Emergence of Highly Enantioselective Catalytic Activity in a Helical Polymer Mediated by Deracemization of Racemic Pendants
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Title
Emergence of Highly Enantioselective Catalytic Activity in a Helical Polymer Mediated by Deracemization of Racemic Pendants
Authors
Keywords
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Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 143, Issue 32, Pages 12725-12735
Publisher
American Chemical Society (ACS)
Online
2021-08-05
DOI
10.1021/jacs.1c05620
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Note: Only part of the references are listed.- Helical Self-Organizations and Emerging Functions in Architectures, Biological and Synthetic Macromolecules
- (2021) Virgil Percec et al. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
- A Facile and Versatile Synthesis of End-Functionalized Poly(phenylacetylene)s: A Multicomponent Catalytic System for Well-Controlled Living Polymerization of Phenylacetylenes
- (2020) Tsuyoshi Taniguchi et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Emergence of homochiral benzene-1,3,5-tricarboxamide helical assemblies and catalysts upon addition of an achiral monomer
- (2020) Yan Li et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Heteroaromatic N-Oxides in Asymmetric Catalysis: A Review
- (2020) Zuzanna Wrzeszcz et al. MOLECULES
- Enantioconvergent Cu-Catalyzed Intramolecular C–C Coupling at Boron-Bound C(sp3) Atoms of α-Aminoalkylboronates Using a C1-Symmetrical 2,2′-Bipyridyl Ligand Attached to a Helically Chiral Macromolecular Scaffold
- (2020) Yukako Yoshinaga et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Racemic Monomer‐Based One‐Handed Helical Polymer Recognizes Enantiomers through Auto‐Evolution of Its Helical Handedness Excess
- (2020) Tomoyuki Ikai et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Recyclable helical poly(phenylacetylene)‐supported catalyst for asymmetric aldol reaction in aqueous media
- (2019) Chunhong Zhang et al. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
- Inducing Enantioselectivity in a Dynamic Catalyst by Supramolecular Interlocking
- (2019) Oliver Trapp et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Unexpectedly Strong Chiral Amplification of Chiral/Achiral and Chiral/Chiral Copolymers of Biphenylylacetylenes and Further Enhancement/Inversion and Memory of the Macromolecular Helicity
- (2019) Ryoma Ishidate et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Role of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds
- (2019) Kenso Soai et al. Symmetry-Basel
- Preparation of Enantioenriched Chiral Organic Molecules by Dynamic Asymmetric Induction from a Outer Chiral Source
- (2019) Kazunobu Igawa et al. CHEMISTRY LETTERS
- Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold
- (2019) Yuuya Nagata et al. ACS Central Science
- Stereochemical enhancement of polymer properties
- (2019) Joshua C. Worch et al. Nature Reviews Chemistry
- Catalysts Supported by Homochiral Molecular Helices: A New Concept to Implement Asymmetric Amplification in Catalytic Science
- (2019) Yan Li et al. ChemCatChem
- Helicity Induction and Its Static Memory of Poly(biphenylylacetylene)s Bearing Pyridine N ‐Oxide Groups and Their Use as Asymmetric Organocatalysts
- (2019) Mitsuka Ando et al. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
- Solvent dependence of the stereoselectivity in bipyridine N,N′-dioxide catalyzed allylation of aromatic aldehydes: A computational perspective
- (2019) Cuihuan Geng et al. Molecular Catalysis
- Autocatalytic Models for the Origin of Biological Homochirality
- (2019) Donna G. Blackmond CHEMICAL REVIEWS
- Enantioseparation using helical polyacetylene derivatives
- (2019) Chunhong Zhang et al. TRAC-TRENDS IN ANALYTICAL CHEMISTRY
- Chiral Autocatalysis and Mirror Symmetry Breaking
- (2018) Andrew J. Gellman et al. CATALYSIS LETTERS
- Direct Detection of Hardly Detectable Hidden Chirality of Hydrocarbons and Deuterated Isotopomers by a Helical Polyacetylene through Chiral Amplification and Memory
- (2018) Katsuhiro Maeda et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Spontaneous Symmetry Breaking in the Formation of Supramolecular Polymers: Implications for the Origin of Biological Homochirality
- (2018) Suneesh C. Karunakaran et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Polymerization Amplified Stereoselectivity (PASS) of Asymmetric Michael Addition Reaction and Aldol Reaction Catalyzed by Helical Poly(phenyl isocyanide) Bearing Secondary Amine Pendants
- (2018) Ling Shen et al. MACROMOLECULES
- Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction
- (2017) Takeshi Yamamoto et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Significant Improvement on Enantioselectivity and Diastereoselectivity of Organocatalyzed Asymmetric Aldol Reaction Using Helical Polyisocyanides Bearing Proline Pendants
- (2017) Li Zhou et al. ACS Macro Letters
- Noncovalent Interactions in Organocatalysis and the Prospect of Computational Catalyst Design
