4.5 Article

High-temperature modification and air-quenching granulation of steel slag

Journal

JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL
Volume 29, Issue 5, Pages 783-792

Publisher

SPRINGER
DOI: 10.1007/s42243-021-00641-y

Keywords

Steel slag; Modification; Air-quenching granulation; Free CaO; Amorphous; Property

Funding

  1. Key Research and Development Program of Hebei Province [19273806D]
  2. Project of Hebei Provincial Department of Education [JQN2020042]

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Modifying and air-quenching granulation processes can improve the properties of steel slag and create a value-added product, air-quenching granulated steel slag, with enhanced fluidity and stability.
To solve the problem of difficult utilization of steel slag, the liquid steel slag was modified and the air-quenching granulation process was carried out to make steel slag into a value-added end product: air-quenching granulated steel slag. The granulated slag was tested to analyze the variation rule of slag properties under different modification conditions. Based on the phase diagram of CaO-Si2O-FeO-MgO-Al2O3 slag system, the feasibility of blast furnace (BF) slag as modifier was determined. When the addition of BF slag was increased from 0% to 35%, following results were obtained. The slag fluidity was improved, and the air-quenching temperature range was expanded. Then, the yield of air-quenched steel slag increased, while the granulation rate, the degree of sphericity, the compactness were decreased. Furthermore, the air-quenching granulation process could substantially improve the stability and the amorphous content of steel slag. The maximum removal rate of free CaO was above 80% and the amorphous content was up to 95%. Taking the factors of yield and properties of granulated steel slag into full consideration, the optimum proportion of BF slag is around 15%.

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