Article
Chemistry, Inorganic & Nuclear
Priyanka Devi, Kiran Singh, Bhupender Kumar, Jahnavi Kumari Singh
Summary: Many pyrazoles-based Schiff bases were reported to exhibit high activity against bacterial, parasitic strains, and cancer cells. A new pyrazole based 'NO' bidentate ligand was synthesized and metal complexes with Co+2, Ni+2, Cu+2, and Zn+2 were also prepared. The characterization of the compounds and their metal complexes was performed, and the metal complexes showed enhanced activity compared to the ligand. They exhibited significant anticancer and antibacterial activity, as well as antifungal activity.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Susheela Kumari, Aishwarya Ramesh, Bidisa Das, Saumi Ray
Summary: Planar cobalt(ii) Schiff-base complexes exhibit modified structural and functional properties when encapsulated in zeolite-Y. Encapsulation alters the electron density around the metal center and enhances reactivity for reactions like dye degradation and CO2 transformation. Comparative studies of structural and catalytic modifications provide a rational explanation for the improved reactivity of zeolite encapsulated metal complexes.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Applied
Laila H. Abdel-Rahman, Maram T. Basha, Badriah Saad Al-Farhan, Mohamed R. Shehata, Ehab M. Abdalla
Summary: In this study, five novel metal ion complexes were synthesized and characterized, showing anticancer potential with antiproliferative effects on cancer cell lines, as well as antioxidant and antibacterial activities. The binding nature of the complexes with CT-DNA was investigated to determine intercalation or replacement mode.
APPLIED ORGANOMETALLIC CHEMISTRY
(2022)
Article
Chemistry, Applied
Alireza Oveisi Keikha, Somaye Shahraki, Hassan Mansouri-Torshizi, Effat Dehghanian, Mostafa Heidari Majd
Summary: Two new gold(III) complexes, [AuL1]Cl-3, A, and [AuL2]Cl-3, B, were synthesized and characterized. DFT calculations showed square planar geometry for both complexes. Antioxidant results showed that the ability of compounds to inhibit DPPH center dot is as follows: A > B > L-2 > L-1. The anticancer assay showed that both complexes have the ability to inhibit the growth of HCT116 colon cancer cell lines, but B shows a relatively better effect than cisplatin. The interaction effects of A and B on the activity and structure of the bovine liver catalase (BLC) were investigated by spectroscopic techniques and molecular docking. Both complexes were able to change the performance and structure of BLC; B has a greater effect on BLC activity, so at concentration of 2 mu M, A and B inhibit initial BLC activity by 92.2% and 55.6%, respectively. The interaction mechanism of A and B with BLC was also different; A interacted mostly with van der Waals interactions and hydrogen bonds, but the most important forces for B was hydrophobic interactions. According to docking results, both complexes prefer the domain III of BLC, but B has higher affinity toward BLC than A, which supports the results of spectroscopic and FMO analysis.
APPLIED ORGANOMETALLIC CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Zinat Rezazadeh, Faezeh Soleimani, Boshra Mahmoudi, Mohammad Ali Nasseri, Milad Kazemnejadi
Summary: In this study, NiO, CuO, and Co2O3 nanoparticles with significant antibacterial activity were efficiently synthesized by thermal decomposition of polysalicylaldehyde Schiff base-M(II) complexes. The nanoparticles exhibited high uniformity, homogeneous morphology, high purity, and crystallinity. Their antibacterial activity against Escherichia coli, Bacillus cereus, and Staphylococcus aureus was significantly better compared to the initial complexes.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2021)
Article
Polymer Science
Atif A. El-Gharably, El-Refaie S. Kenawy, Ahmed A. Safaan, Saad A. Aboamna, Yehia A. G. Mahmoud
Summary: Schiff bases and aminochitosan derivatives were synthesized and tested for their antimicrobial activity. Compound (3b) showed good inhibitory activity against Bacillus cereus, while (3f) exhibited pronounced inhibitory activity against Staphylococcus aureus. Aminochitosan derivatives demonstrated medium to high antibacterial activity against Pseudomonas aeruginosa and Proteus mirabilis. The modification of pyrazole/chitosan Schiff bases increased their biological activity as antimicrobial and anticancer agents.
