Self-Assembled Heterometallic Complexes by Incorporation of Calcium or Strontium Ion into a Manganese(II) 12-Metallacrown-3 Framework Supported by a Tripodal Ligand with Pyridine-Carboxylate Motifs: Stability in Their Manganese(III) Oxidized Form

Current Understanding of the Mechanism of Water Oxidation in Photosystem II and Its Relation to XFEL Data

(2020) Nicholas Cox et al.   Annual Review of Biochemistry

Water-oxidizing complex in Photosystem II: Its structure and relation to manganese-oxide based catalysts

(2020) Mohammad Mahdi Najafpour et al.   COORDINATION CHEMISTRY REVIEWS

Seven Reversible Redox Processes in a Self-Assembled Cobalt Pentanuclear Bis(triple-stranded helicate): Structural, Spectroscopic, and Magnetic Characterizations in the CoICoII4, CoII5, and CoII3CoIII2 Redox States

(2020) Eric Gouré et al.   INORGANIC CHEMISTRY

Syntheses and Crystal Structures of a Series of Manganese-Lanthanide-Sodium 12-Metallacrown-4 Dimers

(2020) Collin M. Foley et al.   JOURNAL OF CHEMICAL CRYSTALLOGRAPHY

Artificial Mn4Ca-cluster with Exchangeable Solvent Molecules Mimicking the Oxygen-Evolving Center in Photosynthesis

(2019) Changhui Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

What has biomimicry so far brought on mysterious natural oxygen evolution?

(2019) Mojtaba Shamsipur et al.   COORDINATION CHEMISTRY REVIEWS

New insights in Mn–Ca chemistry from the use of oximate-based ligands: {Mn II/III 22 Ca 2 } and {Mn IV 2 Ca 2 } complexes with relevance to both low- and high-valent states of the oxygen-evolving complex

(2018) Alysha A. Alaimo et al.   POLYHEDRON

Structural models of the biological oxygen-evolving complex: achievements, insights, and challenges for biomimicry

(2017) Satadal Paul et al.   GREEN CHEMISTRY

What Can We Learn from a Biomimetic Model of Nature’s Oxygen-Evolving Complex?

(2017) Satadal Paul et al.   INORGANIC CHEMISTRY

Structural Diversities in Heterometallic Mn–Ca Cluster Chemistry from the Use of Salicylhydroxamic Acid: {MnIII4Ca2}, {MnII/III6Ca2}, {MnIII/IV8Ca}, and {MnIII8Ca2} Complexes with Relevance to Both High- and Low-Valent States of the Oxygen-Evolving Complex

(2017) Alysha A. Alaimo et al.   INORGANIC CHEMISTRY

Manganese-calcium/strontium heterometallic compounds and their relevance for the oxygen-evolving center of photosystem II

(2016) Bertrand Gerey et al.   COORDINATION CHEMISTRY REVIEWS

Molecular Designs for Controlling the Local Environments around Metal Ions

(2015) Sarah A. Cook et al.   ACCOUNTS OF CHEMICAL RESEARCH

Calcium and heterometallic manganese–calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations

(2015) Bertrand Gerey et al.   DALTON TRANSACTIONS

Artificial synthetic MnIVCa–oxido complexes mimic the oxygen-evolving complex in photosystem II

(2015) Changhui Chen et al.   DALTON TRANSACTIONS

Manganese–calcium clusters supported by calixarenes

(2015) Rebecca O. Fuller et al.   DALTON TRANSACTIONS

Magnetic Behavior of Heterometallic Wheels Having a [MnIV6M2O9]10+ Core with M = Ca2+ and Sr2+

(2015) Luis Escriche-Tur et al.   INORGANIC CHEMISTRY

A synthetic Mn4Ca-cluster mimicking the oxygen-evolving center of photosynthesis

(2015) C. Zhang et al.   SCIENCE

A synthetic model for the oxygen-evolving complex in Sr2+-containing photosystem II

(2014) Changhui Chen et al.   CHEMICAL COMMUNICATIONS

Preparation and properties of a calcium(ii)-based molecular chain decorated with manganese(ii) butterfly-like complexes

(2014) A. C. Benniston et al.   DALTON TRANSACTIONS

Controllable Formation of Heterotrimetallic Coordination Compounds: Systematically Incorporating Lanthanide and Alkali Metal Ions into the Manganese 12-Metallacrown-4 Framework

