4.7 Article

Improvement criteria for different advanced technologies towards bio-stabilized leachate based on molecular subcategories of DOM

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 414, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jhazmat.2021.125463

Keywords

Recalcitrantly biodegraded organics; PAC adsorption; Electrolysis; Fenton; Membrane technologies

Funding

  1. National Key Research and Development Program of China [2018YFD1100600]
  2. National Natural Science Foundation of China [22076145]

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This study investigates the individual removal targets of nine advanced treatment technologies for bio-stabilized landfill leachate, focusing on dissolved organic matter (DOM) molecules. The research identifies the preferable technologies and removal rates for various DOM molecular subcategories, recommending specific technology combinations based on target complementarity in compound intensity and abundance. The study suggests that tailored treatment strategies for unknown recalcitrantly biodegraded wastewater can be designed based on the subcategorized DOM characteristics of the refractory wastewater.
Considering dissolved organic matter (DOM) molecules, the present study is an attempt to unravel the individual removal targets of nine advanced treatment technologies for bio-stabilized landfill leachate. For the eight DOM molecular subcategories, preferable technologies and removal rates were as follows: lipids - powdered activated carbon (PAC) adsorption (97%) and Fenton (97%); proteins - extended electrolysis (92%) and Fenton (92%); and lignins/carboxylic rich alicyclic molecules (CRAM)-like organics - Fenton (90%) and extended electrolysis (75%). As to individual technologies, Fenton, PAC adsorption, extended electrolysis, and reverse osmosis (RO) had the highest removal rates based on the intensity and abundance of DOM. As to the improved technology combinations, Fenton with PAC adsorption and PAC adsorption with reverse osmosis were then recommended according to the target complementarity in compound intensity and abundance. The study suggested that the treatment strategy of an unknown recalcitrantly biodegraded wastewater could be designed in a tailored way based on the subcategorized DOM characteristics of the refractory wastewater.

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