4.7 Article

Graphene quantum dots decorated on spinel nickel cobaltite nanocomposites for boosting supercapacitor electrode material performance

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 876, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.159990

Keywords

Graphene quantum dots; Hydrothermal method; Nickel-cobaltite/graphene quantum dots; Supercapacitor electrode; Potassium hydroxide

Funding

  1. Department of Science & Technology, New Delhi, India, under Women Scientists Scheme-A (WOS-A) [SR/WOS-A/PM-107/2017]

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In this study, NiCo2O4/GQDs composite structures were prepared with improved electrical conductivity to serve as electrode materials with higher energy density. The specific capacitance of the composite was found to be higher than that of Graphene Quantum Dots, attributed to enhanced electrical conductivity and faster ion diffusion. These findings demonstrate the suitability of the fabricated composites as superior electrode materials for supercapacitor applications.
Composites of transition metal oxides, with carbon, have been considered to be appropriate materials for enhancing their electrochemical properties in supercapacitor applications. In this study, we prepare Nickel-Cobaltite/Graphene Quantum Dots (NiCo2O4/GQDs) composite structures that exhibit improved electrical conductivity and function as electrode materials with higher energy density in comparison to GQDs and NiCo2O4. The electrochemical performance of NiCo2O4/GQDs is confirmed through galvanostatic charge-discharge method for three electrode systems with an electrolyte of 0.1 M potassium hydroxide. The ob-served specific capacitance for the fabricated composite has been found to be 481.4 Fg(-1) at 0.35Ag(-1). It is higher than that of Graphene Quantum Dots (C-sp similar to 45.6 Fg(-1)). This is due to the enhancement in the electrical conductivity and diffusion of ions which become faster between electrodes and electrolyte. These findings demonstrate the unique characteristics of the fabricated composites as superior electrode materials for applications in supercapacitors. (C) 2021 Elsevier B.V. All rights reserved.

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