(2014) Michael R. Azar et al.   INORGANIC CHEMISTRY

Ca K-Edge XAS as a Probe of Calcium Centers in Complex Systems

(2014) Vlad Martin-Diaconescu et al.   INORGANIC CHEMISTRY

Emissive {Mn4IIICa} Clusters with Square Pyramidal Topologies: Syntheses and Structural, Spectroscopic, and Physicochemical Characterization

(2014) Alysha A. Alaimo et al.   INORGANIC CHEMISTRY

Toward Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination To Lower the Symmetry of the Mn3CaO4 Cubane: Demonstration That Electronic Effects Facilitate Binding of a Fifth Metal

(2014) Jacob S. Kanady et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How calcium affects oxygen formation

(2014) Davide Lionetti et al.   NATURE

Water oxidation energy diagrams for photosystem II for different protonation states, and the effect of removing calcium

(2014) Per E. M. Siegbahn   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Electronic structure of the oxygen-evolving complex in photosystem II prior to O-O bond formation

(2014) N. Cox et al.   SCIENCE

Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters

(2013) Emily Y. Tsui et al.   Nature Chemistry

Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals

(2013) E. Y. Tsui et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The Basic Properties of the Electronic Structure of the Oxygen-evolving Complex of Photosystem II Are Not Perturbed by Ca2+Removal

(2012) Thomas Lohmiller et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Synthetic model of the asymmetric [Mn3CaO4] cubane core of the oxygen-evolving complex of photosystem II

(2012) S. Mukherjee et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Heterobimetallic complexes with MIII-(μ-OH)-MIIcores (MIII= Fe, Mn, Ga; MII= Ca, Sr, and Ba): structural, kinetic, and redox properties

(2012) Young Jun Park et al.   Chemical Science

S1-State Model of the O2-Evolving Complex of Photosystem II

(2011) Sandra Luber et al.   BIOCHEMISTRY

Structural models of the manganese complex of photosystem II and mechanistic implications

(2011) Alexander Grundmeier et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Towards models of the oxygen-evolving complex (OEC) of photosystem II: a Mn4Ca cluster of relevance to low oxidation states of the OEC

(2011) Evangelia S. Koumousi et al.   CHEMICAL COMMUNICATIONS

Trigonal propeller-shaped [MnIII3MIINa] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII

(2011) Sanjit Nayak et al.   DALTON TRANSACTIONS

Multireversible Redox Processes in Pentanuclear Bis(Triple-Helical) Manganese Complexes Featuring an Oxo-Centered triangular {MnII2MnIII(μ3-O)}5+or {MnIIMnIII2(μ3-O)}6+Core Wrapped by Two {MnII2(bpp)3}−

(2011) Sophie Romain et al.   INORGANIC CHEMISTRY

Calcium in the oxygen-evolving complex: Structural and mechanistic role determined by X-ray spectroscopy

(2011) Vittal K. Yachandra et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY

Effect of Ca2+/Sr2+Substitution on the Electronic Structure of the Oxygen-Evolving Complex of Photosystem II: A Combined Multifrequency EPR,55Mn-ENDOR, and DFT Study of the S2State

(2011) Nicholas Cox et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Effects of Redox-Inactive Metal Ions on the Activation of Dioxygen: Isolation and Characterization of a Heterobimetallic Complex Containing a MnIII–(μ-OH)–CaIICore

(2011) Young Jun Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Model of the Mn3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II

(2011) J. S. Kanady et al.   SCIENCE

Synthesis and characterization of a new 2D trimetallic Mn/Ca/Na complex

(2010) Na Li et al.   INORGANIC CHEMISTRY COMMUNICATIONS

The first heterometallic Mn–Ca cluster containing exclusively Mn(III) centers

(2010) Vasiliki Kotzabasaki et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Electro- and Photoinduced Formation and Transformation of Oxido-Bridged Multinuclear Mn Complexes

(2009) Marie-Noëlle Collomb et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Definition of Magneto-Structural Correlations for the MnIIIon

(2008) Carole Duboc et al.   CHEMISTRY-A EUROPEAN JOURNAL

The calcium and chloride requirements of the O2 evolving complex

(2007) C YOCUM   COORDINATION CHEMISTRY REVIEWS