Oxygen-vacancy generation in MgFe2O4 by high temperature calcination and its improved photocatalytic activity for CO2 reduction

MgFe2O4 spinel with abundant oxygen vacancy was synthesized by a simple precipitation method, and tested in photocatalytic reduction of CO2 with water vapor as reductant. A series of characterization including XRD, XPS, EPR, PL spectrum, UV-vis DRS and TPD-CO2 were performed to investigate the influence of calcination temperature on morphology, optical and electronic properties of MgFe2O4 spinel. The results demonstrated that the oxygen vacancy concentration increases first and then decreases with the increase of calcination temperature. By introducing oxygen vacancies, the recombination of photogenerated electron-hole pairs was significantly suppressed, visible light absorption and chemisorption capacity of CO2 were dramatically boosted. Mg-Fe-750 with the richest oxygen vacancies exhibits the highest photocatalytic activity, for which the production rate of CO and H-2 was 24.4 and 34.3 mu mol/gcat/h, respectively. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

By introducing oxygen vacancies, the recombination of photogenerated electron-hole pairs in MgFe2O4 spinel was significantly suppressed, resulting in a dramatic enhancement of visible light absorption and chemisorption capacity of CO2. The sample Mg-Fe-750 with the richest oxygen vacancies exhibited the highest photocatalytic activity.