Article
Chemistry, Multidisciplinary
Yogesh Deswal, Sonika Asija, Deepak Kumar, Deepak Kumar Jindal, Gourav Chandan, Vivek Panwar, Sonia Saroya, Naresh Kumar
Summary: In this research, four new heterocyclic Schiff base ligands were synthesized and their complexation ability with metal ions was confirmed, showing potential antimicrobial and anticancer activities.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Biochemistry & Molecular Biology
Merve Yildirim, Bunyamin Ozgeris, Arzu Gormez
Summary: In this study, a series of novel 8-lactam derivatives were synthesized and their antimicrobial and anticancer activities were investigated. Compound 19 showed the best antibacterial and anticancer activities among the tested compounds.
BIOORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Ruixi Xu, Yuting Wu, Zhe Liu, Jinfeng Liu, Xicheng Liu
Summary: This study designed and synthesized six coumarin-modified cyclometallic Ir-III salicylaldehyde Schiff base complexes, and investigated their cytotoxic activity against cancer cells as well as the underlying anticancer mechanism.
FRONTIERS IN CHEMISTRY
(2022)
Article
Chemistry, Applied
Mamta, Pinki, Ashu Chaudhary
Summary: Novel Schiff base macrocyclic Zn(II) complexes were synthesized and their structures were confirmed using various analytical techniques. The macrocyclic ligands acted as tetradentate ligands, forming coordination bonds with Zn(II) ions. The coordination complexes exhibited potential in antimicrobial, anti-inflammatory, and anticancer activities. The docking studies showed good correlation with the experimental results.
APPLIED ORGANOMETALLIC CHEMISTRY
(2023)
Article
Biochemistry & Molecular Biology
Hanan B. Howsaui, Amal S. Basaleh, Magda H. Abdellattif, Walid M. Hassan, Mostafa A. Hussien
Summary: Three novel 2-aminopyrazine Schiff bases and their uranyl complexes were synthesized and characterized, with studies on DNA binding and anticancer activities showing promising results. Molecular docking analysis provided insights into interactions with cancer proteins.
Article
Chemistry, Physical
Mehmet Esref Alkis, Unzile Kelestemur, Yusuf Alan, Nevin Turan, Kenan Buldurun
Summary: A new Schiff base ligand and its metal complexes were synthesized and evaluated for their anticancer activities on colon cancer cells. The Co(II) and Ru(II) complexes showed significant anticancer properties, especially in combination with electrochemotherapy (ECT).
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Physical
Yasmin M. Ahmed, Gehad G. Mohamed
Summary: A new tetradentate Schiff base ligand was synthesized and characterized, and its complexes were investigated for their antimicrobial activity. The results showed that the ligand could form complexes with metal ions, and the metal chelation enhanced the antimicrobial activity.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Mamta, Subhash, Pinki, Ashu Chaudhary
Summary: Novel synthesised Mn(II) complexes of Schiff base octaazamacrocyclic ligands showed good cytotoxicity against cancerous cell lines and antimicrobial activity against bacterial and fungal strains. The stability and properties of the ligands were determined through experimental and computational studies.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Polymer Science
Fatmah Ali Alasmary, El-Refaie Kenawy, Nehal M. El-Deeb, Elbadawy A. Kamoun, Samar A. Khattab, Abdulnasser Mahmoud Karami, Patrizia Cinelli, Mohamed M. Azaam
Summary: Due to the seriousness of bacterial infections, it is necessary to improve antimicrobial polymers to overcome the limitations of conventional antimicrobial agents. This study successfully modified a polymer to enhance its biological activities and found potential antimicrobial and anticancer effects.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2022)
Article
Chemistry, Analytical
Hossam S. Abdelbaset, Sayed A. Shama, R. M. Hegazey, Ehab A. Abdelrahman
Summary: In this study, nanosized samples of sodium aluminium silicate hydrate and geopolymer/zeolite A were obtained using hydrothermal and precipitation methods, and chitosan composites were fabricated. The properties of the samples and their composites were characterized, and they showed high adsorption capacity for heavy metal ions.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
(2023)
Article
Polymer Science
Asma S. Al-Wasidi, Maram T. Basha, Reem M. Alghanmi, Eida S. Al-Farraj, Ehab A. Abdelrahman
Summary: A novel nanostructure, synthesized using the sol-gel method, showed high adsorption capacity for methylene blue dye. The nanostructure was obtained by reacting an aqueous solution of sodium metasilicate pentahydrate with two different aqueous solutions of magnesium nitrate hexahydrate. The adsorption followed the pseudo-second-order kinetic model and the Langmuir equilibrium isotherm.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2023)
Article
Chemistry, Analytical
Asma S. Al-Wasidi, Maram T. Basha, Reem M. Alghanmi, Eida S. Al-Farraj, Ehab A. Abdelrahman
Summary: Cd(II) and Cu(II) ions, which are harmful to human health and cause diseases, can be effectively removed from water sources using synthesized and functionalized sodium magnesium silicate hydroxide/sodium magnesium silicate hydrate nanostructures. The functionalization with 2,3-dihydroxybenzaldehyde led to changes in the structure and composition of the nanostructures. The synthesized nanostructures and nanocomposite samples exhibited high uptake capacities for both cadmium and copper ions.
