4.7 Article

Evaluation of easy-removing antioxidant films of chitosan with Melaleuca alternifolia essential oil

Journal

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
Volume 186, Issue -, Pages 365-376

Publisher

ELSEVIER
DOI: 10.1016/j.ijbiomac.2021.07.035

Keywords

Film; Tea tree essential oil; Chitosan

Funding

  1. European Social Fund under the Operational Programme Knowledge Education Development [POWR.03.03.00-00-PN13/18]
  2. PROM International Scholarship Exchange for PhD Students and Academic Staff (NAWA, Poland)

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Chitosan-tea tree essential oil (TTEO) films were evaluated for their microstructure, thermal properties, mechanical properties, water vapor permeability, antioxidant activity, and optical properties. The films dissolved completely in water, with those made in malic acid showing higher elongation to break and antioxidant activity. TTEO addition slightly improved the UV-barrier properties of the films, indicating their great potential for food packaging applications.
Chitosan - tea tree essential oil (TTEO) films were obtained as a new biodegradable material. Malic acid or lactic acid solvents were evaluated to obtain easy-removing films. The microstructure by SEM and FT-IR, the thermal properties by TGA/DSC, the mechanical properties, the water vapor permeability, the antioxidant (DPPH center dot and ABTS center dot+) activity and the optical properties of the formulated films were evaluated. A complete dissolution of the film in water was obtained. The elongation to break was higher in the films with malic acid (145.88-317.33%), comparing with those with lactic acid (25.54-44.08%). Chitosan film obtained in malic acid with TTEO showed the highest antioxidant activity. The colour and transparency of the samples did not suffer significant variations by TTEO addition. Films showed good UV-barrier properties, with a slightly improvement by TTEO addition. The films obtained showed a great potential for food packaging applications.

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