- (2016) Steven E. Wheeler et al. ACCOUNTS OF CHEMICAL RESEARCH
- Supramolecular Helical Systems: Helical Assemblies of Small Molecules, Foldamers, and Polymers with Chiral Amplification and Their Functions
- (2016) Eiji Yashima et al. CHEMICAL REVIEWS
- Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis
- (2015) Yuan-Zhen Ke et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Supramolecular Assemblies from Poly(phenylacetylene)s
- (2015) Félix Freire et al. CHEMICAL REVIEWS
- Supramolecular Chirality in Self-Assembled Systems
- (2015) Minghua Liu et al. CHEMICAL REVIEWS
- Exerting Control over the Helical Chirality in the Main Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols
- (2015) Yuuya Nagata et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Adsorption-induced auto-amplification of enantiomeric excess on an achiral surface
- (2015) Yongju Yun et al. Nature Chemistry
- A rational strategy for the realization of chain-growth supramolecular polymerization
- (2015) J. Kang et al. SCIENCE
- Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main-Chain Helical Chirality
- (2014) Yuuya Nagata et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Switchable enantioseparation based on macromolecular memory of a helical polyacetylene in the solid state
- (2014) Kouhei Shimomura et al. Nature Chemistry
- Supramolecular Chirality: Solvent Chirality Transfer in Molecular Chemistry and Polymer Chemistry
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- Mechanistic Dichotomy in the Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes Catalyzed by Chiral PyridineN-Oxides
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- Conformationally Rigid Chiral Pyridine N-Oxides as Organocatalyst: Asymmetric Allylation of Aldehydes
- (2012) Elumalai Gnanamani et al. ADVANCED SYNTHESIS & CATALYSIS
- Chiral Biscarboline N,N′-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes
- (2012) Bing Bai et al. ADVANCED SYNTHESIS & CATALYSIS
- Consequences of Cooperativity in Racemizing Supramolecular Systems
- (2012) Seda Cantekin et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Stable Axial Chirality in Metal Complexes Bearing 4,4′-Substituted BIPHEPs: Application to Catalytic Asymmetric Carbon–Carbon Bond-Forming Reactions
- (2012) Kohsuke Aikawa et al. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
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- (2012) Hiroki Iida et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalytic asymmetric synthesis using chirality-switchable helical polymer as a chiral ligand
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- (2012) Zhenglin Tang et al. ACS Macro Letters
- Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines
- (2011) Miguel Yus et al. CHEMICAL REVIEWS
- Synthesis of polysaccharide derivatives bearing pyridine N-oxide groups and their use as asymmetric organocatalysts
- (2011) Tomoyuki Ikai et al. REACTIVE & FUNCTIONAL POLYMERS
- Oxygen Superbases as Polar Binding Pockets in Nonpolar Solvents
- (2010) Lucie Ducháčková et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes
- (2010) Takeshi Yamamoto et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Synthesis of axially chiral bipyridine N,N'-dioxides and enantioselective allylation of aldehydes
- (2010) Martin Kotora PURE AND APPLIED CHEMISTRY
- Simple and Fast Synthesis of New Axially Chiral BipyridineN,N′-Dioxides for Highly Enantioselective Allylation of Aldehydes
- (2009) Aneta Kadlčíková et al. ADVANCED SYNTHESIS & CATALYSIS
- Neutral and ionic reaction mechanisms for the allylation of aldehydes by bipyridine N,N′-dioxides
- (2009) Radim Hrdina et al. CHEMICAL COMMUNICATIONS
- Dendron-Mediated Self-Assembly, Disassembly, and Self-Organization of Complex Systems
- (2009) Brad M. Rosen et al. CHEMICAL REVIEWS
- Visualization of synthetic helical polymers by high-resolution atomic force microscopy
- (2009) Jiro Kumaki et al. CHEMICAL SOCIETY REVIEWS
- Chirality in Dynamic Supramolecular Nanotubes Induced by a Chiral Solvent
- (2009) Benjamin Isare et al. CHEMISTRY-A EUROPEAN JOURNAL
- Asymmetric reduction of aromatic ketimines in the presence of helical polymer as catalyst
- (2009) Kayo Terada et al. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
- Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis
- (2008) Takeshi Yamamoto et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Synthesis of functional poly(phenyl isocyanide)s with macromolecular helicity memory and their use as asymmetric organocatalysts
- (2008) Toshitaka Miyabe et al. CHIRALITY
- Self-assembly of supramolecular polymers into tunable helical structures
- (2008) Ho-Joong Kim et al. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
- Control of dynamic helicity at the macro- and supramolecular level
- (2008) Dirk Pijper et al. Soft Matter
- New pyridine N-oxides as chiral organocatalysts in the asymmetric allylation of aromatic aldehydes
- (2008) Andrei V. Malkov et al. TETRAHEDRON
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