Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction

Impactful Role of Cocatalysts on Molecular Electrocatalytic Hydrogen Production

(2021) Charles G. Margarit et al.   ACS Catalysis

Induction of Enzyme-like Peroxidase Activity in an Iron Porphyrin Complex Using Second Sphere Interactions

(2019) Snehadri Bhakta et al.   INORGANIC CHEMISTRY

On the Basicity of Organic Bases in Different Media

(2019) Sofja Tshepelevitsh et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Electrocatalytic Hydrogen Evolution with a Cobalt Complex Bearing Pendant Proton Relays: Acid Strength and Applied Potential Govern Mechanism and Stability

(2019) Nicolas Queyriaux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rational Design of Mononuclear Iron-porphyrins for Facile and Selective 4e-/4H+ O2 Reduction: Activation of O-O Bond by 2nd Sphere Hydrogen Bonding

(2018) Sarmistha Bhunia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon Dioxide Reduction by Iron Hangman Porphyrins

(2018) Charles G. Margarit et al.   ORGANOMETALLICS

Positional effects of second-sphere amide pendants on electrochemical CO2 reduction catalyzed by iron porphyrins

(2018) Eva M. Nichols et al.   Chemical Science

Reversing the Tradeoff between Rate and Overpotential in Molecular Electrocatalysts for H2 Production

(2018) Christina M. Klug et al.   ACS Catalysis

Oxygen-Tolerant H2 Production by [FeFe]-H2ase Active Site Mimics Aided by Second Sphere Proton Shuttle

(2018) Md Estak Ahmed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Basicity of Conjugated Nitrogen Heterocycles in Different Media

(2017) Märt Lõkov et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Activating Fe(I) Porphyrins for the Hydrogen Evolution Reaction Using Second-Sphere Proton Transfer Residues

(2017) Atanu Rana et al.   INORGANIC CHEMISTRY

Redox and Spectroscopic Properties of Iron Porphyrin Nitroxyl in the Presence of Weak Acids

(2017) Md. Hafizur Rahman et al.   INORGANIC CHEMISTRY

Selective Photocatalytic CO2 Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals

(2017) Moritz F. Kuehnel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Heterolytic Cleavage of the H–H Bond by Molybdenum Complexes: Controlling the Dynamics of Exchange Between Proton and Hydride

(2017) Shaoguang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling Proton Delivery through Catalyst Structural Dynamics

(2016) Allan Jay P. Cardenas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst

(2016) Eric S. Rountree et al.   ACS Catalysis

Proton-coupled electron transfer chemistry of hangman macrocycles: Hydrogen and oxygen evolution reactions

(2015) Dilek K. Dogutan et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center

(2015) Lingjing Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism

(2015) Brian H. Solis et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Beyond the Active Site: The Impact of the Outer Coordination Sphere on Electrocatalysts for Hydrogen Production and Oxidation

(2014) Bojana Ginovska-Pangovska et al.   ACCOUNTS OF CHEMICAL RESEARCH

Arginine-Containing Ligands Enhance H2Oxidation Catalyst Performance

(2014) Arnab Dutta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heme Enzyme Structure and Function

(2014) Thomas L. Poulos   CHEMICAL REVIEWS

How Biology Handles Nitrite

(2014) Luisa B. Maia et al.   CHEMICAL REVIEWS

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile—Implications for Electrocatalytic Hydrogen Evolution

(2014) Brian D. McCarthy et al.   INORGANIC CHEMISTRY

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry

(2014) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Molecular Catalysis of H2 Evolution: Diagnosing Heterolytic versus Homolytic Pathways

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic H2 Evolution by Proton-Gated Hangman Iron Porphyrins

(2014) Daniel J. Graham et al.   ORGANOMETALLICS

Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins

(2014) D. Kwabena Bediako et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Theoretical Analysis of Cobalt Hangman Porphyrins: Ligand Dearomatization and Mechanistic Implications for Hydrogen Evolution

(2014) Brian H. Solis et al.   ACS Catalysis

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

High Catalytic Rates for Hydrogen Production Using Nickel Electrocatalysts with Seven-Membered Cyclic Diphosphine Ligands Containing One Pendant Amine

(2013) Michael P. Stewart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of Porphyrines as Catalysts for Electrochemical Reduction of O2 and Oxidation of H2O

(2013) Jakub D. Baran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Earth-abundant hydrogen evolution electrocatalysts

(2013) James R. McKone et al.   Chemical Science

Electrochemical Hydrogen Production in Acidic Water by an Azadithiolate Bridged Synthetic Hydrogenese Mimic: Role of Aqueous Solvation in Lowering Overpotential

(2013) Subal Dey et al.   ACS Catalysis

The Artificial Leaf

(2012) Daniel G. Nocera   ACCOUNTS OF CHEMICAL RESEARCH

The Outer-Coordination Sphere: Incorporating Amino Acids and Peptides as Ligands for Homogeneous Catalysts to Mimic Enzyme Function

(2012) Wendy J. Shaw   CATALYSIS REVIEWS-SCIENCE AND ENGINEERING

Pendant amine bases speed up proton transfers to metals by splitting the barriers

(2012) Ying Wang et al.   CHEMICAL COMMUNICATIONS

Hydrogen peroxide as a sustainable energy carrier: Electrocatalytic production of hydrogen peroxide and the fuel cell

(2012) Shunichi Fukuzumi et al.   ELECTROCHIMICA ACTA

Synthesis, Characterization, and Reactivity of Fe Complexes Containing Cyclic Diazadiphosphine Ligands: The Role of the Pendant Base in Heterolytic Cleavage of H2

(2012) Tianbiao Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Wolfe cycle comes full circle

(2012) R. K. Thauer   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles

(2011) Dilek K. Dogutan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Generation by Hangman Metalloporphyrins

(2011) Chang Hoon Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Density Functional Theory Calculations on the Mononuclear Non-Heme Iron Active Site of Hmd Hydrogenase: Role of the Internal Ligands in Tuning External Ligand Binding and Driving H2Heterolysis

(2010) Abhishek Dey   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hangman Corroles: Efficient Synthesis and Oxygen Reaction Chemistry

(2010) Dilek K. Dogutan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparison of Cobalt and Nickel Complexes with Sterically Demanding Cyclic Diphosphine Ligands: Electrocatalytic H2Production by [Co(PtBu2NPh2)(CH3CN)3](BF4)2†

(2010) Eric S. Wiedner et al.   ORGANOMETALLICS

Oxygen reduction reactivity of cobalt(ii) hangman porphyrins

(2010) Robert McGuire Jr. et al.   Chemical Science

Hydrogen Evolution Catalyzed by Cobaloximes

(2009) Jillian L. Dempsey et al.   ACCOUNTS OF CHEMICAL RESEARCH

Development of Molecular Electrocatalysts for CO2Reduction and H2Production/Oxidation

(2009) M. Rakowski Dubois et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chemistry of Personalized Solar Energy

(2009) Daniel G. Nocera   INORGANIC CHEMISTRY

The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation

(2008) M. Rakowski DuBois et al.   CHEMICAL SOCIETY REVIEWS