4.7 Article

Constant Potential and Constant Current Electrolysis: An Introduction and Comparison of Different Techniques for Organic Electrosynthesis

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 22, Pages 15866-15874

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c01391

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Funding

  1. University of Missouri-Kansas City

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Electrosynthesis involves transferring charge between two electrodes to promote chemical reactions. Controlling the current and potential can affect the reaction mechanism and product distribution. This Synopsis applies theoretical discussion to specific case studies to illustrate methods of adjusting and tracking electrical parameters for the optimization and monitoring of electroorganic reactions.
Electrosynthesis involves transferring charge between two electrodes to promote chemical reactions by applying potential. The modes of controlling the current and potential can affect the reaction mechanism, product distribution and yields, and add a control factor for reaction optimization. In this Synopsis, theoretical discussion is applied to specific case studies from the literature to illustrate methods of adjusting and tracking electrical parameters for the optimization and monitoring of electroorganic reactions.

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