP QDs/TiO2 NRs/Al2O3 with enhanced photoelectrochemical properties. This composite showed significantly higher photocurrent density and IPCE value compared to pure TiO2 nanorods, indicating great potential for solar hydrogen generation.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Multidisciplinary
YuPeng Liu, WeiXiang Sun, TingHua Li, DaoAi Wang
Summary: An organic/inorganic hybrid coating with self-healable hydrophobicity was prepared using micro-arc oxidation (MAO) and fluorinated sol-gel (FSG) coating to create a triboelectrical layer. The resulting MAO/FSG hybrid coating-based TENG (MF-TENG) demonstrated significantly higher current and voltage outputs compared to traditional coatings, with good wear resistance and self-healing properties.
SCIENCE CHINA-TECHNOLOGICAL SCIENCES
(2022)
Article
Polymer Science
Chuhao Qiu, Weixiang Sun, Tao Wang, Zhen Tong
Summary: When a copolymer network of chemically crosslinked poly(n-butyl methacrylate-co-methacrylic acid) is immersed into a bath of N,N-dimethylformamide (DMF) and water, the network undergoes phase separation depending on the water fraction in the bath. The properties of the swollen network, such as swelling ratio, light transmittance, thermomechanics, dynamical mechanical spectra, and tensile property, were investigated for different water fractions. The results showed that the polymer-rich phase after phase separation became glassy when the water fraction in the bath was above 0.75. This led to a fundamental change in the thermomechanical behavior of the gel. A dynamical gel-to-glass transition was also observed, and its transition temperature decreased with increasing water fraction.
Article
Chemistry, Physical
Di Yang, Liqiang Zhang, Ning Luo, Ying Liu, Weixiang Sun, Jialiang Peng, Min Feng, Yange Feng, Haifeng Wang, Daoai Wang
Summary: The relationship between triboelectrification and tribological characteristics at the metal-semiconductor heterojunction interface was studied, and a new strategy for achieving a stable DC triboelectric output and wear resistance was proposed through controlling the tribological behavior.
Article
Chemistry, Physical
Jialiang Peng, Liqiang Zhang, Ying Liu, Chenguang Xu, Di Yang, Xiao Sun, Yange Feng, Min Feng, Weixiang Sun, Daoai Wang
Summary: This paper presents a high-efficiency drip nanogenerator based on the brachistochrone curve principle, which achieves high output efficiency and energy collection efficiency. The generator has potential applications in collecting water energies in nature.
Article
Materials Science, Multidisciplinary
Jialiang Peng, Liqiang Zhang, Weixiang Sun, Ying Liu, Di Yang, Min Feng, Yange Feng, Daoai Wang
Summary: The use of triboelectrification to collect dissipated energy in the environment is a new strategy for in-situ cathodic protection of metal materials. The design of a droplet TENG based on an arc-shaped surface structure greatly increases the output current density, making it a potential solution for corrosion protection of marine equipment.
APPLIED MATERIALS TODAY
(2022)
Article
Chemistry, Multidisciplinary
Yupeng Liu, Weixiang Sun, Min Feng, Tinghua Li, Daoai Wang
Summary: In this study, a new type of triboelectric nanogenerator (TENG) with corrosion resistance and self-healable electrical output properties is developed using a titanium dioxide nanotube coating. The TENG exhibits high current and voltage output, as well as good hydrophobicity. The hydrophobicity is achieved through the transfer of loaded perfluorosilane. Furthermore, the electric energy generated by the TENG can improve the corrosion resistance of the metal matrix.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Chemistry, Physical
Kai Zhang, Hao Li, Lei Xin, Pengchang Li, Weixiang Sun
Summary: This study investigates the phenomenon of small Wenzel droplets being engulfed by large Cassie droplets and verifies this hypothesis through experiments and simulations. The results show that engulfing small Wenzel droplets does not reduce the velocity of large Cassie droplets. The effects of the number and distribution of small Wenzel droplets on the motion state and velocity of large Cassie droplets are also examined.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Zhejian He, Haoqiang Hua, Zhantao Zou, Lin Shu, Tao Wang, Weixiang Sun, Xiangmin Xu, Zhen Tong
Summary: This study presents a simple method to prepare a reliable nanocomposite organohydrogel (NCO hydrogel) strain sensor and its corresponding flexible wearable device for long-term monitoring of outdoor human motion. The NCO hydrogel exhibits excellent notch insensitivity, universal adhesion, and environmental tolerance. A portable wearable device was designed by attaching the NCO hydrogel to the substrate and connecting it to a Bluetooth module, enabling the recording and real-time display of various human physical motions through an APP on a mobile phone. Deep learning using a two-level fully connected neural network achieved a classification accuracy of 87% for different motions.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Ning Luo, Di Yang, Min Feng, Yang Dong, Yange Feng, Weixiang Sun, Tongtong Yu, Feng Zhou, Weimin Liu, Daoai Wang
Summary: Given the security issues caused by electrostatic discharge, triboelectrification has attracted attention as a new energy-generation and -collection method. However, its development is hindered by high output impedance and low current density. This study introduces a vacuum environment to overcome these limitations and enhances the performance of energy harvesting.
CELL REPORTS PHYSICAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Weixiang Sun, Di Yang, Ning Luo, Hao Li, Daoai Wang
Summary: With the development of a new self-powered fabric composition detection system from F-TENGs modified by different functional groups, this research successfully integrated the power unit and group analysis system into one device, providing tremendous application potential for collecting human motion energy and detecting group types.
NEW JOURNAL OF CHEMISTRY
(2022)