4.7 Article

K-preintercalated MnO2 nanosheets as cathode for high-performance Zn-ion batteries

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 895, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2021.115529

Keywords

K0.19MnO2.0.56H(2)O; Preintercalation strategy; Energy storage mechanism; Zinc ion battery

Funding

  1. National Natural Science Founda-tion of China [21805247, 51802288]
  2. Henan provincial key science and technology research projects [192102310299]
  3. China Postdoctoral Science Foundation [2021 T140612]

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Preintercalation of K+ ions and structural reconstruction in MnO2 nanosheets improves electronic conductivity, diffusion kinetics, and structural stability, leading to the development of high-performance KMO electrode for aqueous zinc ion batteries.
Manganese oxides are regarded as promising cathode materials for aqueous zinc ion batteries (ZIBs) due to their low cost and high theoretical capacity. However, their practical application is seriously hindered because of the inferior electronic conductivity, sluggish diffusion kinetics and structural instability. Herein, we develop a new K-preintercalated MnO2 (K0.19MnO2 center dot 0.56H(2)O, KMO) nanosheet by a facile hydrothermal method. Preintercalation of K+ ions into the MnO2 crystal layers with structural reconstruction can activate more active sites, strengthen the crystal structural stability and facilitate the insertion/extraction of Zn2+ ions. The charge shielding effect of crystal water promotes the diffusion kinetics of Zn2+ ions. The obtained KMO electrode delivers high specific capacity (107 mAh g(-1)) and good cycling stability (similar to 87.5% capacity retention after 2000 cycles), revealing its potential application for aqueous ZIBs.

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