Article
Polymer Science
Nada S. S. Al-Kadhi, Fawaz A. A. Saad, Reem K. K. Shah, Gharieb S. S. El-Sayyad, Zahrah Alqahtani, Ehab A. A. Abdelrahman
Summary: The synthesized lithium borate/copper oxide nanocomposite exhibits excellent photocatalytic performance in the decomposition of methylene blue and indigo carmine dyes. The combination of lithium borate and copper oxide enhances charge transfer efficiency and product separation, leading to higher degradation efficiency.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2023)
Article
Polymer Science
Asma S. Al-Wasidi, Abdulrahman A. Almehizia, Hamad M. Alkahtani, Ahmad J. Obaidullah, Ahmed M. Naglah, Eida S. Al-Farraj, M. Khairy, Gharieb S. El-Sayyad, Ehab A. Abdelrahman
Summary: In this study, Fe0.5Mn0.5Co2O4/Fe2O3 nanocomposites were fabricated using the chemical pechini sol-gel method at different temperatures. The nanocomposites were characterized using various techniques, and their average crystallite size and morphology were determined. The synthesized nanocomposites showed efficient photocatalytic degradation of safranin dye in the presence of H2O2, decomposing it completely within 25 minutes.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2023)
Article
Polymer Science
Nada S. S. Al-Kadhi, Fawaz A. A. Saad, Reem K. K. Shah, Eida S. S. Al-Farraj, Gharieb S. S. El-Sayyad, Ehab A. A. Abdelrahman
Summary: In this paper, novel nanostructures of MC and MO were synthesized using precipitation and ignition methods, respectively, and used for the removal of Eriochrome Black T dye. The small crystallite size and large surface area of the nanostructures contribute to their high adsorption capacity. The maximum uptake capabilities of MC and MO for the dye were found to be 416.67 and 386.10 mg/g, respectively. The adsorption process followed the pseudo-first-order model and Langmuir isotherm. The synthesis of these nanostructures provides a simple and efficient method for the removal of Eriochrome Black T dye.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2023)
Article
Plant Sciences
Aneela Bashir, Qudrat Ullah Khan, Ahmad Alem, Awatif A. Hendi, Umber Zaman, Shahid Ullah Khan, Khalil ur Rehman, Asghar Ali Khan, Ihsan Ullah, Yasir Anwar, Ehab A. Abdelrahman
Summary: This study investigated the synergizing effect of zinc and potassium fertilizers on the uptake of essential nutrients, growth, yield, and quality of wheat crops. Results showed a positive response to the fertilizer treatments, with the local landrace exhibiting higher plant height and biological yield, while improved Hashim-08 showed increased agronomic parameters. Application of zinc and potassium fertilizers significantly enhanced agronomic parameters, with minimal changes in crude protein and grain potassium content. The dynamics of soil zinc and potassium content varied among treatments.
Article
Chemistry, Multidisciplinary
Asma S. Al-Wasidi, Hanadi A. Katouah, Fawaz A. Saad, Ehab A. Abdelrahman
Summary: In this study, silica nanoparticles were modified by 5-chloro-8-quinolinol to create a new nanocomposite for the efficient removal and preconcentration of Al3+ ions from water sources. Characterization techniques such as XRD, SEM, FT-IR, TEM, CHN elemental analyzer, and N2 adsorption/desorption analyzer were used to analyze the composite. The results showed successful loading of 5-chloro-8-quinolinol on the silica surface, with a specific surface area of 80.53 m2/g and a maximum adsorption capacity of 95.06 mg/g for aluminum ions.
Article
Chemistry, Physical
Ehab A. Abdelrahman, Wagdy El-Dougdoug, Yousra H. Kotp
Summary: Novel zeolite adsorbent nanostructures were fabricated using the hydrothermal approach, which efficiently removed lead and mercury ions from aqueous solutions with maximum removal capacities of 160.77 mg/g and 295.86 mg/g, respectively. The removal process was exothermic, chemical, spontaneous, and followed the Langmuir isotherm and pseudo-second-order model. The synthesized ED1 and ED2 samples can be utilized multiple times without compromising their efficacy.
Article
Chemistry, Inorganic & Nuclear
Ehab A. Abdelrahman, Faisal K. Algethami, Huda S. Alsalem, Mona S. Binkadem, Fawaz A. Saad, Gharieb S. El-Sayyad, Nadeem Raza, Khalil ur Rehman
Summary: A new nanostructure, sodium manganese silicate/sodium manganese silicate hydroxide hydrate, was successfully fabricated as an efficient adsorbent for the disposal of crystal violet dye from aqueous solutions. The nanostructures, abbreviated as MS1, MS2, MS3, and MS4, were formed through hydrothermal treatment of a gel produced from the interaction of Mn(II) ions with Si(IV) ions. The MS1, MS2, MS3, and MS4 adsorbents exhibited good adsorption capacity for crystal violet dye under optimized conditions, with maximum disposal capacities of 342.47, 362.32, 411.52, and 310.56 mg/g, respectively.
Article
Chemistry, Inorganic & Nuclear
Asma S. Al-Wasidi, Mohamed Khairy, Babiker Y. Abdulkhair, Ehab A. Abdelrahman
Summary: Amorphous and crystalline novel products based on Zr, Mg, and Mn were fabricated using the Pechini sol-gel procedure, which is a cost-effective method. These products showed high efficiency as adsorbents in removing basic fuchsin dye from aqueous solutions.
Article
Nanoscience & Nanotechnology
Asma S. Al-Wasidi, Ehab A. Abdelrahman
Summary: In this study, barium titanate nanoparticles were synthesized for the efficient removal of malachite green dye. The synthesized nanoparticles were characterized and showed unique characteristics, including small crystallite sizes, low rate of hole/electron recombination, high chemical stability, and ability for multiple regeneration and reuse without efficiency loss.
Article
Nanoscience & Nanotechnology
Faisal K. Algethami, Asma S. Al-Wasidi, Eida S. Al-Farraj, Hanadi A. Katouah, Ehab A. Abdelrahman
Summary: In this study, a novel Fe3O4/analcime nanocomposite was used for the disposal of cadmium and copper ions from aqueous solutions. The synthesized products were characterized using FE-SEM, FT-IR, and X-ray diffraction. The FE-SEM images showed that the analcime and Fe3O4 samples had polyhedral and quasi-spherical shapes with average diameters of 923.28 and 28.57 nm, respectively. The Fe3O4/analcime nanocomposite had polyhedral and quasi-spherical shapes with an average diameter of 1100.00 nm. The nanocomposite exhibited the highest uptake capability for copper and cadmium ions at 176.68 and 203.67 mg/g, respectively. The uptake of copper and cadmium ions using the nanocomposite followed the pseudo-second-order kinetic model and Langmuir equilibrium isotherm. The adsorption process was exothermic and chemical in nature.
Article
Chemistry, Analytical
Y. G. Abou El-Reash, Eslam A. Ghaith, Osama El-Awady, Faisal K. Algethami, Haiqing Lin, Ehab A. Abdelrahman, Fathi S. Awad
Summary: Heavy metal ion pollution is a global problem that requires monitoring in environmental water to ensure safety. A highly sensitive and selective mercury ion (Hg2+) fluorescence probe was developed using functionalized graphitic carbon nitride nanosheets. The probe showed excellent performance in terms of sensitivity, stability, selectivity, and minimal toxicity, making it suitable for environmental applications. Its application in detecting Hg2+ ions in fish samples demonstrated its potential for practical use.
JOURNAL OF ANALYTICAL SCIENCE AND TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Asma S. Al-Wasidi, Fawaz A. Saad, Alaa M. Munshi, Ehab A. Abdelrahman
Summary: This study synthesized novel nanostructures MgMn2O4/Mn2O3 and MgMn2O4/Mn2O3/Mg6MnO8 through the Pechini sol-gel method with mixed solutions of Mg(ii) and Mn(ii) ions, and characterized the structures. These nanostructures were used as adsorbents for the efficient removal of tartrazine dye from aqueous media.